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您的检索式：作者名="Songtong Zhang"
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| 1 | Micrometer-sized ferrosilicon composites wrapped with multi-layered carbon nanosheets as industrialized anodes for high energy lithium-ion batteries显示文摘Various nanostructured architectures have been demonstrated to be effective to address the issues of high capacity Si anodes. However, the scale-up of these nano-Si materials is still a critical obstacle for commercialization. Herein, we use industrial ferrosilicon as low-cost Si source and introduce a facile and scalable method to fabricate a micrometer-sized ferrosilicon/C composite anode, in which ferrosilicon microparticles are wrapped with multi-layered carbon nanosheets. The multi-layered carbon nanosheets could effectively buffer the volume variation of Si as well as create an abundant and reliable conductivity framework, ensuring fast transport of electrons. As a result, the micrometer-sized ferrosilicon/C anode achieves a stable cycling with 805.9 m Ah g-1 over 200 cycles at 500 mA g-1 and a good rate capability of455.6 mAh g-1 at 10 A g-1. Therefore, our approach based on ferrosilicon provides a new opportunity in fabricating cost-effective, pollution-free, and large-scale Si electrode materials for high energy lithium-ion batteries. | Meng Li Jingyi Qiu Songtong Zhang Pengcheng Zhao Zhaoqing Jin Anbang Wang Yue Wang Yusheng Yang Hai Ming | 2020 | Journal of Energy Chemistry2020，29，11： | 2 |
| 2 | New Insight on Graphite Anode Degradation Induced by Li-Plating显示文摘Graphite is the dominant anode material for lithium-ion batteries;however,it still suffers from Li-plating when charging fast or at low temperature,and Liplating is associated with performance fading and safety concerns.Herein,we clarify the mechanism of lithium evolution from graphite particles by overlithiation cycle test,in-situ XRD,and titration gas chromatography.We observe that the graphite intercalation compounds(GICs,LiC_(12) and LiC_(6)e.g.)gradually become inactive and wrapped by dead lithium or side reaction sediments,while the rate of this degradation will be accelerated as the overpotential of Liplating is decreased after initial Li metal nucleation.This understanding is contradictory to the popular one that the degradation of graphite anode after Li plating is mainly caused by the inferior SEI and dead Li induced hindering of Li-ion intercalation.The isolation of lithiated graphite particles leading to the fast vanishing of Li insertion/deintercalation process in graphite anodes.We further study the insertion/deintercalation vanishing process at low temperature and high rates,respectively.This work provides a insight on graphite anode degradation induced by Li-plating,and the new understanding can be used to guide the design of advanced materials and electrodes to avoid Li-plating and achieve extreme fast while safe charging. | Yongchuang Xiong Yan Liu Long Chen Songtong Zhang Xiayu Zhu Tengteng Shen Dongsheng Ren Xiangming He Jingyi Qiu Li Wang Qiao Hu Hao Zhang | 2022 | Energy & Environmental Materials2022，5，3： | 0 |
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