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1Cloning of 9-cis-epoxycarotenoid dioxygenase (NCED) gene encoding a key enzyme during abscisic acid (ABA) biosynthesis and ABA-regulated ethylene production in detached young persimmon calyx显示文摘Unlike the typical climacteric fruits, persimmons (Diospyros kaki Thunb.) produce higher levels of ethylene when they are detached from trees at a younger stage. In order to obtain detailed information on the role of abscisic acid (ABA) in ripening, we cloned the DKNCED1, DKACS2, and DKACO1 genes from the calyx. Water loss was first noted in the calyx lobe, and DKNCED1 was highly expressed 1 d after the fruits were detached, coinciding with an increase in the ABA content. Then, the DKACS2 and DKACO1 genes were expressed after some delay. In the calyx, the ABA peak was observed 2 d after the fruits were harvested, and this peak preceded the ethylene peak observed on day 3. The fruit firmness rapidly decreased on day 4, and the fruits softened completely 6 d after they were harvested. The increases in the expressions of ABA, ethylene, and the genes in the calyxes occurred earlier than the corresponding increases in the pulp, although the 3 increases occurred on different days. Exogenous ABA treatment increased ABA concentration, induced expression of both ACS and ACO, and promoted ethylene synthesis and young-fruit softening; by contrast, treatment with NDGA inhibited the gene expressions and ethylene synthesis and delayed young-fruit softening. These results indicate that ethylene biosynthesis in the detached young persimmon fruits is initially triggered by ABA, which is induced by water loss in the calyx, through the induction of DKACS2 and DKACO1 expressions. The ethylene produced in the calyx subsequently diffuses into the pulp tissue, where it induces autocatalytic ethylene biosynthesis, resulting in an abrupt increase in ethylene production.LENG Ping ZHANG GuangLian LI XiangXin WANG LiangHe ZHENG ZhongMing 2009Chinese Science Bulletin2009,54,16:13
2SHRIMP zircon U-Pb dating of the intrusives in the Tongling metallogenic cluster and its dynamic setting显示文摘This paper selected five typical Mesozoic intrusives from the Tongling metallogenic cluster (Xiaotongguanshan, Fenghuangshan, Xinqiao, Dongguashan, and Shatanjiao plutons), and made a systemic SHRIMP zircon U-Pb dating for the five plutons, which produced an age range of 151.8±2.6- 142.8±1.8 Ma. This work put an accurate constraint on the formation age of the intrusives in the Tongling metallogenic cluster. These age data indicate that magmatic activity reached a peak during Late Jurassic. The intrusive sequence of magma is generally from quartz monzonite (porphyry) through monzonite to granodiorite to quartz monzodiorite to pyroxene monzodiorite to gabbro-diabase. The intrusives of different lithology differed in crystallization age, probably implying the intrusives in the Tongling area underwent an evolutional process of magma, which was closely related to geodynamical setting in the depths of the area. A dynamic model was presented for the origin of the igneous rocks in the study area as follows. The assembly between the Yangtze craton and the North China craton fini- shed at the end of T3, and then the stage of another compressional orogeny began in the Tongling area, i.e., Pacific dynamic system. Along with the subduction of the Izanagi plate underneath the Eurasian plate at J2-J3, NW-trending compression toward the East China continent was produced, and compres- sional deformation also took place, forming NE-trending fold and resulting in thickening of the crust in the Tongling area. High-density eclogite-facies rocks were produced in the low part of the crust, re- sulting in the delamination of mantle lithosphere and lower crust, and upwelling of materials in as- thenosphere. Decompression melting produced basaltic magma, and the materials in lower crust were heated by the underplating of the basaltic magma. Thus, melting of lower crust yielded granitic magma, which intruded along deep and large faults through various geological processes (J3-K1). The SHRIMP U-Pb zircon age of 151.8±2.6-142.8±1.8 Ma for intrusives in the Tongling area suggests that the de- lamination of lithosphere mantle and lower crust at least began at middle-late stage of Late Jurassic, resulting in sharp thinning of lithosphere and intense extension of middle-upper crust. Thus, a lot of decollements were produced between cover and cover, basement and cover, and middle and lower crust. This was structural layering or detachment of lithosphere in the Tongling area. Three concordant ages for old inherited cores of magmatic origin (747-823 Ma) indicated that there were obvious mag- matism in the Tongling area during Neoproterozoic, and a little more of the Neoproterozoic igneous source rocks participated in the formation of Mesozoic intrusives.GanGuo Wu Da Zhang YongJun Di WenShuan Zang XiangXin Zhang Biao Song ZhongYi Zhang 2008Science China Earth Sciences2008,51,7:11
3Removal kinetics of phosphorus from synthetic wastewater using basic oxygen furnace slag显示文摘Removal kinetics of phosphorus through use of basic oxygen furnace slag(BOF-slag)was investigated through batch experiments. Effects of several parameters such as initial phosphorus concentration, temperature, BOF-slag size, initial p H, and BOF-slag dosage on phosphorus removal kinetics were measured in detail. It was demonstrated that the removal process of phosphorus through BOF-slag followed pseudo-first-order reaction kinetics. The apparent rate constant(kobs) significantly decreased with increasing initial phosphorus concentration, BOF-slag size, and initial p H, whereas it exhibited an opposite trend with increasing reaction temperature and BOF-slag dosage.A linear dependence of kobson total removed phosphorus(TRP) was established with kobs=(3.51 ± 0.11) × 10- 4× TRP. Finally, it was suggested that the Langmuir–Rideal(L–R)or Langmuir–Hinshelwood(L–H) mechanism may be used to describe the removal process of phosphorus using BOF-slag.Chong Han Zhen Wang He Yang Xiangxin Xue 2015Journal of Environmental Sciences2015,27,4:6
4Genesis and Implications of the Composition and Sedimentary Structure of Fine-Grained Carbonate Rocks in the Shulu Sag显示文摘Fine-grained carbonate rocks, which extensively occur in the Eocene strata in the Shulu sag, Bohai Bay Basin, North China, represent an unconventional, fine-grained carbonate reservoir. However, previous studies have ignored the complexity of the lithofacies components and their formation mechanisms. Fine-grained carbonate rocks are typical reservoirs in which hydrocarbons form and gather. A better understanding of the nature of these rocks is extremely important for evaluating the quality of unconventional, fine-grained carbonate reservoirs. Various lithofacies components were discriminated in this study with a combination of petrographic observations and carbon isotope analyses. These finegrained carbonate rocks comprise terrigenous, biogenic and diagenetic materials. Terrigenous input and biologically induced precipitation are the main sources of the materials in the lake. Five lithofacies were identified based on the observations of sedimentary features(core and thin section) and mineralogical data:(1) varve-like laminated calcilutite,(2) graded laminated calcilutite,(3) interlaminated calcisiltitecalcilutite,(4) massive calcilutite, and(5) massive calcisiltite-calcarenite. Their origins were recorded by various lithofacies components, which are controlled by the interactions of physical, chemical and biological processes. This study indicated that the lithology of the bedrocks was the key factor controlling carbonate accumulation. The tectonics and climate can influence the weathering and types of lithofacies. Primary productivity controlled the precipitation of the endogenic calcite. These factors jointly determined the abundant fine-grained carbonate rocks that have accumulated in the Shulu sag.Xiangxin Kong Zaixing Jiang Chao Han Lijing Zheng Yiming Zhang Ruifeng Zhang Jianzhang Tian 2017Journal of Earth Science2017,28,6:6
5A novel true triaxial test system for microwave-induced fracturing of hard rocks显示文摘This study introduces a test system for microwave-induced fracturing of hard rocks under true triaxial stress.The test system comprises a true triaxial stress loading system,an open-ended microwaveinduced fracturing system,a data acquisition system,an acoustic emission(AE)monitoring system,and an auxiliary specimen loading system.Microwave-induced surface and borehole fracturing tests under true triaxial stress were fulfilled for the first time,which overcomes the problem of microwave leakage in the coupling loading of true triaxial stress and microwave.By developing the dynamic monitoring system,the thermal response and fracture evolution were obtained during microwave irradiation.The monitoring system includes the infrared thermometry technique for monitoring rock surface temperature,the distributed optic fiber sensing technique for monitoring temperature in borehole in rock,the AE technique and two-dimensional digital speckle correlation technique for monitoring the evolution of thermal damage and the rock fracturing process.To validate the advantages of the test system and investigate the characteristics of microwave-induced fracturing of hard rocks,the study demonstrates the experimental methods and results for microwave-induced surface and borehole fracturing under true triaxial stress.The results show that thermal cracking presented intermittent characteristics(calm eactiveecalm)during microwave-induced surface and borehole fracturing of basalt.In addition,true triaxial stress can inhibit the development and distribution of thermal cracks during microwave-induced surface fracturing.When microwave-induced borehole fracturing occurs,it promotes the distribution of thermal cracks in rock,but inhibits the width of cracks.The results also prove the reliability of the test system.Xia-Ting Feng Jiuyu Zhang Chengxiang Yang Jun Tian Feng Lin Shiping Li Xiangxin Su 2021Journal of Rock Mechanics and Geotechnical Engineering2021,13,5:5
6Kinetics and mechanism of hexavalent chromium removal by basic oxygen furnace slag显示文摘Basic oxygen furnace slag(BOFS) has the potential to remove hexavalent chromium(Cr(VI))from wastewater by a redox process due to the presence of minerals containing Fe2+. The effects of the solution p H, initial Cr(VI) concentration, BOFS dosage, BOFS particle size, and temperature on the removal of Cr(VI) was investigated in detail through batch tests. The chemical and mineral compositions of fresh and reacted BOFS were characterized using scanning electron microscope(SEM) equipped with an energy dispersive spectrometer(EDS)system and X-ray diffractometer(XRD). The results show that Cr(VI) in wastewater can be efficiently removed by Fe2+released from BOFS under appropriate acidic conditions. The removal of Cr(VI) by BOFS significantly depended on the parameters mentioned above. The reaction of Cr(VI) with BOFS followed the pseudo-second-order kinetic model. Fe2+responsible for Cr(VI) removal was primarily derived from the dissolution of Fe O and Fe3O4 in BOFS. When H2SO4 was used to adjust the solution acidity, gypsum(Ca SO4·2H2O)could be formed and become an armoring precipitate layer on the BOFS surface, hindering the release of Fe2+and the removal of Cr(VI). Finally, the main mechanism of Cr(VI) removal by BOFS was described using several consecutive reaction steps.Chong Han Yanan Jiao Qianqian Wu Wangjin Yang He Yang Xiangxin Xue 2016Journal of Environmental Sciences2016,28,8:4
7Fungal diversity in major oil-shale mines in China显示文摘As an insufficiently utilized energy resource,oil shale is conducive to the formation of characteristic microbial communities due to its special geological origins.However,little is known about fungal diversity in oil shale.Polymerase chain reaction cloning was used to construct the fungal ribosomal deoxyribonucleic acid internal transcribed spacer(r DNA ITS)clone libraries of Huadian Mine in Jilin Province,Maoming Mine in Guangdong Province,and Fushun Mine in Liaoning Province.Pure culture and molecular identification were applied for the isolation of cultivable fungi in fresh oil shale of each mine.Results of clone libraries indicated that each mine had over 50% Ascomycota(58.4%–98.9%)and 1.1%–13.5%unidentified fungi.Fushun Mine and Huadian Mine had 5.9% and 28.1% Basidiomycota,respectively.Huadian Mine showed the highest fungal diversity,followed by Fushun Mine and Maoming Mine.Jaccard indexes showed that the similarities between any two of three fungal communities at the genus level were very low,indicating that fungi in each mine developed independently during the long geological adaptation and formed a community composition fitting the environment.In the fresh oil-shale samples of the three mines,cultivable fungal phyla were consistent with the results of clone libraries.Fifteen genera and several unidentified fungi were identified as Ascomycota and Basidiomycota using pure culture.Penicillium was the only genus found in all three mines.These findings contributed to gaining a clear understanding of current fungal resources in major oil-shale mines in China and provided useful information for relevant studies on isolation of indigenous fungi carrying functional genes from oil shale.Shaoyan Jiang Wenxing Wang Xiangxin Xue Chengyou Cao Ying Zhang 2016Journal of Environmental Sciences2016,28,3:4
8Zircon U-Pb Geochronology and Geochemistry of the Early Cretaceous Volcanic Rocks from the Manitu Formation in the Hongol Area, Northeastern Inner Mongolia显示文摘We undertook zircon U-Pb dating and geochemical analyses of volcanic rocks from the Manitu Formation in the Hongol area,northeastern Inner Mongolia,to determine their age,petrogenesis and sources,which are important for understanding the Late Mesozoic tectonic evolution of the Great Xing'an Range.The volcanic rocks of the Manitu Formation from the Hongol area consist primarily of trachyandesite,based on their chemical compositions.The zircons from two of these trachyandesites are euhedral-subhedral in shape,display clear oscillatory growth zoning and have high Th/U ratios(0.31-1.15),indicating a magmatic origin.The results of LA-ICP-MS zircon U-Pb dating indicate that the volcanic rocks from the Manitu Formation in the Hongol area formed during the early Early Cretaceous with ages of 138.9-140.5 Ma.The volcanic rocks are high in alkali(Na_2O + K_2O = 6.22-8.26 wt%),potassium(K_2O = 2.49-4.58 wt%) and aluminium(Al_2O_3 = 14.27-15.88 wt%),whereas they are low in iron(total Fe_2O_3 = 3.76-6.53 wt%) and titanium(TiO_2 = 1.02-1.61 wt%).These volcanic rocks are obviously enriched in large ion lithophile elements,such as Rb,Ba,Th and U,and light rare earth elements,and are depleted in high field strength elements,such as Nb,Ta and Ti with pronounced negative anomalies.Their Sr-Nd-Pb isotopic compositions show positive ε_(Nd)(t)(+0.16‰ to+1.64‰) and low T_(DM)(t)(694-767 Ma).The geochemical characteristics of these volcanic rocks suggest that they belong to a shoshonitic series and were likely generated from the partial melting of an enriched lithospheric mantle that was metasomatised by fluids released from a subducted slab during the closure of the MongolOkhotsk Ocean.Elemental and isotopic features reveal that fractional crystallization with the removal of ferromagnesian minerals,plagioclase,ilmenite,magnetite and apatite played an important role during the evolution of the magma.These shoshonitic rocks were produced by the partial melting of the enriched lithospheric mantle in an extensional regime,which resulted from the gravitational collapse following the final closure of the Mongol-Okhotsk Ocean in the Middle-Late Jurassic.ZHANG Xiangxin SU Zhen GAO Yongfeng 2017Acta Geologica Sinica(English Edition)2017,91,4:3
9Effects of grazing disturbance of spatial distribution pattern and interspecies relationship of two desert shrubs显示文摘Grazing significantly affects the distribution,growth,and productivity of shrubs.In this study,we evalu-ated the effects of grazing disturbance on the spatial distri-bution patterns and interspecific relationships of two desert shrubs,Ammopiptanthus mongolicus and Sarcozygium xan-thoxylon.Three types of grazing conditions were considered,including enclosed area(EA),seasonal rotational grazing area(SRGA),and grazing area(GA)(100 m×100 m),in the West Ordos Nature Reserve of Inner Mongolia,China.The results showed that A.mongolicus and S.xanthoxylon populations were uniformly distributed at a small scale,and the distribution in EA and SRGA became gradually ran-dom.In GA,A.mongolicus population showed aggregated distribution but S.xanthoxylon population showed random distribution at a small scale. Moreover, both A. mongolicus and S. xanthoxylon populations at the 5-7 m scale showed random distribution. At the small and intermediate scales, the two species showed positive interspecific relationships of GA. However, no interspecific relationship was noted between the two species in EA and SRGA. A significant positive relationship (P < 0.01) was noted between the two species at 2-9 m and a negative relationship (P < 0.01) at 13-17 m scales in GA. Positive relationship (P < 0.01) was noted between the two species at 6-13 m scales and a sig-nificant negative relationship (P < 0.01) at 14-24 m scales in SRGA. The two species of desert shrubs showed posi-tive interspecific relationships at the small scale, and they showed negative relationships as the interspecific compe-tition intensified in the presence of grazing disturbance. When the grazing intensity exceeds a certain threshold, the interspecific relationships become weak. Therefore, moder-ate grazing would facilitate interspecific competition and species succession, whereas excessive grazing would disrupt natural competition causing desertification ultimately.Lei Zhang Yong Gao Jinrong Li Chao Zhang Minyu Li Zhao Hu Xiangxin Cui 2022Journal of Forestry Research2022,33,2:3
10Progress in researching into the transition of the Mesozoic tectonic systems in southeast China显示文摘这篇论文论述在东南中国用进 NE- NNE 西方的和平的领域构造的 E-W paleo-Tethyan 在中生代构造系统转变的研究上做的最近的进步。西方太平洋领域的 Tectonism 在中间的侏罗记开始了(J 2) 并且形成了一套趋势 NE 结构, non-coaxially 早并且同时代地在可以是的电子 trending 构造的带上套印由 paleo- Tethyan 领域生产了。因此从电子 trending paleo- Tethyan 开始了构造领域转变到在早白垩纪和平、充分完成的趋势 NE。东方 Nanling 区域是在中间的侏罗记的转变的一个连接地区(J 2), 并且此后,连接地区可能倾斜地移居到沿海的区域,在此是这个学习区域的东方部分。到 Nanling 区域的北方, Ganjiang 差错地区是在二个构造领域之间的边界。相应于构造系统的转变,中国从一个有压缩性的系统改变了到前的 SE 的地球动力学紧张的系统,继续直到中生代的结束,第三级。YU Xinqi WU Ganguo ZHANG Da ZHANG Xiangxin DI yongjun ZANG Wenshuan WANG Qunfeng HUANG Huojian 2006Progress in Natural Science:Materials International2006,16,6:3
11Dendrite-structured FeF_(2) consisting of closely linked nanoparticles as cathode for high-performance lithium-ion capacitors显示文摘Lithium-ion capacitors(LICs)are regarded as a good choice for next-generation energy storage devices,which are expected to exhibit high energy densities,high power densities,and ultra-long cycling stability.Nevertheless,only a few battery-type cathode materials with limited kinetic properties can be employed in LICs,and their electrochemical properties need to be optimized urgently.Here,we exploit a new dendrite-structured FeF_(2) consisting of closely linked primary nanoparticles using a facile solvothermal method combined with the subsequent annealing treatment.This particular architecture has favorable transport pathways for both lithium ions and electrons and exhibits an ultrafast chargedischarge capability with high reversible capacities.Furthermore,a well-designed LIC employing the prepared dendrite-structured FeF_(2) as the battery-type cathode and commercialized activated carbon(AC)as supercapacitor-type anode was constructed in an organic electrolyte containing Li ions.The LIC operates at an optimal voltage range of 1.1-3.8 V and shows a maximum high energy density of 152 W h kg^(-1) and a high power density of 4900 W kg^(-1) based on the total mass of cathode and anode.Long-term cycling stability(85%capacity retention after 2000 cycles)was achieved at 1 A g^(-1).This work suggests that the dendrite-structured FeF_(2) is a prime candidate for high-performance LICs and accelerates the development of hybrid ion capacitor devices.Huanyu Liang Zhengqiang Hu Zhongchen Zhao Dong Chen Hao Zhang Huaizhi Wang Xia Wang Qiang Li Xiangxin Guo Hongsen Li 2021Journal of Energy Chemistry2021,30,4:3
12Geochronology and Geochemistry of the Early Permian A-Type Granite in the Hongol Area, Central Inner Mongolia:Petrogenesis and Tectonic Implications显示文摘We performed geochronological and geochemical analyses of the A-type granite in the Hongol area, central Inner Mongolia, to determine its age, petrogenesis and tectonic setting, which are significant for clarifying the Late Paleozoic tectonic evolution of the Xing'an Mongolian Orogenic Belt(XMOB). The rock type of the A-type granite in the Hongol area is alkali-feldspar granite, and it constitutes a western part of the Baiyinwula-Dongujimqin A-type granite belt. Zircon U-Pb geochronology yields ^(206)Pb/^(238)U ages ranging from 293 to 286 Ma for the alkali-feldspar granite, indicating this granitic pluton formed in the Early Permian. The alkali-feldspar granite is high in silica(SiO_2=75.13 wt%-80.17 wt%), aluminum(Al_2 O_3=10.59 wt%-13.17 wt%) and alkali(Na_2 O+K_2 O=7.33 wt%-9.11 wt%), and low in MgO(0.08 wt%-0.39 wt%) and CaO(0.19 wt%-0.70 wt%). It is obviously enriched in LILEs such as Rb, Th and K,depleted in HFSEs such as Nb, Ti, La and Ce, with pronounced negative anomalies of Nb, Ti, P, Eu, Sr and Ba. Its Sr-Nd-Pb isotopic compositions show positive ε_(Nd)(t)(+0.72-+3.08), low T_(DM2)(805-997 Ma),and high radioactive Pb with(^(206)Pb/^(204)Pb)_i of 18.710-19.304,(^(207)Pb/^(204)Pb)_i of 15.557-15.604 and(^(208)Pb/^(204)Pb)_i of 37.887-38.330. Petrological characteristics and geochemical data suggest that the alkalifeldspar granite in the Hongol area belongs to aluminous A-type granite. This A-type granite formed in a post-collisional extensional setting and was generated by the partial melting of felsic rocks in the middlelower crust resulting from post-collisional slab breakoff. It is suggested that the Paleo-Asian Ocean was closed before the Permian in central Inner Mongolia.ZHANG Xiangxin GAO Yongfeng LEI Shihe 2018Acta Geologica Sinica(English Edition)2018,92,3:3
13Heterogeneous electrolyte membranes enabling double-side stable interfaces for solid lithium batteries显示文摘The solid polymer electrolyte(SPE) is one of the most promising candidates for building solid lithium batteries with high energy density and safety due to its advantages of flexibility and light-weight.However,the conventional monolayered electrolytes usually exhibit unstable contacts with either high-voltage cathodes or Li-metal anodes during cell operation.Herein,heterogeneous dual-layered electrolyte membranes(HDEMs) consisting of the specific functional polymer matrixes united with the designed solid ceramic fillers are constructed to address the crucial issues of interfacial instability.The electrolyte layers composed of the high-conductivity and oxidation-resistance polyacrylonitrile(PAN) combined with Li_(0.33)La_(0.557)TiO_(3) nanofibers are in contact with the high-voltage cathodes,achieving the compatible interface between the cathodes and the electrolytes.Meanwhile,the electrolyte layers composed of the highstability and dendrite-resistance polyethylene oxide(PEO) with Li_(6.4)La_(3) Zr_(1.4)Ta_(0.6)O_(12) nanoparticles are in contact with the Li-metal anodes,aiming to suppress the dendrite growth,as well as avoid the passivation between the PAN and the Li-metal.Consequently,the solid LiNi_(0.6)Co_(0.2)Mn_(0.2)O2‖Li full cells based on the designed HDEMs show the good rate and cycling performance,i.e.the discharge capacity of 170.1 mAh g^(-1) with a capacity retention of 78.2% after 100 cycles at 0.1 C and 30℃.The results provide an effective strategy to construct the heterogeneous electrolyte membranes with double-side stable electrode/-electrolyte interfaces for the high-voltage and dendrite-free solid lithium batteries.Shuang Mu Weilin Huang Wuhui Sun Ning Zhao Mengyang Jia Zhijie Bi Xiangxin Guo 2021Journal of Energy Chemistry2021,30,9:2
14Photocatalytic activity of Fe-doped CaTiO_3 under UV–visible light显示文摘The photocatalytic degradation of methylene blue(MB) over Fe-doped CaTiO3 under UV–visible light was investigated. The as-prepared samples were characterized using X-ray diffraction(XRD), scanning electron microscope(SEM) equipped with an energy dispersive spectrometer(EDS) system, Fourier transform infrared spectra(FT-IR), and UV–visible diffuse reflectance spectroscopy(DRS). The results show that the doping with Fe significantly promoted the light absorption ability of CaTiO3 in the visible light region. The Fe-doped CaTiO3 exhibited higher photocatalytic activity than CaTiO3 for the degradation of MB.However, the photocatalytic activity of the Fe-doped CaTiO3 was greatly influenced by the calcination temperature during the preparation process. The Fe-doped CaTiO3 prepared at500°C exhibited the best photocatalytic activity, with degradation of almost 100% MB(10 ppm)under UV–visible light for 180 min.He Yang Chong Han Xiangxin Xue 2014Journal of Environmental Sciences2014,26,7:2
15Development Status and Research Progress in Rare Earth Hydrometallurgy in China显示文摘Characteristic and hydrometallurgy processes for Baotou mixed-type rare earth concentrate, bastnasite, and ionic adsorption deposit in China were reviewed. The R & D circumstance and new progresses in extraction and separation of RE element in China were introduced. Moreover, the development trend of RE hydrometallurgy was predicted. The direction and emphasised fields of research and development are also brought forward as: to R & D high efficient green progresses in hydrometallurgy and separation of RE ore, resolve the waste pollution problem of water, slagand gas, reduce the chemical material consumption and improve comprehensive efficiency of resources; to R & D preparation technology for RE compounds with ultra high-purity and special physical property for extending application fields of RE.Huang Xiaowei Li Hongwei Xue Xiangxin Zhang Guocheng 2006Journal of Rare Earths2006,24,2:2
16Effects of boron number per unit volume on the shielding properties of composites made with boron ores from China显示文摘The total macroscopic removal cross sections,deposited energies and the absorbed doses of three new shielding composites loaded with specific boron-rich slag,boron concentrate ore and boron mud of China for 252Cf neutron source were investigated by experimental and Monte Carlo calculation.The results were evaluated by boron mole numbers per unit volume in composites.The half value layers of the composites were calculated and compared with that of Portland concrete,indicating that ascending boron mole numbers per unit volume in the composites can enhance the shielding properties of the composites for 252Cf neutron source.LI Zhefu XUE Xiangxin LIU Sulan LI Yong DUAN Peining 2012Nuclear Science and Techniques2012,23,6:2
17Sandwiched N-carbon@Co_(9)S_(8)@Graphene nanosheets as high capacity anode for both half and full lithium-ion batteries显示文摘Transition metal sulfides(TMSs) are promising candidates for replacing graphite anode in LIBs. However,the low conductivity and structural collapse caused by the large volume change during lithium insertion and extraction greatly limit its application. Herein, we report a unique design of a two-dimensional(2 D) sandwich structure of N-doped carbon@Co9 S8@graphene(N–C@Co9 S8@G) with multilayer structure. Electrochemical tests reveal that the N–C@Co9 S8@G nanosheets possess a high reversible capacity(1009 mAhg^(-1) at 0.1 Ag^(-1)), and excellent rate capability(422mAhg^(-1) at 10 Ag^(-1)) and long cycle life(853 m Ahg^(-1) at 1Ag^(-1) for 500 cycles). Experimental studies reveal that capacitive storage contributes to the high reversible capacity. The lithium storage kinetics are studied by Galvanostatic intermittent titration technique(GITT) and electrochemical impedance spectroscopy(EIS). Meanwhile, the potential of N–C@Co9 S8@G anode in a full cell using Li Co O2 as the cathode is also demonstrated, exhibiting a high reversible capacity of 300mAhg^(-1) cycles at 0.1Ag^(-1). The strategy proposed in this work paves the way to engineering high performance anodes in LIBs.Ningning Li Li Sun Kai Wana Sheng Xu Jun Zhang Xiangxin Guo Xianghong Liu 2020Journal of Energy Chemistry2020,29,12:2
18Porous, multi-layered piezoelectric composites based on highly oriented PZT/PVDF electrospinning fibers for high-performance piezoelectric nanogenerators显示文摘Piezoelectric nanogenerators(PENGs)that can harvest mechanical energy from ambient environment have broad prospects for multi-functional applications.Here,multi-layered piezoelectric composites with a porous structure based on highly oriented Pb(Zr_(0.52)Ti_(0.48))O_(3)/PVDF(PZT/PVDF)electrospinning fibers are prepared via a laminating method to construct high-performance PENGs.PZT particles as piezoelectric reinforcing phases are embedded in PVDF fibers and facilitate the formation of polarβphase in PVDF.The multi-layered,porous structure effectively promotes the overall polarization and surface bound charge density,resulting in a highly efficient electromechanical conversion.The PENG based on 10 wt%PZT/PVDF composite fibers with a 220µm film thickness outputs an optimal voltage of 62.0 V and a power of 136.9μW,which are 3.4 and 6.5 times those of 10 wt%PZT/PVDF casting film-based PENG,respectively.Importantly,the PENG shows a high sensitivity of 12.4 V·N^(−1),presenting a significant advantage in comparison to PENGs with other porous structures.In addition,the composites show excellent flexibility with a Young’s modulus of 227.2 MPa and an elongation of 262.3%.This study shows a great potential application of piezoelectric fiber composites in flexible energy harvesting devices.Xiangxin DU Zheng ZHOU Zhao ZHANG Liqin YAO Qilong ZHANG Hui YANG 2022Journal of Advanced Ceramics2022,11,2:2
19Multilayered structure of N-carbonenvelopediron oxide/graphene nanocomposites as an improved anode for Li-ion battery显示文摘Transition metal oxides with high capacity are considered a promising electrode material for lithium-ion batteries(LIBs).Nevertheless,the huge volume expansion and poor conductivity severely hamper their practical application.In this work,a carbon riveting method is reported to address the above issues by designing multilayered N-doped carbon(N-carbon) enveloped Fe3O4/graphene nanosheets.When evaluated as a negative electrode,the N-carbon/Fe3O4/graphene nanocomposites demonstrate greatly enhanced electrochemical properties compared with Fe3O4/graphene.The N-carbon/Fe3O4/graphene presents a superior reversible capacity(807 mAh/g) over Fe3O4/graphene(540 mAh/g).Furthermore,it affords a considerable capacity of 550 mAh/g at 1 A/g over 700 cycles,indicating supe rb cycling stability.The structure-property correlation studies reveal that the carbon riveting layer is essential for enhancing the lithium diffusion kinetics.The good electrochemical properties and effective structure design make the carbon riveting strategy quite general and reliable to manipulate high performance electrodes for future LIBs.Li Sun Kai Wang Ningning Li Jun Zhang Xiangxin Guo Xianghong Liu 2020Chinese Chemical Letters2020,31,9:2
20Use of the Jiaolong manned submersible for accurate mapping of deep-sea topography and geomorphology显示文摘High-resolution bathymetric side-scan sonar(BSSS) performs the functions of traditional side-scan sonar, while also providing a depth-sounding function that allows simultaneous measurement of seafloor topography and geomorphology. Submarine microtopography and microgeomorphology detection ability and advanced underwater acoustic digital communication are important technical capabilities of the Jiaolong manned submersible. High resolution BSSS achieved accurate detection of seafloor topography and geomorphology at a depth of 7000 m, and successful mapping of local microtopography and microgeomorphology in the Mariana Trench.Tongwei ZHANG Jialing TANG Zhengguang LI Yubin ZHOU Xiangxin WANG 2018Science China Earth Sciences2018,61,8:2
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