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| 1 | Fe/Fe2O3 nanoparticles anchored on Fe-N-doped carbon nanosheets as bifunctional oxygen electrocatalysts for rechargeable zinc-air batteries显示文摘有高催化的活动和稳定性玩的 Electrocatalysts 在有希望的可更新的精力技术的一个关键角色,例如燃料房间和金属空气电池。这里,我们报导 Fe/Fe 2 O 3 nanoparticles 在 Fe-N-doped 碳 nanosheets 上抛锚了(Fe/Fe 2 导出壳的做 N 的碳 nanodots 由一条简单热分解途径面对 FeCl 3 作为碳和氮采购的 O 3@Fe-N-C) 使用虾。Fe/Fe 2 O 3@Fe-N-C 在 1,000 的热分解温度获得了 ??????????? ″ ? 猼灵资 ? ??( ?? | Yipeng Zang Haimin Zhang Xian Zhang Rongrong Liu Shengwen Liu Guozhong Wang Yunxia Zhang Huijun Zhao | 2016 | Nano Research2016，9，7： | 10 |
| 2 | Meaningful comparison of photocatalytic properties of {001} and {101} faceted anatase TiO2 nanocrystals显示文摘The facet-dependent photocatalytic performance of TiO_2 nanocrystals has been extensively investigated due to their promising applications in renewable energy and environmental fields. However, the intrinsic distinction in the photocatalytic oxidation activities between the {001}and {101} facets of anatase TiO_2 nanocrystals is still unclear and under debate. In this work, a simple photoelectrochemical method was employed to meaningfully quantify the intrinsic photocatalytic activities of {001} and{101} faceted TiO_2 nanocrystal photoanodes. The effective surface areas of photoanodes with different facets were measured based on the monolayer adsorption of phthalic acid on TiO_2 photoanode surface by an ex situ photoelectrochemical method, which were used to normalize the photocurrents obtained from different faceted photoanodes for meaningful comparison of their photocatalytic activities. The results demonstrated that the {001} facets of anatase TiO_2 nanocrystals exhibited much better photocatalytic activity than that of {101} facets of anatase TiO_2 nanocrystals toward photocatalytic oxidation of water and organic compounds with different functional groups(e.g.,–OH, –CHO, –COOH). Furthermore, the instantaneous kinetic constants of photocatalytic oxidation of pre-adsorbates on {001} faceted anatase TiO_2 photoanode are obviously greater than those obtained at {101} faceted anatase TiO_2 photoanode, further verifying the higher photocatalytic activity of {001} facets of anatase TiO_2.This work provided a facile photoelectrochemical method to quantitatively determine the photocatalytic oxidation activity of specific exposed crystal facets of a photocatalyst, which would be helpful to uncover and meaningfully compare the intrinsic photocatalytic activities of different exposed crystal facets of a photocatalyst. | Yang Lu Yipeng Zang Haimin Zhang Yunxia Zhang Guozhong Wang Huijun Zhao | 2016 | Science Bulletin2016，61，13： | 8 |
| 3 | Nitrogen doped FeS_(2) nanoparticles for efficient and stable hydrogen evolution reaction显示文摘Performance breakthrough of electrocatalysts highly relies on the regulation of internal structures and electronic states.In present work,for the first time,we successfully synthesized nitrogen doped FeS_(2) nanoparticles(N-FeS_(2))as the electrocatalysts for hydrogen evolution reaction(HER).The band structure and electronic state of FeS_(2) are modulated by a nitrogen doping strategy,as confirmed by X-ray photoelectron spectroscopy(XPS),X-ray absorption spectroscopy(XAS)and density functional theory(DFT)calculations.Owing to the band structure and electronic state regulation as well as the weakening of H-S interaction,the designed N-FeS_(2) electrocatalyst exhibits superior catalytic performance with a low overpotential(~126 mV at 10 mA cm^(-2))and excellent activity stability under alkaline conditions,which is substantially improved as compared with that of the pure FeS_(2) counterpart.Our work demonstrates that the modulation of electron state and band structure of an electrocatalyst,which can provide a valuable guidance for designing excellent catalysts for hydrogen evolution reaction and beyond. | Jian Ye Yipeng Zang Qingyu Wang Yida Zhang Da Sun Leijie Zhang Gongming Wang Xusheng Zheng Junfa Zhu | 2021 | Journal of Energy Chemistry2021，30，5： | 2 |
| 4 | Tailoring the adsorption behavior of superoxide intermediates on nickel carbide enables high-rate Li-O_(2) batteries显示文摘Probing the relationship between the adsorption of superoxide species and the kinetics of Li-O_(2) chemistry is critical for designing superior oxygen electrodes for the Li-O_(2) battery,yet the modulation essence,especially at the atomic level,remains little understood.Herein,we reveal that the adsorption behaviors of superoxide species can be effectively regulated via a core-induced interfacial charge interaction,and we find that moderate adsorption strength can enable superior rate capability in a Li-O_(2) battery.More importantly,operando X-ray absorption near-edge structure and surface-enhanced Raman spectroscopy provide tools to monitor in situ the evolution of the superoxide intermediates and the electronic states of the catalyst's metal sites during the discharge and charge processes,and correlate these with the surface adsorption states.The concept of tuning adsorption behavior through interfacial charge engineering could open up new opportunities to further advance the development of the Li-O_(2) battery and beyond. | Yun Liu Jinyan Cai Jianbin Zhou Yipeng Zang Xusheng Zheng Zixuan Zhu Bo Liu Gongming Wang Yitai Qian | 2022 | eScience2022，2，4： | 1 |
| 5 | Orbital-regulated interfacial electronic coupling endows Ni3N with superior catalytic surface for hydrogen evolution reaction显示文摘The interstitial structure and weak Ni-N interaction of Ni3N lead to high unoccupied d orbital energy and unsuitable orbital orientation,which consequently results in weak orbital coupling with H2O and slow water dissociation kinetics for alkaline hydrogen evolution catalysis.Herein,we successfully lower the unoccupied d orbital energy of Ni3N to strengthen the interfacial electronic coupling by employing the strong electron pulling capability of oxygen dopants.The prepared O-Ni3N catalyst delivers an overpotential of 55 mV at 10 mA cm−2,very close to the commercial Pt/C.Refined structural characterization indicates the oxygen incorporation can decrease the electron densities around the Ni sites.Moreover,density functional theory calculation further proves the oxygen incorporation can create more unoccupied orbitals with lower energy and superior orientation for water adsorption and dissociation.The concept of orbital-regulated interfacial electronic coupling could offer a unique approach for the rational design of hydrogen evolution catalysts and beyond. | Yanyan Fang Da Sun Shuwen Niu Jinyan Cai Yipeng Zang Yishang Wu Linqin Zhu Yufang Xie Yun Liu Zixuan Zhu Amirabbas Mosallanezhad Di Niu Zheng Lu Junjie Shi Xiaojing Liu Dewei Rao Gongming Wang Yitai Qian | 2020 | Science China Chemistry2020，63，11： | 1 |
| 6 | Application of Serial Section Method to Determine the Radiotherapy Target Volume for Esophageal Squamous Carcinoma显示文摘 | Yipeng Song Yemin Liang Rukun Zang Likuan Hu Shiguan Zhu | 2013 | Cell Biochemistry and Biophysics2013，，： | 1 |
| 7 | Accelerating water dissociation kinetics of Ni3N by tuning interfacial orbital coupling显示文摘The high unoccupied d band energy of Ni_(3)N basically results in weak orbital coupling with water molecule,consequently leading to slow water dissociation kinetics.Herein,we demonstrate Cr doping can downshift the unoccupied d orbitals and strengthen the interfacial orbital coupling to boost the water dissociation kinetics.The prepared Cr-Ni_(3)N/Ni displays an impressive overpotential of 37 mV at 10 mA·cmgeo-2,close to the benchmark Pt/C in 1.0 M KOH solution.Refined structural analysis reveals the Cr dopant exists as the Cr-N_(6)states and the average d band energy of Ni_(3)N is also lowered.Density functional theory calculation further confirms the downshifted d band energy can strengthen the orbital coupling between the unpaired electrons in O 2p and the unoccupied state of Ni 3d,which thus facilitates the water adsorption and dissociation.The work provides a new concept to achieve on-demand functions for hydrogen evolution catalysis and beyond,by regulating the interfacial orbital coupling. | Yishang Wu Yufang Xie Shuwen Niu Yipeng Zang Jinyan Cai Zenan Bian Xuanwei Yin Yanyan Fang Da Sun Di Niu Zheng Lu Amirabbas Mosallanezhad Huijuan Wang Dewei Rao Hongge Pan Gongming Wang | 2021 | Nano Research2021，14，10： | 1 |
| 8 | Superior surface electron energy level endows WP_(2) nanowire arrays with N_(2) fixation functions显示文摘Nitrogen reduction reaction(NRR)under ambient conditions is always a long-standing challenge in science,due to the extreme difficulty in breaking the strong N≡N triple bond.The key to resolving this issue undoubtedly lies in searching superior catalysts to efficiently activate and hydrogenate the stable nitrogen molecules.We herein evaluate the feasibility of WP_(2) for N2 activation and reduction,and first demonstrate WP_(2) with an impressive ammonia yield rate of 7.13 lg h^(-1)cm^(-2),representing a promising W-based catalyst for NRR.DFT analysis further reveals that the NRR catalysis on WP_(2) proceeds in a distal reaction pathway,and the exceptional NRR activity is originated from superior surface electron energy level matching between WP_(2) and NRR potential which facilitates the interfacial proton-coupled electron transfer dynamics.The successfully unraveling the intrinsic catalytic mechanism of WP_(2) for NRR could offer a powerful platform to manipulate the NRR activity by tuning the electron energy levels. | Dongdong Han Xiaojing Liu Jinyan Cai Yufang Xie Shuwen Niu Yishang Wu Yipeng Zang Yanyan Fang Fengqi Zhao Wengang Qu Minghua Chen Gongming Wang Yitai Qian | 2021 | Journal of Energy Chemistry2021，30，8： | 0 |
| 9 | Design and experimental study of the fertilizer applicator with vertical spiral fluted rollers显示文摘To improve the uniformity and accuracy of fertilizing amount for fertilizer applicators with spiral fluted roller,this paper experimentally studied the influence of major structural parameters on the fertilizing performance.Through two sets of orthogonal tests,it is found that the helix angle and installation angle of spiral fluted rollers are the main factors,which affect the uniformity of fertilizer discharge and the linear relationship between fertilizing amount and opening,respectively.Based on these findings,the experiment and analysis were carried out to determine the optimal helix angle and installation angle for the spiral fluted roller The experimental results of fertilizing performance show that:when the helix angle is 45°,it able to achieve satisfactory uniformity of fertilizer discharge and linear relationship between fertilizing amount and rotational speed;when the installation angle is 40°,it enhances the accuracy of fertilizer discharge with good linear relationship between fertilizing amount and opening.Compared with the fertilizing performance of traditional fertilizer applicators with horizontally installed straight fluted roller,in the aspect of uniformity,the optimized fertilizer applicators reduce the variation coefficient of fertilizing amount within 0.2 s at low speed(10-30 r/min)from 5.1%-52.5%to 4.2%-14.7%;in the aspect of accuracy;and increase the correlation coefficient square R2 between fertilizing amount and opening from 0.93-0.97 to no less than 0.996,and the regression intercept in the fitting equation is reduced from larger than 10.0 to less than 1.0. | Yu Wang Yipeng Tan Silong Wei Mingming Liao Ying Zang Shan Zeng | 2023 | International Journal of Agricultural and Biological Engineering2023，16，5： | 0 |
| 10 | Amorphous Sn(HPO_(4))_(2)-derived phosphorus-modified Sn/SnO_(x) core/shell catalyst for efficient CO_(2) electroreduction to formate显示文摘Simultaneously achieving high activity,selectivity and stability for electrochemical CO_(2)reduction reaction(CO_(2)RR)remains great challenges.Herein,a phosphorus-modified Sn/Sn Oxcore/shell(P-Sn/SnO_x)catalyst,derived from in situ electrochemical reduction of an amorphous Sn(HPO_(4))_(2) pre-catalyst,exhibits high CO_(2)RR performance.The total Faradaic efficiency(FE)of C_(1) products is close to 100%in a broad potential range from-0.49 to-1.02 V vs.reversible hydrogen electrode,and a total current density of 315.0 m A cm^(-2)is achieved.Moreover,the P-Sn/SnO_(x) catalyst maintains a formate FE of~90%for 120 h.Density functional theory calculations suggest that the phosphorus-modified Sn/SnO_(x) core/shell structure effectively facilitates formate production by enhancing CO_(2)adsorption and improving free energy profile of formate formation. | Chunfeng Cheng Tianfu Liu Yi Wang Pengfei Wei Jiaqi Sang Jiaqi Shao Yanpeng Song Yipeng Zang Dunfeng Gao Guoxiong Wang | 2023 | Journal of Energy Chemistry2023，，6： | 0 |
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