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| 1 | A Hierarchically Porous Metal-Organic Framework from Semirigid Ligand for Gas Adsorption显示文摘层次地多孔的材料在便于集体运输和吸附和分离过程的改善效率起一个重要作用。在这份报纸,新策略被建议认识到一个层次地多孔的金属器官的框架([Cu 2(OH)(L)]·(DMF)0.8(FJU-11, H 3L=3,5-(4-carboxybenzyloxy ) 安息香的酸, DMF=N, N-dimethylformamide ) 经由使用半硬的多羧基的酸。有趣地, FJU-11 向公司 2 拥有大吸附能力和小 isosteric 热。为 FJU-11 的列突破实验在烟道气体的分离加亮它的潜在的申请。 | Lizhen Liu Yingxiang Ye Zizhu Yao Liuqin Zhang Ziyin Li Lihua Wang Xiuling Ma Qian-Huo Chen Zhangjing Zhang Shengchang Xiang | 2016 | Chinese Journal of Chemistry2016，34，2： | 4 |
| 2 | High proton conductivity in metalloring-cluster based metalorganic nanotubes显示文摘Two novel anionic single-walled metal-organic nanotubes(MONTs),[(CH_(3))_(2)NH_(2)][ln(cdc)(thb)].2DMF.9.5H_(2)O(FJU-105)and[(CH_(3))_(2)NH_(2)][ln(cdc)(H-btc)]-2DMA·11H_(2)O(FJU-106)(H_(2)cdc=9H-carbazole-3,6-dicarboxylic acid,H_(2)thb=2,5-thiophene dicarboxylic acid,H3btc=1,3,5-benzene tricarboxylic acid),are achieved by employing[ln_(6)(cdc)_(6)]^(6+)metalloring cluster with largest diameter as the secondary building blocks(SBUs).The inner surface of FJU-106 is functionalized by uncoordinated-COOH groups of the H-btc linkers,leading to a higher proton conduction than FJU-105.At 70℃,FJU-106 displays the proton conduction performances among MONTs,up to 1.80×10^(-2)S·cm(^-1).And FJU-105 and FJU-106 are the first examples of MONT proton conductors operating at subzero temperature. | Quanjie Lin Yingxiang Ye Lizhen Liu Zizhu Yao Ziyin Li Lihua Wang Chulong Liu Zhangjing Zhang Shengchang Xiang | 2021 | Nano Research2021，14，2： | 2 |
| 3 | Utilization of cationic microporous metal-organic framework for efficient Xe/Kr separation显示文摘The separation of xenon/krypton(Xe/Kr)mixtures plays a vital role in the industrial process of manufacturing high-purity xenon.Compared with energy-intensive cryogenic distillation,porous materials based on physical adsorption are very promising in the low-cost and energy-saving separation processes.Herein,we show that a cationic metal-organic framework(named as FJU-55)exhibits highly efficient Xe/Kr separation performance,which can be attributable to its uniform three-dimensional(3D)interconnection channels and the electro-positive features as the host framework.Moreover,FJU-55 demonstrates good Xe adsorption capacity of 1.41 mmol/g and excellent Xe/Kr selectivity of 10(298 K and 100 kPa),together with a high Qst value of 39.4 kJ/mol at low coverage area.The superior Xe/Kr separation performance of FJU-55 was further confirmed by the dynamic breakthrough experiments.Results obtained via molecular modeling studies have revealed that the suitable pore size and abundant accessible aromatic ligands in FJU-55 could offer strong multiple C–H∙∙∙Xe interactions,which play a collaborative role in this challenging gas separation task. | Lingshan Gong Ying Liu Junyu Ren Abdullah MAl-Enizi Ayman Nafady Yingxiang Ye Zongbi Bao Shengqian Ma | 2022 | Nano Research2022，15，8： | 1 |
| 4 | Advances of nanoparticles in transmucosal drug delivery显示文摘Transmucosal drug administration represents a potential strategy for enhancing treatment efficacy and reducing side effects by avoiding the first-pass effect into the systemic circulation and delivering therapeutics directly to the target disease site.However,many challenges still remain in its clinical application,including low drug availability and limited retention time in the mucosa.The burgeoning advancement of nanotechnologies offers great potential to overcome the above limitations,leveraging their distinct advantages of high drug-loading capacity and strong permeability.In this review,the latest developments of nanoparticles(NPs)in transmucosal drug delivery as well as their clinical applications are discussed. | Li Zhang Changwei Yang Yingxiang Song Tao Sheng Junyan Li Jicheng Yu Xiaohong Wu Xiao Ye | 2024 | Nano Research2024，17，4： | 0 |
| 5 | Microporous Nitrogen-Rich Polymers via Ullmann Coupling Reaction for Selective Adsorption of C_(2)H_(2) over CH_(4)显示文摘Acetylene purification from methane is challenging in the field of porous organic polymers(POPs).Herein,we have provided one-pot Ullmann coupling reaction to synthesize a series of POPs with rich N-sites,named FJU-POP-n,wherein the low-cost and non-toxic Cu(acac)2 and environmental-friendly glycerol are employed as catalyst and solvent,respectively. | Jitao Huang Qinfang Peng Chulong Liu Yingxiang Ye Liangji Chen Yuanchao Lv Yisi Yang Shimin Chen Fahui Xiang Hao Zhang Zhangjing Zhang Shengchang Xiang | 2023 | Chinese Journal of Chemistry2023，41，5： | 0 |
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