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| 1 | Nickel cobalt phosphide with three-dimensional nanostructure as al highly efficient electrocatalyst for hydrogen evolution reaction in both I acidic and alkaline electrolytes显示文摘Transition metal phosphides (TMPs) are promising candidates for noble metal free electrocatalysts in water splitting applicati ons. In this work, we prese nt the facile syn thesis of nickel cobalt phosphide electrocatalyst with three-dime nsional nano structure (3D-NiCoP) on the nickel foam, via hydrothermal reaction and phosphorization. The as-prepared electrocatalyst exhibits an excellent activity for hydrogen evolution reaction (HER) in both acidic and alkaline electrolytes, with small overpotentials to drive 10 mA/cm^2 (80 mV for 0.5 M H2SO4, 105 mV for 1 M KOH), small Tafel slopes (37 mV/dec for 0.5 M H2SO4, 79 mV/dec for 1 M KOH), and satisfying durability in long-term electrolysis. 3D-NiCoP also shows a superior HER activity compared to single metal phosphide, such as cobalt phosphide and nickel phosphide. The outstanding performa nee for HER suggests the great pote ntial of 3D-NiCoP as a highly efficient electrocatalyst for water splitting technology. | Bo Ma Zhengchun Yang Yantao Chen Zhihao Yuan | 2019 | Nano Research2019，12，2： | 14 |
| 2 | Ni-_2P-MoS_2/γ-Al_2O_3 Catalyst for Deep Hydrodesulfurization via the Hydrogenation Reaction Pathway显示文摘A series of highly active Ni2P-Mo S2/γ-Al2O3 catalysts were prepared and characterized, the catalytic performance of which was evaluated through hydrodesulfurization of dibenzothiophene. The result indicated that when the amount of Ni2 P was 4%, the catalyst showed a relatively high activity to provide a reliable reference for the hydrodesulfurization pathway in comparison with the conventional Ni Mo and Ni Mo P catalysts. The physicochemical properties of the catalysts were correlated with their catalytic activity and selectivity on hydrodesulfurization. The stacking number of active Mo S2 phases was important for influencing the hydrogenation activity. | Liu Lihua Liu Shuqun | 2014 | China Petroleum Processing & Petrochemical Technology2014，16，4： | 13 |
| 3 | Interfacial Engineering of NiFeP/NiFe-LDH Heterojunction for Efficient Overall Water Splitting显示文摘In consideration of application prospect of non-noble metallic materials catalysts,the study of exploring more highly effective electrocatalysts has been focused on by researchers.Herein,a novel strategy is employed to construct a heterojunction consisting of metal phosphide Ni_(x)Fe_(y)P and layered double hydroxide(LDH)with graphene oxide(GO)as conductive support.By adjusting the molar ratio of Ni to Fe,a series of heterojunctions with mixed valence state Fe^(δ+)/Fe^(3+)and Ni^(δ+)/Ni^(2+)(δis likely close to 0)redox couples are achieved and strong synergistic effects towards overall water splitting performance are found.The optimized catalyst with a Ni/Fe molar ratio of 0.72:0.33,namely Ni_(0.7)Fe_(0.3)P/LDH/GO,delivers ultra-low overpotentials for hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)of 79 and 198 mV at the current density of 10 mA·cm^(-2),respectively.Furthermore,for overall water-splitting practical application,it only requires 1.526 V at 10 mA·cm^(-2)with robust stability,which is superior to most reported electrocatalysts.Experimental results demonstrate the im-proved electronic conductivity,enlarged electrochemically active area and accelerated kinetics together account for the enhanced performance.This work supplies new prospects for the promotion and application of such heterojunction electrocatalysts in overall water splitting. | Xuanyu Long Jiazhi Meng Jiabao Gu Lanqing Ling Qianwen Li Nan Liu Kaiwen Wang Zequan Li | 2022 | Chinese Journal of Structural Chemistry2022，41，4： | 4 |
| 4 | Metal-organic framework-derived phosphide nanomaterials for electrochemical applications显示文摘Because of features,such as adjustable structures,high porosity,and high crystallinity,metal-organic frameworks(MOFs)deservedly have received considerable attention.Nevertheless,there is still room for improvements in the electrical conductivity and chemical stability of some MOFs,because of which they cannot be utilized as electrode materials.Fortunately,MOF derivatives have received widespread attention in recent years,especially phosphide materials,which are widely used in practical applications because of their outstanding conductivity,excellent specific surface area,and standout charge mobility.In this review,the latest developments of MOF-derived phosphides in electrocatalysis related to energy,including the excellent performance in terms of electrochemical energy storage and ingenious strategies,and diversified synthetic approaches are emphasized and summarized.Additionally,the arduous task and feasible proposals of MOF-derived phosphides are also discussed. | Xinlan Wang Guangxun Zhang Wei Yin Shasha Zheng Qingquan Kong Jingqi Tian Huan Pang | 2022 | Carbon Energy2022，4，2： | 3 |
| 5 | Ni_2P/ZrO_2-SBA-15 Dibenzothiophene Hydrodesulfurization Catalysts: Preparation,Characterization and Evaluation显示文摘Ni_2P/ZrO_2-SBA-15 catalysts with different zirconium n-propoxide/SBA-15 mass ratios were synthesized to evaluate their dibenzothiophene hydrodesulfurization catalytic activity. Effect of ZrO_2 introduction was investigated. Supports and catalysts were characterized by BET,XRD,^(29)SiNMR,XPS and FTIR. The results indicated that zirconium was incorporated into SBA-15 in the forms of [(–O–)_2 Si(–O–Zr)_2 ] and/or [(–O–)_3 Si–O–Zr],and that the SBA-15 framework structure was maintained after incorporation of ZrO_2. With zirconium content increasing,ZrO_2 was transformed from amorphous phase to tetragonal phase. Zirconium incorporation into SBA-15 supports could facilitate to form more dispersed Ni_2P active phase. There might be some interaction occurring between the P and Zr species. In addition to Ni_2P,another kind of active phase,ZrP,was formed,which might exhibit a better HDS activity than Ni_2P. It was observed that at a temperature of 280 °C,pressure of 3.0 MPa,WHSV of 6.5 h^(-1) and H_2 to oil ratio of 450,the Ni_2P/Zr-SBA(1.5) catalyst,where 1.5 represents zirconium n-propoxide/SBA-15 mass ratio,showed the highest DBT conversion,which was 86.6%,almost 35% higher than that of the Ni_2P/Zr-SBA(0) catalyst. | Hongqin Ma Qiurong Li Yang Shi Xiao Sun | 2018 | Transactions of Tianjin University2018，24，4： | 3 |
| 6 | N-doped-carbon coated Ni2P-Ni sheets anchored on graphene with superior energy storage behavior显示文摘Transition metal phosphides (TMPs) have been widely studied as electrode materials for supercapacitors and lithium-ion batteries due to their high electrochemical reacti on activities. The practical applicati on of TMPs was gen erally hampered by their low con ductivity and large volume changes during electrochemical reactions. In this work, nitrogen-doped-carbon (NC) coated Ni2P-Ni hybrid sheets were fabricated and loaded into highly con ductive graphe ne n etwork, forming a Ni2P ?Ni@NC@G composite. The highly con ductive g raphe ne, the NC coati ng layer, and the decorated Ni nano particles in combi nation offer continu ous electro n tran sport cha nnels in the composite, resulti ng with facilitated electrode reaction kinetics and superior rate performance. Besides, the flexible graphene sheets and well-decorated Ni particles among Ni2P can effectively buffer the harmful stress during electrochemical reactions to maintain an integrated electrode structure. With these favorable features, the composite dem on strated superior capacitive and lithium storage behavior. As an electrode material for supercapacitors, the composite shows a remarkable capacitance of 2,335.5 F·g^-1 at 1 A·g^-1 and high capacitance retention of 86.4% after 2,000 cycles. Asymmetrical supercapacitors (ASCs) were also prepared with remarkable energy density of 53.125 Whk·g^-1 and power density of 3,750 Whk·g^-1. As an anode for lithium ion batteries, a high reversible capacity of 1,410 mAh·g^-1 can be delivered at 0.2 A·g^-1 after 200 cycles. Promising high rate capability was also demonstrated with a high discharge capacity of 750 mAh·g^-1 at 8 A·g^-1. This work shall pave the way for the production of other TMP materials for energy storage systems. | Yuanxing Zhang Li Sun Liqi Bai Haochen Si Yu Zhang Yihe Zhang | 2019 | Nano Research2019，12，3： | 3 |
| 7 | Au/Ni12P5 core/shell single-crystal nanoparticles as oxygen evolution reaction catalyst显示文摘We have demonstrated the improved performance of oxygen evolution reactions(OER) using Au/nickel phosphide (Ni12P5) core/shell nanoparticles (NPs) underbasic conditions. NPs with a Ni12Ps shell and a Au core, both of which havewell-defined crystal structures, have been prepared using solution-based syntheticroutes. Compared with pure NiuP5 NPs and Au-Ni12P5 oligomer-like NPs, thecore/shell crystalline structure with Au shows an improved OER activity. Itaffords a current density of 10 mA/cm2 at a small overpotential of 0.34 V, in 1 MKOH aqueous solution at room temperature. This enhanced OER activity mayrelate to the strong structural and effective electronic coupling between thesingle-crystal core and the shell. | Yingying Xu Sibin Duan Haoyi Li Ming Yang Shijie Wang Xun Wang Rongming Wang | 2017 | Nano Research2017，10，9： | 2 |
| 8 | Hydrothermal preparation of nanocrystalline indium phosphidein non-aqueous system显示文摘Nanocrystalline semiconductors are potentially useful materials due to their novel prop-erties which are markedly different from those of the bulk solids,the most notable one beingquantum confinement.Preparation and application of nanocrystalline Ⅲ-V class of materialssuch as InP have recently attracted much attention.It is difficult to synthesize Ⅲ-V mat-erials by use of the traditional solid-state methods,due to their high synthesis temper- | 谢毅 王文中 钱逸泰 刘先明 | 1996 | Chinese Science Bulletin1996，41，23： | 2 |
| 9 | Size-dependent catalytic activity of cobalt phosphides for hydrogen evolution reaction显示文摘Transition metal phosphides are a class of promising electrocatalysts for hydrogen evolution reaction(HER) to replace noble metals.In this work,we for the first time synthesize carbon supported CoP nanoparticles with the average particle sizes from 3.3 to 9.2 nm,via a solvothermal process followed by low-temperature topological phosphorization,and the size-dependent HER activity of the CoP is investigated by virtue of TEM,XRD,XPS and the electrochemical techniques.It is discovered that the 9.2nm-CoP particles possess high intrinsic HER catalytic activity as compared to the 3.3nm-CoP,although the smaller one displays a high mass activity due to the large surface area.Detailed studies manifest that the small CoP particles suffer from serious oxidation once exposing to air.In contrast,most cobalt remains in the quasi-metallic state in the relatively large CoP particles,which is beneficial for the desorption of Hads,the rate determining step of the HER process over CoP surface.In addition,the low charge transfer resistance across the liquid/solid interfaces also contributes to the excellent HER activity of the relatively large CoP particles. | Xiaoke Li Luhua Jiang Jing Liu Qingfeng Hua Erdong Wang Guangwen Xie | 2020 | Journal of Energy Chemistry2020，29，4： | 1 |
| 10 | Decorating cobalt phosphide and rhodium on reduced graphene oxide for high-efficiency hydrogen evolution reaction显示文摘Electrochemical reduction of water to hydrogen holds great promise for clean energy,while its widespread application relies on the development of efficient catalysts with large surface area,abundant exposed active sites and superior electron conductivity.Herein,we report a facile strategy to configure an electrocatalyst composed of cobalt phosphide and rhodium uniformly anchored on reduced graphene oxide for hydrogen generation.The hybrids effectively integrate the exposed active sites,electron conductivity and synergistic effect of the catalyst.Electrochemical tests exhibit that the catalyst shows superior hydrogen evolution reaction catalytic activity and stability,with a small Tafel slope of 43 m V dec-1.Overpotentials as low as 29 and 72 mV are required to achieve current densities of 2 and 10 mA cm-2in 0.5M H2SO4,respectively.The hybrid constitution with highly active sites on conductive substrate is a new strategy to synthesize extremely efficient electrocatalysts.Especially,the efficient synergistic effect among cobalt phosphide,rhodium and reduced graphene oxide provides a novel approach for configuring electrocatalysts with high electron efficiency. | Haiyan Zheng Xiubing Huang Hongyi Gao Wenjun Dong Guilong Lu Xiao Chen Ge Wang | 2019 | Journal of Energy Chemistry2019，28，7： | 1 |
| 11 | Photonic integration technologies for indoor optical wireless communications显示文摘Indoor optical wireless communication(OWC) using steerable infrared beams is regarded as an important component in future 5 G network. Photonic integration technologies can meet the criteria of such application, and provide low-cost, high-performance and very compact chips. In this paper, we review the recent development of photonic integration technologies suitable for indoor OWC application, and discuss in detail the current status and future opportunities of several key devices, such as the chip to free space couplers, integrated receivers and transmitters. | Yuqing JIAO Zizheng CAO | 2018 | Science China(Information Sciences)2018，61，8： | 1 |
| 12 | InP quantum dots-based electroluminescent devices显示文摘Indium phosphide(InP) quantum dots(QDs) have shown great potential to replace the widely applied toxic cadmiumcontaining and lead perovskite QDs due to their similar emission wavelength range and emission peak width but without intrinsic toxicity. Recently, electrically driven red and green InP-based quantum-dot light-emitting diodes(QLEDs) have achieved great progress in external quantum efficiency(EQE), reaching up to 12.2% and 6.3%, respectively. Despite the relatively poor device performance comparing with cadmium selenide(CdSe)-and perovskite-based QLEDs, these encouraging facts with unique environmental friendliness and solution-processability foreshadow the enormous potential of InP-based QLEDs for energy-efficient, high-color-quality thin-film display and solid-state lighting applications. In this article, recent advances in the research of the InP-based QLEDs have been discussed, with the main focus on device structure selection and interface research, as well as our outlook for on-going strategies of high-efficiency InP-based QLEDs. | 吴倩倩 曹璠 孔令媚 杨绪勇 | 2019 | Chinese Physics B2019，28，11： | 1 |
| 13 | Interface-strengthened CoP nanosheet array with Co2P nanoparticles as efficient electrocatalysts for overall water splitting显示文摘Highly active and durable bifunctional electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) play a pivotal role in overall water splitting. Herein, we demonstrate the construction of interface-strengthened CoP nanosheet array with Co2P nanoparticles as such an electrocatalyst through a facile hydrothermal reaction and the subsequent phosphorization process. The twodimensional (2D) nanosheets with thickness of^55 nm expose a great number of active sites. The surface chemical state indicates that the strongly coupled CoP/Co2P electrocatalysts can adsorb or generate more targeted intermediates (e.g. OH- or OOH*) for both HER/OER. As a result, the CoP/Co2P electrocatalysts exhibit small overpotentials of 68 and 256 mV to drive 10 mA cm^-2 for HER and OER, respectively, outperforming most of the recently reported Co-based electrocatalysts. Furthermore, an alkaline electrolyzer assembled by using CoP/Co2P as both cathode and anode can achieve a current density of 10 mA cm^-2 at a low voltage of 1.57 V and work continuously for over 58 h. This work provides a feasible structural design for transition metal phosphides electrocatalysts with efficient and stable overall water splitting. | Yanping Hua Qiucheng Xu Yanjie Hu Hao Jiang Chunzhong Li | 2019 | Journal of Energy Chemistry2019，28，10： | 1 |
| 14 | Selective substitution induced anomalous phonon stiffening within quasi-one-dimensional P–P chains in SiP2显示文摘Light-matter interactions in low-dimensional quantum-confined structures can dominate the optical properties of the materials and lead to optoelectronic applications.In anisotropic layered silicon diphosphide(SiP2)crystal,the embedded quasi-onedimensional(1D)phosphorus–phosphorus(P–P)chains directly result in an unconventional quasi-1D excitonic state,and a special phonon mode vibrating along the P–P chains,establishing a unique 1D quantum-confined system.Alloying SiP2 with the homologous element serves as an effective way to study the properties of these excitons and phonons associated with the quasi-1D P–P chains,as well as the strong interaction between these quasiparticles.However,the experimental observation and the related optical spectral understanding of SiP2 with isoelectronic dopants remain elusive.Herein,with the photoluminescence and Raman spectroscopy measurements,we demonstrate the redshift of the confined excitonic peak and the stiffening of the phonon vibration mode■of a series of Si(P1−xAsx)2 alloys with increasing arsenic(As)compositions.This anomalous stiffening of■is attributed to the selective substitution of As atoms for P atoms within the P–P chains,which is confirmed via our scanning transmission electron microscopy investigation.Such optical spectra evolutions with selective substitution pave a new way to understand the 1D quantum confinement in semiconductors,offering opportunities to explore quasi-1D characteristics in SiP2 and the resulting photonic device application. | Xueting Dai Feng Qin Caiyu Qiu Ling Zhou Junwei Huang Fanghua Cheng Xiangyu Bi Caorong Zhang Zeya Li Ming Tang Shengqiang Wu Xiaoxu Zhao Yangfan Lu Huiyang Gou Hongtao Yuan | 2023 | Nano Research2023，16，1： | 0 |
| 15 | Ni_(3)S_(2)@NiFePx electrode with dual-anion-modulated layer for efficient and stable oxygen evolution显示文摘The rational construction of high-performance and stable electrocatalyst for oxygen evolution reaction(OER)is a prerequisite for efficient water electrolysis.Herein,we develop a broccoli-like Ni_(3)S_(2)@NiFeP_(x)(Ni_(3)S_(2)@NFP)catalyst on nickel foam(NF)via a sequential two-step layer-by-layer assembly electrodeposition method.X-ray diffraction,in situ Raman and Fourier-transform infrared spectra have mutually validated the element segregation and phase refusion during OER condition.The reconstruction of double layer Ni_(3)S_(2)@NFP facilitates the formation of the active(oxy)hydroxides,which is modulated by the dual anionic layer with mixed sulfate and phosphate ions.As a result,the obtained Ni_(3)S_(2)@NFP electrode exhibits low overpotential(329 mV)and long-term durability(∼500 h)for OER at current density of 500mA/cm^(2).Moreover,the self-supported Ni_(3)S_(2)@NFP can act as an efficient and durable anode in alkaline anion exchange membrane water electrolysis device(AEMWE).This work provides a facile and scaled-up strategy to construct self-supported electrocatalyst and emphasizes the crucial role of anions in pre-catalyst reconstruction and enhancing OER performance. | Xijie Chen Keqiang Xu Jinhan Li Xiao Wang Tete Zhao Fangming Liu Meng Yu Fangyi Cheng | 2023 | Chinese Chemical Letters2023，34，11： | 0 |
| 16 | Bifunctional Fe-doped CoP@Ni_(2)P heteroarchitectures for highefficient water electrocatalysis显示文摘It is important to develop economical and durable electrocatalysts for sustainable energy conversion technology.However,the current catalysts still suffer from insufficient hydrogen adsorption energy.Herein,we report a kind of novel bi-phosphide catalyst through constructing heterogeneous structures and cation doping.The obtained sample delivers an outstanding hydrogen evolution reaction(HER)performance at all pH range.As oxygen evolution reaction(OER)electrocatalyst,Fe-CoP@Ni_(2)P samples show an overpotential of 237 mV at 50 mA·cm^(−2) in alkaline solution.For electrolysis of water,Fe-CoP@Ni_(2)P catalysts deliver a cell voltage of 1.59 V at 50 mA·cm^(−2) and long durability.Furthermore,density functional theory(DFT)calculation further confirms that the doped heterostructure promotes Gibbs free energy for hydrogen adsorption.And the significant increase in the density of total states(DOS)also enhances the catalytic activity of HER. | Zhongxin Duan Depeng Zhao Yuchen Sun Xiaojie Tan Xiang Wu | 2022 | Nano Research2022，15，10： | 0 |
| 17 | Analysis of structural distortion in Eshelby twisted InP nanowires by scanning precession electron diffraction显示文摘Tran smissio n electro n microscopes (TEM) are widely used in nan otech no logy research. However, it is still challe nging to characterize nano scale objects;their small size coupled with dynamical diffraction makes interpret!ng real- or reciprocal-space data difficult. Scanning precession electron diffraction ((S)PED) represents an invaluable contribution, reducing the dynamical contributions to the diffraction pattern at high spatial resolution. Here a detailed analysis of wurtzite InP nanowires (30-40 nm in diameter) containing a screw dislocation and an associated wire lattice torsion is presented. It has been possible to characterize the dislocation with great detail (Burgers and line vector, handedness). Through careful measurement of the strain field and comparison with dynamical electron diffraction simulations, this was found to be compatible with a Burgers vector modulus equal to one hexagonal lattice cell parameter despite the observed crystal rotation rate being larger (ca. 20%) than that predicted by classical elastic theory for the nominal wire diameter. These findings corroborate the importance of the (S)PED technique for characterizing nano scale materials. | Daniel Ugarte Luiz H. G. Tizei Monica A. Cotta Caterina Ducati Paul A. Midgley Alexander S. Eggeman | 2019 | Nano Research2019，12，4： | 0 |
| 18 | Trace ruthenium promoted dual-reconstruction of CoFeP@C/NF for activating overall water splitting performance beyond precious-metals显示文摘At present,Ru dopants mainly enhance electrocatalytic performance by inducing strain,vacancy,local electron difference,and synergy.Surprisingly,this work innovatively proposes that trace Ru atoms induce dual-reconstruction of phosphide by regulating the electronic configuration and proportion of Co–P/Co–O species,and ultimately activate superb electrocatalytic performance.Specifically,Ru-CoFeP@C/nickel foam(NF)is reconstructed to generate hydrophilic Co(OH)_(2)nanosheets during the hydrogen evolution reaction(HER)process,further accelerating the alkaline HER kinetics of phosphide.And the as-formed CoOOH during the oxygen evolution reaction(OER)process directly accelerates the oxygen overflow efficiency.As expected,the overpotential at 100 mA·cm^(−2)(η100)values of the reconstructed Ru-CoFeP@C/NF are 0.104 and 0.257 V for HER and OER,which are greatly lower than that of Pt/C-NF and RuO_(2)-NF benchmarks,respectively.This work provides guidance for the construction of highperformance catalysts for HER and OER dual reconstruction.This work provides a new idea for the optimization of catalyst structure and electrocatalytic performance. | Jinhong Ren Jie Liu Yunmei Du Shuangshuang Li Mengmeng Wang Bin Li Bo Yang Lei Wang Yanru Liu | 2023 | Nano Research2023，16，8： | 0 |
| 19 | 封装有Ni掺杂FeP纳米颗粒的氮掺杂碳纳米管作为双功能电催化剂显示文摘清洁能源支撑的电解海水技术是公认的最有前途的未来可持续绿色制氢途径.商用贵金属催化剂储量低、成本昂贵,且在复杂离子环境下容易快速失活的特性,严重阻碍了电解海水技术的工业化发展.本工作通过Ni掺杂Fe团簇催化碳纳米管生长,再气体磷化法,成功构建了一种含Ni掺杂FeP纳米颗粒封端的新型氮掺杂碳纳米管交织结构(NFP@NC).独特的N-CNTs交织网络,以及N-CNTs和Ni掺杂FeP的强相互作用提供了快速的传质途径,提高了气体逸出效率,并显著增强了催化剂稳定性.NFP@NC在10 mA cm^(−2)的电流密度下的析氧反应过电位为280 mV,析氢反应过电位为206 mV,低于大多数报道的铁基催化剂.本研究为构建交织的碳纳米管网络和制备高性能双功能海水电解催化剂提供了一种有效的途径. | 张含 王勇龙 张波 张述磊 马艺茹 吴则星 朱玉静 刘福胜 肖振宇 王磊 | 2023 | Science China Materials2023，66，12： | 0 |
| 20 | Effect of Cerium on Morphology of Phosphide Eutectic显示文摘The phosphide eutectic formation process in high purity Fe-4. 6% C alloy, in which 0.02%-1.0% P was added, was studied with DTA, SEM and EDS, and the effect of cerium on the morphology of phosphide eutectic in the ternary Fe-C-P alloy was also investigated. The results show that the ternary phosphide eutectic with the addition of 0.04% P is formed at low cooling rate. After cerium is added, the morphology of phosphide eutectic is changed from non-continuous or continuous distribution net to round or nodular form locating along the eutectic cell boundaries. | 陈贵如 梁吉 魏秉庆 吴德海 | 2000 | Journal of Rare Earths2000，18，1： | 0 |
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