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| 1 | Study of the seismic performance of expansion double spherical seismic isolation bearings for continuous girder bridges显示文摘The development of an expansion double spherical seismic isolation (DSSI) bearing by modifying the fixed DSSI bearing is described in this paper. The expansion DSSI bearing is characterized by its good energy dissipation and horizontal displacement capacity and has been successfully integrated into the seismic design of several important engineering projects in China. It is envisioned to be used as a substitute for ordinary expansion bearings in continuous girder bridges to distribute the longitudinal earthquake action among all the piers. Its development, configuration and working mechanism are introduced first. The test method and the seismic performance of an expansion DSSI bearing are then briefly described. A theoretical analysis followed by a numerical analysis for an actual four-span continuous girder bridge are provided as an example, and it is concluded that the expansion DSSI bearing can be integrated into the seismic design of continuous girder bridges. | Peng, Tianbo Yu, Xuntao Wang, Zhennan Han, Lei | 2012 | Earthquake Engineering and Engineering Vibration2012，11，2： | 11 |
| 2 | Reaction decoupling in thermochemical fuel conversion and technical progress based on decoupling using fluidized bed显示文摘Thermochemical conversion of fuels via pyrolysis/carbonization,cracking,gasification and combustion has to involve a number of individual reactions called attribution reactions to form an intercorrelated reaction network for any conversion process.By separating one or some attribution reactions from the others to decouple their interactions existing in the reaction network,the so-called reaction decoupling enables a better understanding of the complex thermal conversion process and further the optimization of the conditions for attribution reactions as well as the entire conversion process to realize advanced performances.The dual bed conversion and two-stage conversion are the two representative types of fuel conversion technologies developed in recent years based on reaction decoupling.Many technical advantages have been proven for such decoupling fuel conversion technologies,such as poly-generation of products,low-cost production of high-grade products,elimination of undesirable products or pollutants,easy operation and control,and so on.The treated fuels with decoupling conversion technologies mainly include solid biomass and coal,as well as liquid petroleum oil.This paper is devoted to reiteration of the reaction decoupling concept and further to reviewing the research,developments and successful applications of several decoupling fuel conversion technologies of two such types by using fluidized bed as their major reactors. | Zhennan Han Sulong Geng Xi Zeng Shipei Xu a Ping An Jiguang Cheng Jun Yang Feng Li Suyi Zhang Miao Liu Guoqing Guan Guangwen Xu | 2018 | Carbon Resources Conversion2018，1，2： | 8 |
| 3 | Characterization and pilot scale test of a fluidized bed two-stage gasification process for the production of clean industrial fuel gas from low-rank coal显示文摘To utilize low rank coal efficiently,a fluidized bed two-stage(FBTS)gasification process,mainly consisting of a FB pyrolyzer and a transport FB(TFB)gasifier,has been proposed for the production of clean fuel gas.To verify the feasibility and technical features of this novel gasification technology,a pilot autothermal platform,with a treating capacity of 100 kg/h for coal,was designed and built up.By adopting a kind of lignite from Inner Mongolia,the running state and fuel gas quality were compared systematically under typical operational conditions.The results show that by keeping the reaction temperatures of pyrolyzer and gasifier at around 840C and 1000C,respectively,the corresponding tar content in fuel gas at the outlets of pyrolyzer and gasifier were 1127 mg/Nm3 and 365 mg/Nm3,reaching a high tar removal efficiency.Under the stable operation state,the volume fractions of CO,H2,CH4 and CO2 in fuel gas were 14.4%,8.3%,3.4%and 11.3%,respectively,and the corresponding higher heating value of fuel gas was about 1100 kcal/Nm3.Compared with the tar from pyrolyzer,the heavy oil fraction in tar from gasifier reduced significantly,while the light oil components increased sharply simultaneously,showing significant effect of catalytic reforming by hot char bed on tar removal. | Xi Zeng Fang Wang Zhennan Han Yanlin Sun Yanbin Cui Guangwen Xu | 2018 | Carbon Resources Conversion2018，1，1： | 8 |
| 4 | Characteristics of gas-solid micro fluidized beds for thermochemical reaction analysis显示文摘Fuel conversion and clean energy reaction systems involve a variety of catalytic and non-catalytic gas-solid thermochemical reactions.A good understanding of the correct reaction mechanism and kinetics,as well as the profiles of reaction products,is of great significance to the development,design,and operation of such reaction systems.The micro fluidized bed reaction analysis provides an efficient and reliable method to acquire this essential information with low capital and operating costs,low energy consumption and enhanced safety.This paper provides an overview of the system and its characteristics for the micro fluidized bed reaction analyzer that has been well proven to be a reliable new approach as well as an instrument for characterizing various gas-solid thermochemical reactions. | Zhennan Han Junrong Yue Xi Zeng Jian Yu Fang Wang Shaozeng Sun Hong Yao Guangqian Luo Xuejing Liu Yining Sun Fu Ding Liangliang Fu Lei Shi Kangjun Wang Jiebin Yang Shaonan Wang Xueqing Chen Dingrong Bai Guangwen Xu | 2020 | Carbon Resources Conversion2020，3，1： | 6 |
| 5 | Recent progress in tar removal by char and the applications:A comprehensive analysis显示文摘Tar catalytic removal by char is a promising technology for gasification process because of its porous structure,good catalytic activity,low cost,and easy to treatment after deactivation.To provide comprehensive information on the tar catalytic removal by char,this study focuses on the ongoing efforts and advances from fundamental researches to the industrial applications.The tar removal efficiency by char much depends on reaction conditions and char property,such as char origin,porous structure,the functional group on char surface,carbon structure,and AAEM components.The typical reaction kinetics,reaction mechanism,and the deactivation,will be introduced.Then,for the different gasification processes,the potential or typical applications of tar removal by char are discussed and compared.Finally,a comprehensive analysis and improvement in scaling up,commercializing tar removal technologies and integrating the gasification process,are also evaluated and analyzed in this review. | Xi Zeng Yasuaki Ueki Ryo Yoshiie Ichiro Naruse Fang Wang Zhennan Han Guangwen Xu | 2020 | Carbon Resources Conversion2020，3，1： | 5 |
| 6 | Secondary cracking of volatile and its avoidance in infrared-heating pyrolysis reactor显示文摘This study aims to compare the pyrolysis behavior of Huadian oil shale in two infrared heating fixed bed reactors with different directions of infrared beam.Our previous work has shown that fast pyrolysis of oil shale conducted in the shallow fixed bed infrared heating reactor(co-current)presented the massive secondary reactions,which lowered the shale oil production(Siramard et al.,2017).Conversely,the cross-current infrared achieved shale oil yields higher than the Fischer Assay oil yield(13.07 wt%of dry basis),such as 117.7%of the Fischer Assay yield at our realized highest heating rate of 7℃/s under a specified pyrolysis temperature of 550℃.The shale oil from the cross-current infrared heating reactor was obviously heavier than the oil obtained from the cocurrent heating reactor.Thus,the infrared cross heating evidently suppressed the secondary reactions toward volatile.Our realized shale oil yield could reach 13.67 wt%or 122.5%of the Fischer Assay yield under reducing pyrolysis pressure of 0.6 atm,indicating that lower pressure is also beneficial to the release of volatile and reduction of the secondary cracking reactions.This work shows essentially that the infrared cross heating provides an effective merge of the advantages from quick heating and minimization of secondary cracking reactions to enable the shale oil yields being higher than the Fischer Assay oil yield. | Somprasong Siramard Jin-Hui Zhan Zhennan Han Shipei Xu Ondřej Mašek Guangwen Xu | 2018 | Carbon Resources Conversion2018，1，3： | 3 |
| 7 | Pyrolysis characteristics of waste tire particles in fixed-bed reactor with internals显示文摘This study investigated the characteristics of pyrolysis for waste tire particles in the newly developed fixed-bed reactor with internals that are a central gas collection channel mounted inside reactor.And a few metallic plates vertically welded on the internal wall of the reactors and extending to the region closing their central gas collection pipe walls.Experiments were conducted in two laboratory fixed bed reactors with or without the internals.The results shown that employing internals produced more light oil at externally heating temperatures above 700℃due to the inhibited secondary reactions in the reactor.The oil from the reactor with internals contained more aliphatic hydrocarbons and fewer aromatic hydrocarbons,leading to its higher H/C atomic ratios as for crude petroleum oil.The char yield was relatively stable for two beds and showed the higher heating values(HHVs)of about 23 MJ/kg.The gaseous product of pyrolysis mainly consisted of H2 and CH4,but the use of internals led to less pyrolysis gas through its promotion of oil production. | Shipei Xu Dengguo Lai Xi Zeng Lijuan Zhang Zhennan Han Jiguang Cheng Rongcheng Wu Ondřej Mašek Guangwen Xu | 2018 | Carbon Resources Conversion2018，1，3： | 3 |
| 8 | Energy-saving strategy for a transport bed flash calcination process applied to magnesite显示文摘A transport bed flash calcination(TBFC)process applied to magnesite is systematically investigated through process simulation to optimize the energy-saving strategy.The high-temperature calciner flue gas is used to preheat the fed magnesite,while the sensible heat with the caustic calcined magnesia(CCM)product is cooled by air sent to the calciner.Pre-decomposition of magnesite during preheating is considered on basis of the kinetics measured using a micro fluidized bed reaction analyzer that allows the minimized effect of external diffusion on reaction.With staged fuel gas supply the TBFC process allows the equivalence ratios around 1.2 for combustion.The preferred arrangement of stages for magnesite preheating and CCM cooling are respectively 4 and 2,leading to the energy consumption of 4100 kJ/kg-CCM and the energy efficiency of 66.8%,which is almost doubly higher than the 33.9%of the conventional reverberatory furnaces(RF).The pre-decomposition occurs mainly in the 1st-stage preheater,and the maximal conversion is about 13%.Varying the stages of preheating appears more influential on the energy saving than varying the cooling stages,while residence time above 1 s in the preheaters has limited effect. | Ping An Zhennan Han Kangjun Wang Jiguang Cheng Zhongkai Zhao Yohanes Andre Situmorang Jenny Rizkiana Abuliti Abudula Guoqing Guan | 2021 | Carbon Resources Conversion2021，4，1： | 1 |
| 9 | ReaxFF molecular dynamic simulation of primary and secondary reactions involving in sub-bituminous coal pyrolysis for tar production显示文摘ReaxFF molecular dynamic simulation combined with experimental verification was performed to understand the overall reaction mechanism,especially the primary and secondary reactions involving in tar formation of sub-bituminous coal pyrolysis.Quantitative relationship at atomic level is clarified between bond breakage of functional groups and products generation,revealing that the amount and order in forming each product are subject to the number of corresponding functional groups and their bond energies respectively.The primary breakage of-C-O-and-C-C-bridge-bonds present in initial coal macromolecular generates molecular of heavy tar,whereas heavy tar can be converted into light tar through cracking side chain of aromatic rings and cyclic hydrocarbons at increased pyrolysis temperatures.At very high temperatures the cracking of short-chain hydrocarbons and residual atoms connecting to aromatic rings further occurs to generate light tar and gas.The remaining aromatic-ring fragments of heavy tar are likely cross-linked to form char.Furthermore,the simultaneous evolution tendency of tar yield and tar quality under different pyrolysis temperatures and heating rates is obtained at molecular level.For obtaining high yield and quality of tar,appropriately high temperature as well as suitable heating rate are needed to compromise the high yield of primary tar and high quality of secondarily upgraded products. | Yanan Qian Jin-Hui Zhan Wei Xu Zhennan Han Xiaoxing Liu Guangwen Xu | 2021 | Carbon Resources Conversion2021，4，1： | 1 |
| 10 | Synergetic NO reduction by biomass pyrolysis products simulating their reburning in circulating fluidized bed decoupling combustion显示文摘The present work investigated the synergetic effect of pyrolysis-derived char,tar and gas(py-gas)on NO reduction,which may occur in circulating fluidized-bed decoupling combustion(CFBDC)system treating N-rich fuel.Experiments were carried out in a lab-scale drop-tube reactor for NO reduction by some binary mixtures of reagents including char/py-gas,tar/py-gas and tar/char.At a specified total mass rate of0.15 g·min^-1 for NO-reduction reagent,the char/py-gas(binary reagent)enabled the best synergetic NO reduction in comparison with the others.There existed effective interactions between char and some species in py-gas(i.e.,H2,CxHy)during NO reduction by pyrolysis products,meanwhile the tar/py-gas or tar/char mixture only caused a positive effect when tar proportion was necessarily lowered to about 26%.On the other hand,the synergetic effects were not improved for all tested binary reagents by increasing the reaction temperature and residence time. | Hai-Sam Do Tuyet-Suong Tran Zhennan Han Xi Zeng Shiqiu Gao Guangwen Xu | 2019 | Chinese Journal of Chemical Engineering2019，27，7： | 1 |
| 11 | Hydrothermal pretreatment of protein-rich substrate:Modified physicochemical properties and consequent responses in its anaerobic digestion显示文摘Wasted tofu rich in protein was subject to hydrothermal pretreatment(HTPT)under different conditions(at 120,140,160 and 180℃;for 0,30,60 and 90 min)followed by biochemical methane potential(BMP)tests,and 140℃and 0 min were found to be respectively the best temperature and duration for HTPT of tofu in terms of its biogas production.Under the under the optimal conditions(140℃,0 min)the accumulative methane yield reached up to 510.9 mL⋅(gVS)-1,which was 26.98%higher than that without HTPT(402.3 mL⋅(gVS)-1).The start-up process of continuous anerobic digestion(AD)of the tofu before and after hydrothermal treated(HT)at the optimal HTPT conditions(140℃,0 min)was examined,to investigate and compare how their consequent AD responded to HTPT.It was found that,for start-up of continuous AD,the HT tofu delivered more balanced nutrients and thus led to more stable AD and quicker biogas production.Unavoidably,HTPT generated products refractory to biodegradation,to slightly decrease the total biogas production.During AD of HT tofu some weak ammonia-tolerant microbes,such as methylotrophic methanogens,survived and played indispensable roles.Analyses of living microbial community structure indicated that,some hydrolytic acidification bacteria intolerant to ammonia nitrogen(such as Proteobacteria)were always active and appeared at high proportion.The viable methylotrophic methanogens,e.g.RumEn M2,took obvious responsibilities in start-up of the AD for HT tofu. | Fa Qiao Guangyi Zhang Jie Fan Hang Zhang Bowen Shi Jiancheng Yang Jianling Zhang Zhennan Han | 2023 | Carbon Resources Conversion2023，6，1： | 0 |
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