|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Phosphogypsum stabilization of bauxite residue:Conversion of its alkaline characteristics显示文摘Reduction of the high alkalinity of bauxite residue is a key problem to solve to make it suitable for plant growth and comprehensive utilization. In this study, phosphogypsum, a waste product from the phosphate fertilizer industry, was used to drive the alkaline transformation of the bauxite residue. Under optimal water washing conditions(liquid/solid ratio of 2 mL/g, 30°C, 24 hr), the impact of quantity added, reaction time and reaction mechanism during phosphogypsum application were investigated. Phosphogypsum addition effectively lowered p H levels and reduced the soluble alkalinity by 92.2%. It was found that the concentration of soluble Na and Ca ions in the supernatant increased gradually, whilst the exchangeable Na+and Ca^(2+)in solid phase changed 112 mg/kg and 259 mg/kg, respectively. Ca^(2+)became the dominant element in the solid phase(phosphogypsum addition of 2%, liquid/solid ratio of 2 mL/g, 30°C, 12 hr). X-ray diffraction data indicated that cancrinite and hydrogarnet were the primary alkaline minerals. SEM images suggested that phosphogypsum could promote the formation of stable macroaggregates, whilst the content of Ca^(2+)increased from 5.6% to 18.2% and Na reduced from 6.8% to 2.4%. Treatment with phosphogypsum could significantly promote the transformation of alkalinity cations by neutralization, precipitation and replacement reactions.This research provided a feasible method to promote soil formation of bauxite residue by phosphogypsum amendment. | Shengguo Xue Meng Li Jun Jiang Graeme J.Millar Chuxuan Li Xiangfeng Kong | 2019 | Journal of Environmental Sciences2019，31，3： | 35 |
| 2 | Lanthanide NIR luminescence for telecommunications, bioanalyses and solar energy conversion显示文摘Present-day advanced technologies heavily rely on the exciting magnetic and spectroscopic properties of lanthanide ions. In particular, their ability to generate well-characterized and intense near-infrared (NIR) luminescence is exploited in any modern fiber-optic telecommunication network. In this feature article, we first summarize the whereabouts underlying the design of highly luminescent NIR molecular edifices and materials. We then focus on describing the main trends in three applications related to this spectral range: telecommunications, biosciences, and solar energy conversion. In telecommunications, efforts concentrate presently on getting easily processable polymer-based waveguide amplifiers. Upconversion nanophosphors emitting in the visible after NIR excitation are now ubiquitous in many bioanalyses while their application to bio-imaging is still in its early stages; however, highly sensitive NIR-NIR systems start to be at hand for both in vitro and in vivo imaging, as well as dual probes combining magnetic resonance and optical imaging. Finally, both silicon-based and dye-sensitized solar cells benefit from the downconversion and upconversion capabilities of lanthanide ions to harvest UV and NIR solar light and to boost the overall quantum efficiency of these next-generation devices. | Jean-Claude G. Bünzli Svetlana V. Eliseeva | 2010 | Journal of Rare Earths2010，28，6： | 22 |
| 3 | He^+离子辐照后Hastelloy N合金的耐腐蚀性研究显示文摘高温、辐照以及强腐蚀所引起的Hastelloy N合金的失效问题是影响熔盐堆(Molten Salt Reactor,MSR)结构材料使用寿命中的关键问题。在常温下用4.5 MeV的He+离子辐照Hastelloy N合金,吸收剂量分别为:1×1015 He+·cm-2、5×1015He+·cm-2、1×1016 He+·cm-2,采用浸入法在700°C熔融氟化盐(FLiNaK)中进行300 h腐蚀试验,研究辐照剂量对合金耐腐蚀性的影响。利用扫描电子显微(Scanning Electron microscope,SEM)、同步辐射微束X射线荧光分析(Microbeam X-ray fluorescence,μ-XRF)对腐蚀后的样品进行分析测试。结果表明,随着辐照剂量的增大,合金的耐腐蚀性逐渐减弱。μ-XRF结果表明:Hastelloy N合金在熔融氟化盐中的腐蚀主要表现为合金中Cr元素的流失。 | 林建波 李爱国 何上明 余笑寒 | 2014 | 核技术2014，37，5： | 11 |
| 4 | Multi-component assembly of luminescent rare earth hybrid materials显示文摘This review focuses on the recent research progress in the multi-component assembly of luminescent rare earth hybrid materials, which is based on the luminescent rare earth compounds and two or more other building units, including the other photoactive species. It covers the multi-component luminescent rare earth hybrids which was assembled with different(a) organic-inorganic polymeric units,(b)nanoporous units,(c) nanoparticle composites or(d) other developing special units. Finally, future challenges and opportunities in this field are discussed. Herein it mainly focuses on the work of Yan's group in recent years. | Qiuping Li Bing Yan | 2019 | Journal of Rare Earths2019，37，2： | 10 |
| 5 | Luminescent characterization of rare earth Dy^(3+) ion doped TiO_2 prepared by simple chemical co-precipitation method显示文摘Pure and rare-earth ion (Dy^(3+)) doped TiO_2 nanomaterials were prepared through a chemical coprecipitation method. The chemical composition, micro structure and optical properties were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-visible spectroscopy and photo luminescence (PL). XPS analysis reveals that Dy^(3+)ions are preferentially occupied in the TiO_2 crystallite lattices. Both the XRD and TEM analyses confirm that both the pure and Dy doped TiO_2 are in pure anatase phase and in nano size range, respectively. Also it is found that the maximum solubility limit for Dy^(3+) ions is found to be 0.4%in TiO_2 matrix, above which it occupies interstitials and/or crystallite surface of TiO_2 nanocrystals. From the UV-Vis spectroscopy studies it is found that Dy doping induces blue shift in TiO_2. From the PL analysis it is found that doping Dy^(3+) improves the luminescence behavior in comparison with the pure TiO_2 nanoparticles.Overall, doping very low concentrations of Dy^(3+) greatly alters the structural morphology and directly increases the luminescence behavior of TiO_2 suitable for advanced optoelectronic applications. | Mohamed Zikriya Y.F.Nadaf P.Vijai Bharathy C.G.Renuka | 2019 | Journal of Rare Earths2019，37，1： | 9 |
| 6 | Ultra low frequency waves impact on radiation belt energetic particles显示文摘One of the most fundamental important issues in the space physics is to understand how solar wind energy transports into the inner magnetosphere.Ultra low frequency(ULF)wave in the magnetosphere and its impact on energetic particles,such as the wave-particle resonance,modulation,and particle acceleration,are extremely important topics in the Earth’s radiation belt dynamics and solar wind― magnetospheric coupling.In this review,we briefly introduce the recent advances on ULF waves study. Further,we will explore the density structures and ion compositions around the plasmaspheric boundary layer(PBL)and discuss its possible relation to the ULF waves. | ZONG QiuGang HAO YongQiang WANG YongFu | 2009 | Science China(Technological Sciences)2009，52，12： | 7 |
| 7 | Heavy-ion and pulsed-laser single event effects in 130-nm CMOS-based thin/thick gate oxide anti-fuse PROMs显示文摘Single event effects of 1-T structure programmable read-only memory(PROM) devices fabricated with a 130-nm complementary metal oxide semiconductorbased thin/thick gate oxide anti-fuse process were investigated using heavy ions and a picosecond pulsed laser. The cross sections of a single event upset(SEU) for radiationhardened PROMs were measured using a linear energy transfer(LET) ranging from 9.2 to 95.6 MeV cm^2mg^(-1).The result indicated that the LET threshold for a dynamic bit upset was ~ 9 MeV cm^2mg^(-1), which was lower than the threshold of ~ 20 MeV cm^2mg^(-1) for an address counter upset owing to the additional triple modular redundancy structure present in the latch. In addition, a slight hard error was observed in the anti-fuse structure when employing209 Bi ions with extremely high LET values(~ 91.6 MeV cm^2mg^(-1)) and large ion fluence(~ 1×10~8 ions cm^(-2)). To identify the detailed sensitive position of a SEU in PROMs, a pulsed laser with a 5-μm beam spot was used to scan the entire surface of the device.This revealed that the upset occurred in the peripheral circuits of the internal power source and I/O pairs rather than in the internal latches and buffers. This was subsequently confirmed by a ^(181)Ta experiment. Based on the experimental data and a rectangular parallelepiped model of the sensitive volume, the space error rates for the used PROMs were calculated using the CRèME-96 prediction tool. The results showed that this type of PROM was suitable for specific space applications, even in the geosynchronous orbit. | Chang Cai Tian-Qi Liu Xiao-Yuan Li Jie Liu Zhan-Gang Zhang Chao Geng Pei-Xiong Zhao Dong-Qing Li Bing Ye Qing-Gang Ji Li-Hua Mo | 2019 | Nuclear Science and Techniques2019，30，5： | 7 |
| 8 | Iterative inversion of global magnetospheric information from energy neutral atom (ENA) images recorded by the TC-2/NUADU instrument显示文摘A method is presented for retrieving the magnetospheric ion distribution from En-ergetic Neutral Atom (ENA) measurements made by the NUADU instrument on the TC-2 spacecraft. Based on the already well-established method of constrained lin-ear inversion, an iterance technique suitable for the low count ENA measurements has been developed which is tolerant of the noise background. By the iterance technique, it is possible for the first time to simultaneously retrieve the magneto-spheric ion distribution and the exospheric neutral density, and further to recover global ENA emissions in three dimensions. The technique is applied to a repre-sentative ENA image recorded in energy channel 2 (protons: 50―81 keV) of the NUADU instrument during a major geomagnetic storm and it is, thereby, shown that the retrieval method developed provides a useful tool for extracting ion distribution information from ENA data. | S. MCKENNA-LAWLOR S. BARABASH J. BALAZ | 2008 | Science China(Technological Sciences)2008，51，10： | 6 |
| 9 | Effect of Sulfate Ions on YAG Powders Synthesized by Microwave Homogeneous Precipitation显示文摘Using Al(NO3)3·9H2O, NH4Al(SO4)2·12H2O, Y(NO3)3 as mother salts, and urea as precipitant, YAG nano-powders were synthesized by microwave homogeneous precipitation. The composition, morphology, and phase transformation of precursor were analyzed by IR, XRD and TEM. The size distribution of YAG powders was characterized using laser diffraction method. The results show that sulfate ions influence the dispersion, composition and morphology of the YAG precursors. The addition of moderate sulfate ions can produce YAG powders with nano size and excellent dispersion at 1100 ℃. | 王介强 徐红燕 王勇 岳云龙 | 2006 | Journal of Rare Earths2006，24，z2： | 6 |
| 10 | Evaluation of D113 cation exchange resin for the removal of Eu(Ⅲ) from aqueous solution显示文摘Batch adsorption experiments were conducted for the adsorption of Eu(Ⅲ) ions from aqueous solution by D113 resin. The results indicated that D113 resin could adsorb Eu(Ⅲ) ion effectively from aqueous solution. The adsorption was strongly dependent on pH of the medium with enhanced adsorption as the pH turned from 3.50 to 7.00 and the optimal adsorption condition was in HAc-NaAc medium with pH value of 6.50. The maximum uptake capacity of Eu(Ⅲ) ions was 290.9 mg/g D113 at 298 K, at an initial pH value of 6.50. The overall adsorption process was best described by Lagergren-first-order kinetics. When Freundlich and Langmuir isotherms were tested, the latter had a better fit with the experimental data. The thermodynamic parameters such as free energy (G) which were all negative, indicated that the adsorption of Eu(Ⅲ) ions onto D113 resin was spontaneous and the positive value of enthalpy (H) showed that the adsorption was endothermic in nature. Thomas model was applied to experimental column data to determine the characteristic parameters of column useful for process design. Furthermore, Eu(Ⅲ) could be eluted by using 3.0 mol/L HCl solution and the D113 resin could be regenerated and reused. | 熊春华 郑展望 | 2010 | Journal of Rare Earths2010，28，6： | 6 |
| 11 | Lead-free thermochromic perovskites with tunable transition temperatures for smart window applications显示文摘The structural flexibility of hybrid perovskite materials allows for phase transition and consequently thermochromic properties.Here we investigate the thermochromic performance in a series of copper-based layered perovskites with organic cations having different alky chain lengths. Their transition temperature is found to be dependent on the organic cations due to molecular motion and hydrogen bond interaction, providing possibilities to prepare thermochromic semiconductors near room temperature for smart window applications. | Jingwen Li Xiaolong Liu Peixin Cui Junmeng Li Tao Ye Xi Wang Chuang Zhang Yong Sheng Zhao | 2019 | Science China Chemistry2019，62，9： | 6 |
| 12 | First-principles calculations on implanted TiO_2 by 3d transition metal ions显示文摘3d transition metal (V, Cr and Fe) ions are implanted into TiO2 by the method of metal ion implantation. The electronic band structures of TiO2 films doped 3d transition metal ions have been analyzed by ab initio band calculations based on a self-consistent full-potential linearized augmented plane-wave method within the first-principle formalism. Influence of implantation on TiO2 films is examined by the method of UV-visible spectrometry. The results of experiment and calculation show that the optical band gap of TiO2 films is narrowed by ion implantation. The calculation shows that the 3d state of V, Cr and Fe ions plays a significant role in red shift of UV-Vis absorbance spectrum. | HOU XingGang1,2, HUANG MeiDong1, WU XiaoLing2 & LIU AnDong2 1 Department of Physics, Tianjin Normal University, Tianjin 300387, China 2 Key Laboratory of Beam Technology and Material Modification of Ministry of Education, Beijing Normal University, Beijing 100875, China | 2009 | Science China(Physics,Mechanics & Astronomy)2009，52，6： | 6 |
| 13 | Micronuclei and cell survival in human liver cancer cells irradiated by 25MeV/u^(40)Ar^(14+)显示文摘INTRODUCTIONHeavyionswithhighlinearenergytransfer(LET)havethefolowingadvantagesascomparedwiththeconventionalXraysandγraysth... | LI Wen Jian 1, GAO Qing Xiang 2, ZHOU Guang Ming 1 and WEI Zeng Quan 1 | 1999 | World Journal of Gastroenterology1999，5，4： | 5 |
| 14 | Effects of lanthanide ions on hydrolysis of phosphatidylin-ositol in human erythrocyte membranes显示文摘The effects of lanthanides on the hydrolysis of phosphatidylinositol in human erythrocyte membranes were studied. 3H-inositoI labeling chromatography and HPLC were used to determine inositol 1, 4, 5-triphosphatc and dia-cylglycerol separately, the hydrolytic products of phosphatidylinositol due to the reaction of lanthanide ions with human erythrocyte membranes. The unhydrolyzed phosphatidylinositol in membranes was also determined. The results indicate that the hydrolysis of phosphatidylinositol can be promoted by lanthanides (La3+, Ce3+, Y3+, Tb3+) and the effects of La3+ and Ce3+ are stronger than those of Y3+ and Tb3+. | Huixue Liu Jian Hu Xiangtao Liu Rongchang Li Kui Wang | 2001 | Chinese Science Bulletin2001，46，5： | 5 |
| 15 | Selective removal of heavy metal ions in aqueous solutions by sulfide-selector intercalated layered double hydroxide adsorbent显示文摘Remaining largely under-appreciated, a majority of metal ion sorbents are limited in their target selectivity. In this work, a 3D sulfide intercalated NiFe-layered double hydroxide (NFL-S) hierarchical sorbent has been synthesized for selective heavy metal removal. The intercalation of sulfurated groups in the interlayer of the layered double hydroxide (LDH) nanosheets endows NFL-S as a selective heavy metal ion filter;the selectivity of NFL-S for heavy metals is in the order of Pb^2+> Cu^2+≥ Zn^2+> Cd^2+> Mn^2+, and NFL-S has high kd values for Pb2+(~10^6 mL/g) and Cu2+(~10^5 mL/g). Scanning electron microscopy. X-ray photoelectron spectroscopy and powder X-ray diffraction were used to analyze the composition of the as-prepared nanoadsorbent. The selective adsorption behavior was systematically studied using batch experiments, and the performance was evaluated through kinetic and isotherm studies. Moreover, the adsorption mechanism of heavy metals by NFL-S through surface complexation was also investigated, which shows great potential for water decontamination. | Jing Wang Liang Zhang Tianshu Zhang Ting Du Tao Li Tianli Yue Zhonghong Li Jianlong Wang | 2019 | Journal of Materials Science & Technology2019，35，9： | 5 |
| 16 | Efficient improvement of 2.7 μm luminescence of Er^(3+):oxyfluoride glass containing gallium by Yb^(3+) ions codoping显示文摘Mid-infrared laser materials with low phonon energy have significant applications. However, the development of available glass systems for high-power laser gain medium have posed a great challenge.Therefore, we investigated the 2.7 μm spectroscopic properties of Er^(3+)/Yb^(3+) -codoped oxyfluoride glass containing gallium, which were prepared by typically melting and quenching methods. The 2.7 μm luminescence properties of the Er^(3+)/Yb^(3+)-codoped oxyfluoride glass containing gallium were recorded by a 980 nm laser diode. The Judde Ofelt parameters, decay curves, emission cross section, energy transfer efficiency and quantum efficiency were calculated. The maximum emission cross section of YbFGa-0.5 is 1.63 × 10^(-20) cm^2 by 980 nm excitation. The energy transfer efficiency is calculated to be77.8% for the YbFGa-0.5 glass around 2700 nm. The quantum efficiency at 1530 nm is 65.6%. The result reveals that the best doping concentration ratio of Er^(3+):Yb^(3+) ions is 1:0.5, and suggests an effective energy transfer from Yb^(3+) to Er^(3+) ions. | Yapei Peng Xinqiang Yuan Long Zhang Peiguang Yan Wenfei Zhang Shuangchen Ruan | 2019 | Journal of Rare Earths2019，37，5： | 5 |
| 17 | Effect of Mixing on Properties and Microstructure of Magnesium Oxychloride Cement显示文摘This paper investigated the effect of mixing on the properties of magnesium oxychloride cement, such as apparent viscosity, setting time, compressive strength, and specific strength as well. The phase composition and crystallographic structure of the cement were determined by X-ray diffraction and scanning electron microscopy. The results indicate that the increases of stirring rate and mixing time change apparent viscosity distinctly, shorten setting time and enhance mechanical property. Magnesium oxychloride cement after mixing for 20 min exhibits the optimal mechanical performance. The effect of stirring rate on the phase composition of magnesium oxychloride cement dominates over the effect of mixing time. The increases of stirring rate and mixing time can increase the dispersion state and accelerate the neutralization, thus promoting the strength of magnesium oxychloride cement due to the formation of stable 5·1·8 phase, needle-like crystals and continuous crystalline structure in the whole cement matrix. The properties and microstructure of magnesium oxychloride cement at a stirring rate of 280 rpm are better than those at 140 rpm. | HE Zhenhui YANG Hongjian SONG Hui GUO Tao WU Songyi | 2016 | Journal of the Chinese Ceramic Society2016，，1： | 5 |
| 18 | Effect of amendments on the leaching behavior of alkaline anions and metal ions in bauxite residue显示文摘A column leaching experiment was used to investigate the efficacy of amendments on their ability to remove alkaline anions and metal ions from bauxite residue leachates.Treatments included,simulated acid rain (AR),phosphogypsum + vermicompost (PVC),phosphogypsum + vermicompost + simulated acid rain (PVA),and biosolids + microorganisms (BSM) together with controls (CK).Results indicated that amendment could effectively reduce the leachate pH and EC values,neutralize OH-,CO32-,HCO3-,and water soluble alkali,and suppress arsenic (As) content.Correlation analysis revealed significant linear correlations with pH and concentrations of OH-,CO32-,HCO3-,water-soluble alkali,and metal ions.BSM treatment showed optimum results with neutralizing anions (OH-,CO32-,and HCO3-),water soluble alkali,and removal of metal ions (Al,As,B,Mo,V,and Na),which was attributed to neutralization from the generation of small molecular organic acids and organic matter during microbial metabolism.BSM treatment reduced alkaline anions and metal ions based on neutralization reactions in bauxite residue leachate,which reduced the potential pollution effects from leachates on the soil surrounding bauxite residue disposal areas. | Tao Tian Jinaju Zhou Feng Zhu Yuzhen Ye Ying Guo William Hartley Shengguo Xue | 2019 | Journal of Environmental Sciences2019，31，11： | 5 |
| 19 | Tribocorrosion behavior of nickel-aluminium bronze sliding against alumina under the lubrication by seawater with different halide concentrations显示文摘The tribocorrosion failure mechanism of nickel-aluminium bronze(NAB) in different halide concentrations of seawater was studied using a pin-on-disc tribometer that was modified to conduct in-situ electrochemical detection during the sliding process. It has been reported that high-halide-concentration seawater provided a good lubricating effect, and thus reduced the coefficient of friction and wear rate of NAB during the tribocorrosion process. However, the existence of halide ions corroded the passive film and hindered the repassivation of the damaged areas in the wear track, resulting in an increased corrosion rate. In addition, the morphology of the wear scar revealed the occurrence of abrasive, delamination, and adhesive wear of NAB in seawater. For the whole range of halide concentration values, a positive synergy between wear and corrosion was proven, and the quantification of this synergy was discussed in detail. The results show that the corrosionwear synergism was decreased with increasing halide concentration in seawater, and the corrosion-induced wear was dominant in the two synergistic components. | Beibei ZHANG Jianzhang WANG Junya YUAN Fengyuan YAN | 2019 | Friction2019，7，5： | 5 |
| 20 | Effects of cupric ions on the corrosion behavior of aluminum alloy 5A02 in ethylene glycol–water solution显示文摘The effects of cupric ions on the corrosion behavior of aluminum alloy 5A02 in ethylene glycol–water solutions were studied by potentiodynamic polarization,electrochemical noise(EN),and complementary techniques including scanning electron microscopy(SEM),atomic force microscopy(AFM),and X-ray photoelectron spectroscopy(XPS). A positive corrosion potential and increased corrosion current were observed due to the deposition of copper. The results demonstrate that the main corrosion type was pitting and the increasing cupric ion concentration augmented the pitting density. The pits became larger and deeper as a result of the embedment of copper into the surface of the alloy. Cupric ions were preferentially deposited at the defects around the secondary phase,leading to the formation of Al–Cu microgalvanic couples,which increased the corrosion rate. The corrosion rate gradually reached a stable value as the concentration of cupric ions was increased beyond 10 mmol/L. | Shu-lun Gao Mei Yu Jian-hua Liu Bing Xue Song-mei Li | 2017 | International Journal of Minerals,Metallurgy and Materials2017，24，4： | 4 |
您所在的机构暂未开通此部分的功能，请联系管理员