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| 1 | Risk analysis for clustered check dams due to heavy rainfall显示文摘Check dams are commonly constructed around the world for alleviating soil erosion and preventing sedimentation of downstream rivers and reservoirs.Check dams are more vulnerable to failure due to their less stringent flood control standards compared to other dams.Determining the critical precipitation that will result in overtopping of a dam is a useful approach to assessing the risk of failure on a probabilistic basis and for providing early warning in case of an emergency.However,many check dams are built in groups,spreading in several tributaries in cascade forms,comprising a complex network.Determining the critical precipitation for dam overtopping requires a knowledge of its upstream dams on whether they survived or were overtopped during the same storm,while these upstream dams in turn need the information for their upstream dams.The current paper presents an approach of decomposing the dam cluster into(1)the heading dam,(2)border dams,and(3)intermediate dams.The algorithm begins with the border dams that have no upstream dams and proceeds with upgraded maps without the previous border dams until all the dams have been checked.It is believed that this approach is applicable for small-scale check dam systems where the time lag of flood routing can be neglected.As a pilot study,the current paper presents the analytical results for the Wangmaogou Check Dam System that has 22 dams connected in series and parallel.The algorithm clearly identified 7 surviving dams,with the remaining ones being overtopped for a storm of 179.6 mm in 12 h,which is associated with a return period of one in 200 years. | Zuyu Chen Xieping Huang Shu Yu Wei Cao Weiqin Dang Yangqiang Wang | 2021 | International Journal of Sediment Research2021，36，2： | 9 |
| 2 | Photoreduction of CO_(2) in the presence of CH_(4) over g-C_(3)N_(4) modified with TiO_(2) nanoparticles at room temperature显示文摘CO_(2)reduction under simulated sunlight over photocatalysts has become an attractive researcher area recently.In this work,carbon nitride compounds modified by TiO_(2)nanoparticles(TNPs)have been used for the photoreduction of CO_(2)in the presence of CH_(4)at room temperature.Briefly,a series of noble-metal-free TNP-graphitic-carbon nitride(g-C_(3)N_(4),also abbreviated CN)photocatalysts with different TNPs loadings and calcination temperatures have been synthesized by a wet-chemical method.The characterization results of XRD,FTIR,SEM,TEM,BET,XPS,CO_(2)Adsorption,UV-vis,and PL demonstrate that the BET surface area and CO_(2)adsorption capacity have been improved after the calcination.Besides,the g-C_(3)N_(4)has been successfully coupled with the TNPs and a heterojunction has formed at their interface.These characters contribute to increase the photocatalytic activity of TNPs-CN toward reducing CO_(2)in the presence of CH_(4),and its'performance is better than bare g-C_(3)N_(4),Titania(P_(25))-CN,MgO-CN,or Cu_(2)O-CN.Orthogonal experiments are then carried out to investigate the sensitivity factors and optimum conditions.The sensitivity results show that the reaction pressure makes little difference on the photocatalysis results,which verifies the photoinduced CO_(2)-CH_(4)reaction has a tiny change in gas volume.In addition,under the optimum conditions,the turnover frequency(TOF)of CO after 4 h reaction can reach 9.98μmol g-cat.^(-1)h^(-1),and traces of ethane and ethylene have been detected during the reactions.In addition,surface acetate and carbonaceous deposit are found on the(20)TNPs-CN/450 surface after continuous 24 h irradiation under the optimum conditions,which resulting in the inactivation of the catalyst.Finally,possible reaction mechanisms have been proposed based on the results. | Ming Chen Jiachen Wu Chongchong Lu Xiao Luo Yangqiang Huang Bo Jin Hongxia Gao Xiaowen Zhang Morris Argyle Zhiwu Liang | 2021 | Green Energy & Environment2021，6，6： | 2 |
| 3 | Novel carbon-nitride based catalysts for enhanced CH_(4) reforming under visible light: From morphology to heterojunction design principles显示文摘The synthesis of high value-added chemical products using CO_(2)and CH_(4)is a promising CO_(2)conversion technology that can reduce greenhouse gas emissions while also alleviating the energy crisis.However,problems such as high energy consumption and strict reaction conditions in reforming process hinder the further development of the technology.In this work,carbon-nitrogen based composites were prepared for the first time according to the design principle from morphology to heterojunction,which is innovatively applied in the process of photocatalytic CH4reforming.Firstly,C_(3)N_(4)materials with different dimensions(D) are prepared and applied to a CO_(2)-CH_(4)photocatalytic system.Additionally,the 2D/2D TiO_(2)/g-C_(3)N_(4)heterostructure is constructed with the ultrasonic impregnation method to further improve charge generation,transfer,and separation efficiency.It is worth noting that the yield of CO reaches173.80 μmol g^(-1),and the catalytic performance is improved by 1546% compared to bulk C_(3)N_(4).Moreover,the physical and chemical properties of 2D/2D TiO_(2)/g-C_(3)N_(4)materials are studied using a variety of cha racterization methods.Furthermore,the work fu nction and adsorption energy of different C3N4/TiO_(2)models for CO_(2)adsorption are calculated by density functional theory(DFT).Then,a possible catalytic mechanism for photocatalytic CO_(2)and CH_(4) conversion is proposed based on DFT calculations and experimental results.This work provides a new technical route for the rapid conversion of CO_(2)and CH_(4) at room temperature,as well as a new research concept for achieving carbon neutrality. | Yufei Huang Ding Wei Ziyi Li Yu Mao Yangqiang Huang Bo Jin Xiao Luo Zhiwu Liang | 2023 | Journal of Energy Chemistry2023，，8： | 0 |
| 4 | A highly efficient La-modified ZnAl-LDO catalyst and its performance in the synthesis of dimethyl carbonate from methyl carbamate and methanol显示文摘In this paper,the highly efficient ZnAlLa layered double oxide(ZnAlLa-LDO)catalyst was evaluated and used in methyl carbamate(MC)alcoholysis synthesis of dimethyl carbonate.Under optimal conditions,the MC conversion was 33.5% and the dimethyl carbonate(DMC)selectivity was up to 92,4% at 443 K and in 9 h.The prepared catalysts were well characterized to investigate the effect on the catalytic performance and reaction catalysis mechanism.The experimental results show that the addition of La adjusted the structure and chemical properties of ZnAl composite oxide and that the synergistic effect among Zn,Al and La play a key role in adjusting the acid-base properties and stability of the catalyst,which definitely improved the DMC selectivity and catalytic stability.Based on the proposed reaction mechanism,two kinetic models of the catalytic reaction were established and modified:LangmuirHinshelwood and power-rate law kinetic model.The good agreement between kinetic models and experimental data showed that the power-rate law kinetic model based on the elementary reactions is a suitable model for providing a theoretical basis.The pre-exponential factor and activation energy of the main reaction are 5.77×10^(7)and 77.60 kJ·mol^(-1),respectively. | Mingxue Yin Bo Jia Kuiyi You Bo Jin Yangqiang Huang Xiao Luo Zhiwu Liang | 2023 | Chinese Journal of Chemical Engineering2023，61，9： | 0 |
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