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1Synthesis and electrochemical performance of LiCoPO_4 micron-rods by dispersant-aided hydrothermal method for lithium ion batteries显示文摘LiCoPO4 micron-rods with an average diameter of about 500 nm and length of about 5 μm were synthesized by dispersant-aided hydrothermal method. Poly(n-vinylpyrrolidone) (PVP) was used as dispersant in the hydrothermal method. The starting solution and the concentration of dispersant have significant influences on the morphology of LiCoPO4,and the electrochemical performance is improved via controlling the particle size and morphology by the hydrothermal method. The cell using smaller particle LiCoPO4 as cathode delivers a larger capacity and lower cell polarization.Zhao, Yujuan Wang, Suijun Zhao, Chunsong Xia, Dingguo 2009Rare Metals2009,28,2:11
2Recent progresses in the suppression method based on the growth mechanism of lithium dendrite显示文摘Lithium secondary batteries(LSBs) with high energy densities need to be further developed for future applications in portable electronic devices, electric vehicles, hybrid electric vehicles and smart grids. Lithium metal is the most promising electrode for next-generation rechargeable batteries. However, the formation of lithium dendrite on the anode surface leads to serious safety concerns and low coulombic efficiency.Recently, researchers have made great efforts and significant progresses to solve these problems. Here we review the growth mechanism and suppression method of lithium dendrite for LSBs' anode protection. We also establish the relationship between the growth mechanism and suppression method. The research direction for building better LSBs is given by comparing the advantages and disadvantages of these methods based on the growth mechanism.Xiaolong Xu Suijun Wang Hao Wang Chen Hu Yi Jin Jingbing Liu Hui Yan 2018Journal of Energy Chemistry2018,27,2:8
3Syntheses, structures and magnetic properties of three Co(Ⅱ)coordination architectures based on a flexible multidentate carboxylate ligand and different N-donor ligands显示文摘Three new cobalt complexes,{[Co5(tci)2(bimb)3(3-O)2(H2O)2]·3DMF·4H2O}n(1),{[Co3(tci)2(bib)]·2DMF·2H2O}n(2)and{[Co(Htci)(bpea)0.5]·H2O}n(3)(H3tci=tris(2-carboxyethyl)isocyanurate,bimb=4,4′-bis(imidazol-1-yl)biphenyl,bib=1,4-bis(imidazol-1-yl)benzene,bpea=1,2-bis(4-pyridyl)ethane,DMF=N,N′-dimethylformamide),have been successfully synthesized through the assembly of Co(II)ions,H3tci and different N-donor ligands,respectively.All complexes were structurally characterized by single crystal X-ray diffraction,elemental analyses,IR spectra,thermogravimetric(TG)analyses and X-ray powder diffraction(XRPD).Complex 1 exhibits a 3D three-fold parallel interpenetrated 3D→3D structure with(65·8)CdSO4topology.Complex 2 is built from[Co3(2-Ocarboxyl)2(CO2)4]clusters and linear bib ligands,displaying a two-fold parallel interpenetrated(3,8)-connected(43)2(46·618·84)topology,while complex 3 is a 3D pillar-layered structure involving an infinite–Co–(2-Ocarboxyl)(CO2)–Co–chain.The diverse structures of the three complexes indicate that the skeletons of different N-donor ligands play an important role in the assembly of such different frameworks.In addition,magnetic investigation indicates that besides spin-orbit coupling of Co(II)ions,there exist antiferromagnetic exchange interactions in Co5and Co3clusters of 1 and 2,respectively.TIAN Dan LIU SuiJun ZHANG DaShuai CHANG Ze HU TongLiang BU XianHe 2013Science China Chemistry2013,56,12:5
4Local mild hypothermia with thrombolysis for acute ischemic stroke within a 6-h window显示文摘Min Bi Qilin Ma Shiyang Zhang Jianpeng Li Yidan Zhang Longting Lin Suijun Tong Desheng Wang 2011Clinical Neurology and Neurosurgery2011,,:1
5Cruciform DPVBi:synthesis,morphology,optical and electroluminescent properties显示文摘Liu Suijun He Feng Wang Hua 2008J Mater Chem2008,18,:1
6Case Fatality Rate of Patients with Acute Myocardial Infarction in 253 Chest Pain Centers--China,2019-2020显示文摘Summary What is already known about this topic?Acute myocardial infarction(AMI)is the most serious form of cardiovascular diseases.The case fatality rate(CFR)of AMI patients is an important index to reflect the prognosis of AMI.What is added by this report?During the study period,the overall 30-day,60-day,and 90-day CFR of AMI was 5.9%,6.9%,and 7.6%,respectively.The CFRs in gradeⅢhospitals were lower than in gradeⅡhospitals,and the in-hospital CFR was significantly lower than that in post-discharge out-of-hospital.Zheng Long Wei Liu Zhenping Zhao Suijun Tong Lijun Wang Maigeng Zhou Dingcheng Xiang Yundai Chen Jianan Wang Xiaoshu Cheng Bao Li Lang Li Wei Li Bei Shi Hong Shi Peng Yin Kai Huang Yong Huo 2022China CDC weekly2022,4,24:1
7Blue-shifted and naked-eye recognition of H_(2)PO_(4)- and acetylacetone based on a luminescent metal-organic framework with new topology and good stability显示文摘Fluorescence detecting both organic and inorganic analytes has aroused tremendous scientific interests, because fluorescence techniques have high sensitivity and are easy to operate. A new threedimensional(3D) MOF {[(CH_(3))_(2)NH_(2)][Zn_(3)(bbip)(BTDI)1.5(OH)]·DMF·MeOH·3H_(2)O}n(JXUST-13, bbip = 2,6-bis(benzimidazol-1-yl)pyridine and H_(4)BTDI = 5,5-(benzo[c][1,2,5]thiadiazole-4,7-diyl)diisophthalic acid)with new 4,4,8-connceted topology has been successfully synthesized and structurally characterized. Importantly, JXUST-13 could recognize H_(2)PO_(4)-and acetylacetone(Acac) by obvious fluorescence blue shift and slight enhancement with the detection limits of 2.70 μmol/L and 0.21 mmol/L, respectively. In addition, JXUST-13 exhibits relatively good thermal stability, chemical stabilities as well as reusability, and the analytes could be distinguished by naked eye and fluorescence test paper. Remarkably, JXUST-13 is the first dual-responsive MOF sensor based on fluorescence blue shift for the detection of H_(2)PO_(4)-and Acac with good selectivity in a handy, economic, and environmentally friendly manner.Shuli Yao Hui Xu Tengfei Zheng Yunwu Li Haiping Huang Jun Wang Jinglin Chen Suijun Liu Herui Wen 2023Chinese Chemical Letters2023,34,4:0
8Emissive Mononuclear Cu(Ⅰ) Triphenylphosphine Complexes with Functionalized 6-tert-Butoxycarbonyl-2,2 '-bipyridine显示文摘LUO Yansheng ZENG Xuehua WANG Wanman CHEN Jinglin HE Lihua ZHANG Mengli LIU Suijun WEN Herui 2018Chemical Research in Chinese Universities2018,34,1:0
9Three new Cu(Ⅱ)-Ln(Ⅲ) heterometallic coordination polymers constructed from quinolinic acid and nicotinic acid: Synthesis, structures, and magnetic properties显示文摘Three new Cu(II)-Ln(Ⅲ) heterometallic coordination polymers based on two N-heterocyclic carboxylic ligands, {[LnCu(L1)2(L2)(H2O)2]·mH2O}n (Ln = La(1), Nd(2), Gd(3), m = 2 (for 1), 1 (for 2, 3), H2L1 = quinolinic acid, HL2 = nicotinic acid), have been synthesized and characterized. 1 has a two-dimensional (2D) layer structure with a Schl?fli symbol of (44.62), while complexes 2 and 3 are isostructural and have three-dimensional (3D) structures with a Schl?fli symbol of (3.4.5)2(32.42.52.614.74.83.9)(32.63.7) of 3-nodal net. Magnetic investigations suggest that antiferromagnetic coupling exists between NdⅢ and CuII in 2, while weak ferromagnetic coupling between GdⅢ and CuII in 3. The difference of magnetic properties between 2 and 3 has been discussed.LIU SuiJun SONG WeiChao XUE Li HAN SongDe ZENG YongFei WANG LiFu BU XianHe 2012中国科学:化学2012,42,6:0
102D Cd-MOF and its mixed-matrix membranes for luminescence sensing antibiotics in various aqueous systems and visible fingerprint identifying显示文摘The abuse of antibiotics has brought great harm to the human living environment and health,so it is extremely significant to develop an efficient and simple method to detect trace antibiotic residues in various wastewaters.Herein,a new two-dimensional(2D)Cd-based metal−organic framework(Cd-MOF,namely LCU-111)and its mixed matrix membranes(MMMs)is sifted as luminescence sensors for efficient monitoring antibiotic nitrofurazone(NFZ)in various aqueous systems and applied as visible fingerprint identifying.The LCU-111 has good selectivity,sensibility,reproducibility and anti-interference for luminescent quenching NFZ with low detection limits(LODs)of 0.4567,0.3649 and 0.8071 ppm in aqueous solution,HEPES biological buffer,and real urban Tuhai River water,respectively.Interestingly,the luminescent test papers and MMMs allow the NFZ sensing easier and more rapid by naked eyes,only with a low LOD of 0.8117 ppm for MMMs sensor.Notably,by combining multiple experiments with density functional theory(DFT)calculations,the photo-induced electron transfer(PET)quenching mechanism is further elucidated.More importantly,potential practical applications of LCU-111 for latent fingerprint visualization provide lifelike evidences for effective identification of individuals,which can be applied in criminal investigation.Kexin Ma Jing Li Huiyan Ma Yan Yang Hua Yang Jing Lu Yunwu Li Jianmin Dou Suna Wang Suijun Liu 2023Chinese Chemical Letters2023,34,11:0
11A designed core-shell structural composite of lithium terephthalate coating on Li_4Ti_5O_(12) as anode for lithium ion batteries显示文摘A core-shell structural composite was synthesized with lithium terephthalate(Li_2C_8H_4O_4) coated on spinel Li_4Ti_5O_(12)(LTO). The composite displays a capacity of about 200 mA h g^(-1) and a good rate capability with two charge/discharge platforms at ~ 1.55 and ~ 0.8 V. The excellent cycling performance of the composite is attributed to the successful combination of high cycling stability of LTO and high specific capacity of Li_2C_8H_4O_4. In addition, an interesting phenomena is observed for the first time for this composite which is that lithium ions transfer between LTO and Li_2C_8H_4O_4 at a fast speed. This is investigated in details via the asymmetric charge/discharge measurement and cyclic voltammogram(CV).The LTO/Li_2C_8H_4O_4 composite may have potential applications to be used as an anode material for the electric vehicle batteries, which is shallowly charged/discharged at ordinary times using the charge/discharge platform of LTO and fully charged/discharged at emergency to release the extra high capacity from Li_2C_8H_4O_4.Yong Yan Liubin Ben Yuanjie Zhan Yanyan Liu Yi Jin Suijun Wang Xuejie Huang 2016Progress in Natural Science:Materials International2016,26,4:0
12Highly selective and turn-on fluorescence probe with red shift emission for naked-eye detecting Al^(3+)and Ga^(3+)based on metal-organic framework显示文摘A novel ZnII-based metal-organic framework with the formula of{[Zn_(2)(BBIP)_(2)(NDC)_(2)]·H_(2)O}n(JXUST-5)derived from 3,5-bis(benzimidazol-1-yl)pyridine(BBIP)and 1,4-naphthalenedicarboxylic acid(H_(2)NDC)has been synthesized.The adjacent Zn^(II)ions are linked through two BBIP ligands to form a[Zn_(2)(BBIP)_(2)]secondary building unit(SBU).The neighbouring SBUs are further connected by NDC^(2-)withμ2-η^(1):η^(1)andμ2-η^(1):η^(1):η^(1)bridging modes to form a two-dimensional(2D)framework.Topological analysis shows that JXUST-5 could be simplified as an uninodal fes topology with a point symbol of{4.8^(2)}.Furthermore,the 2D framework net could be extended through C-H···πinteraction to form the three-dimensional supramolecular structure.Luminescent experiments suggest that JXUST-5 could selectively and sensitively recognize Al^(3+)and Ga^(3+)through fluorescence enhancement effect along with a relatively large red shift.The detection limits for Al^(3+)and Ga^(3+)are 0.17 and 0.69 ppm,respectively.Interestingly,the sensing process for both Al^(3+)and Ga^(3+)could be directly observed with naked eyes under 365 nm UV lamp.Notably,JXUST-5 could be recycled at least five times as a fluorescent sensor toward Al^(3+)and Ga^(3+),which is the second example of turn-on MOF based fluorescent sensor toward Ga^(3+).Linhui Wu Shuli Yao Hui Xu Tengfei Zheng Suijun Liu Jinglin Chen Na Li Herui Wen 2022Chinese Chemical Letters2022,33,1:0
13Two 2D uranyl coordination complexes showing effective photocatalytic degradation of Rhodamine B and mechanism study显示文摘Two new hydrostable two-dimensional(2 D) uranyl coordination complexes [(UO_(2))_(5)(μ_(3)-O)_(2)(nbca)_(2)].7 H_(2)O(1) and [(UO_(2))_(3)(nbca)_(2)(H_(2)O)_(3)]·2 H_(2)O(2)(H_(3) nbca=5-nitro-1,2,3-benzenetricarboxylic acid) were hydrothermal synthesized.Single-crystal structural refinements reveal that both of the two complexes were formed by the packing of 2D uranyl coordination sheets via the hydrogen bonds.The nbca ligand coordinating to the uranyl polyhedron centers constructed the 2D sheets.There are UO8 hexagonal bipyramids and UO7 pentagonal bipyramids in 1 while only U07 pentagonal bipyramids in 2.Photocatalytic degradation of rhodamine B(RhB) in aqueous solution was studied.Complex 2 possesses better performance than 1 with 96.2 % of the RhB was degraded in only 60 min.Mechanism studies reveal that the dissolved oxygens are essential to the RhB degradation.The photocurrent density of 2 is more stable than that of 1,which indicating the stronger ability to separate photoexcited electrons and hole pairs of 2.Xiaolan Tong Shan Wang Jun Zuo Yingchong Ge Qiang Gao Suijun Liu Jianhua Ding Fen Liu Jianqiang Luo Jianbo Xiong 2021Chinese Chemical Letters2021,32,2:0
14Three new Cu(Ⅱ)-Ln(Ⅲ) heterometallic coordination polymers constructed from quinolinic acid and nicotinic acid: Synthesis, structures, and magnetic properties显示文摘Three new Cu(Ⅱ)-Ln(Ⅲ) heterometallic coordination polymers based on two N-heterocyclic carboxylic ligands, {[LnCu(L1)2(L2)(H2O)2]·mH2O}n (Ln = La(1), Nd(2), Gd(3), m = 2 (for 1), 1 (for 2, 3), H2L1 = quinolinic acid, HL2 = nicotinic acid), have been synthesized and characterized. 1 has a two-dimensional (2D) layer structure with a Schlfli symbol of (44.62), while complexes 2 and 3 are isostructural and have three-dimensional (3D) structures with a Schlfli symbol of (3.4.5)2(32.42.52.614.74.83.9)(32.63.7) of 3-nodal net. Magnetic investigations suggest that antiferromagnetic coupling exists between NdIII and CuII in 2, while weak ferromagnetic coupling between GdIII and CuII in 3. The difference of magnetic properties between 2 and 3 has been discussed.LIU SuiJun SONG WeiChao XUE Li HAN SongDe ZENG YongFei WANG LiFu BU XianHe 2012Science China Chemistry2012,55,6:0
15Integrated fabrication process with multiple optimized factors for high power density of IPMC actuator显示文摘Ionic polymer-metal composites(IPMCs)are typical smart mate-rials that are commonly used in bionic applications,including soft robots,bionic flapping aircraft,and bionic fish.However,their low output force seriously limits device performance.Stacking of multiple IPMC actuators to improve the overall performance of soft actuators is a strategy that is used in practical applications.Under the energy dissipation condition in the IPMC stacking structure,if each single IPMC in the struc-ture has high power density,the structure will produce excel-lent performance with high efficiency that can greatly promote wider application of IPMC actuators.To meet this requirement,a method for fabrication process integration with multiple opti-mized factors was used to obtain IPMC materials in this paper.Carbon nanotube(CNT)doping,isopropyl alcohol-assisted plat-ing,and hot pressing with a mesoscopic structural mold were selected as typical optimization methods for process integration and were initially investigated separately to determine the opti-mal process parameters.By combining the best process para-meters in an integrated process,the IPMC treated by isopropyl alcohol-assisted plating and CNT doping process(No.AC7)showed excellent actuation performance and high work density(~9.71/12.36 gf,~14.93/31.89 kJ/m^(3) under 3/4 VDC).The enhanced performance meets the requirements for practical bionic applications.Zicai Zhu Changsheng Bian Wanfa Bai Qiao Hu Suijun Chen 2022International Journal of Smart and Nano Materials2022,13,4:0
16Expert recommendations on collection and annotation of otoscopy images for intelligent medicine显示文摘Middle and outer ear diseases are common otological diseases worldwide.Otoscopy and otoendoscopy exami-nations are essential first steps in the evaluation of patients with otological diseases.Misdiagnosis often occurs when the doctor lacks experience in interpreting the results of otoscopy or otoendoscopy,leading to delays in treatment or complications.Using deep learning to process otoscopy images and developing otoscopic artificial-intelligence-based decision-making systems will become a significant trend in the future.However,the uneven quality of otoscopy images is among the major obstacles to development of such artificial intelligence systems,and no standardized process for data acquisition,and annotation of otoscopy images in intelligent medicine has yet been fully established.The standards for data storage and data management are unified with those of other specialties and are introduced in detail here.This expert recommendation criterion improved and standardized the collection and annotation procedures for otoscopy images and fills the current gap in otologic intelligent medicine;it would thus lay a solid foundation for the standardized collection,storage,and annotation of oto-scopy images and the application of training algorithms,and promote the development of automatic diagnosis and treatment for otological diseases.The full text introduced image collection(including patient preparation,equipment standards,and image storage),image annotation standards,and quality control.Yuexin Cai Junbo Zeng Liping Lan Suijun Chen Yongkang Ou Linqi Zeng Qintai Yang Peng Li Yubin Chen Qi Li Hongzheng Zhang Fan Shu Guoping Chen Wenben Chen Yahan Yang Ruiyang Li Anqi Yan Haotian Lin Yiqing Zheng 2022Intelligent Medicine2022,2,4:0
17Syntheses, structures and magnetic properties of Fe_6 and Fe_(12) ferric wheels显示文摘Starting from the same Fe3O(RCO2)6 complex and using a similar synthesis strategy, the Fe6 and Fe12 wheels were obtained by utilizing two designed ligands, 2-amino-2-methyl-1,3-propanediol(L1) and 1,3-propanediol(L2), respectively. A biological buffer reagent, Bis-Tris(2-[bis-(2-hydroxyethyl)amino]-2-(hydroxymethyl)propane-1,3-diol) was first introduced in the synthesis of the Fe12 wheel, playing a vital role in adjusting the acidity of reaction environment. Magnetic studies on both Fe6 and Fe12 wheels revealed strong antiferromagnetic coupling between the spins on FeIII ions.Guojian Ren Yanqing Liu Zhenxin Zhao Suijun Liu Songde Han Jian Xu Xianhe Bu 2015Science China(Information Sciences)2015,58,12:0
18Two isostructural Ni(Ⅱ)/Co(Ⅱ)-based metal-organic frameworks for selective dye adsorption and catalytic cycloaddition of CO_(2) with epoxides显示文摘Two isostructu ral Ni(Ⅱ)/Co(Ⅱ)-based metal-organic frameworks(MOFs),namely {[M_(3)(L)_(2)(bpb)_(3)(H_(2) O)_(4)]·2 DMF·2 H_(2)O}_(n) [M=Ni(HL-5,HL is short for Hui-Ling Liu);M=Co(HL-6);H_(3) L=2',6'-dimethyl-[1,1'-biphenyl]-3,4',5-tricarboxylic acid;bpb=1,4-bis(pyrid-4-yl)benzene],have been hydrothermally synthesized and structu rally characterized.Both HL-5 and HL-6,which have the same three-interpenetrated3 D pillared-layer framework with sqc306 type topology,present good selective methyl orange(MO)adsorption over rhodamine B(RhB).Moreover,the catalytic CO_(2) cycloaddition properties with epoxides of the two MOFs have also been studied at ambient pressure and temperature.Hui Hu Dashuai Zhang Huiling Liu Yaoqiang Jin Jun Gao Yongzheng Zhang Zhongmin Liu Xiuling Zhang Longlong Geng Suijun Liu Ranhui Zhang 2021Chinese Chemical Letters2021,32,1:0
19Construction of novel cluster-based MOF as multifunctional platform for CO_(2) catalytic transformation and dye selective adsorption显示文摘Synthetic conditions and ligands are the key structural defining factors of metal-organic frameworks(MOFs).Therefore,reasonable optimization of these aspects is considered to be an effective means for designing materials with novel structures and target functions.Herein,two novel Co(Ⅱ)-based MOFs,namely[Co(HL)(dibp)]_(n)(HL-8) and{[Co_(2)(L)(OH)(dibp)]·DMA}_n(HL-9)(H_(3)L=2',6'-dimethyl-[1,1'-biphenyl]-3,4',5-tricarboxylic acid;dibp=4,4'-di(1H-imidazol-1-yl)-1,1-biphenyl]),have been hydrothermally synthesized and structurally characterized.HL-8 crystallizes in the orthorhombic system (Pna2_(1)) with a grid layer structure,while HL-9 crystallizes in the monoclinic P2_(1)/n space group assembled through Co_(4)(OH)_(2)clusters with organic ligands.Remarkably,benefiting from the finite cage-like structure,HL-9 exhibited enhanced performance in carbon dioxide(CO_(2)) adsorption/catalytic transformation and excellent size selectivity during dye molecular adsorption process.Xiuling Zhang Yongzheng Zhang Wenfeng Zhou Huiling Liu Dashuai Zhang Hui Hu Chao Lv Suijun Liu Longlong Geng 2023Chinese Chemical Letters2023,34,3:0
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