| 1 | Low-temperature SCR activity and SO_2 deactivation mechanism of Ce-modified V_2O_5–WO_3/TiO_2 catalyst显示文摘The promotion effect of ceria modi fi cation on the low-temperature activity of V2O5-WO3/TiO2 catalyst was evaluated for the selective catalytic reduction of NO with NH3(NH3-SCR). The catalytic activity of 1 wt% V2O5-WO3/TiO2 was signi fi cantly enhanced by the addition of 8 wt%ceria, which exhibited a NO x conversion above 80% in a broad temperature range 190–450 1C. This performance was comparable with 3 wt%V2O5-WO3/TiO2, indicating that the addition of ceria contributed to reducing the usage of toxic vanadia in developing low-temperature SCR catalysts. Moreover, V1 Ce WTi exhibited approximately 10% decrease in NOx conversion in the presence of 60 ppm SO2. The characterization results indicated that active components of V, W and Ce were well dispersed on TiO2 support. The synergetic interaction between Ce and V species by forming V–O–Ce bridges enhanced the reducibility of VCe WTi catalyst and thus improved the low-temperature activity. The sulfur poisoning mechanism was also presented on a basis of the designed TPDC(temperature-programmed decomposition) and TPSR(temperatureprogrammed surface reaction) experiments. The deposition of(NH4)2SO4on V1 Ce WTi catalyst was much smaller compared with that on V1 Ti.On the other hand, the oxidation of SO2 to SO3was signi fi cantly promoted on the CeO2-modi fi ed catalyst, accompanied by the formation of cerium sulfates. Therefore, the deactivation of this catalyst was mainly attributed to the vanishing of the V–Ce interaction and the sulfation of active ceria. | Ziran Ma Xiaodong Wu Ya Feng Zhichun Si Duan Weng Lei Shi | 2015 | Progress in Natural Science:Materials International2015，25，4： | 29 |
| 2 | Runoff variation affected by precipitation change and human activity in Hailiutu River basin,China显示文摘For recent years,runoff generation and hydrological processes in Hailiutu River basin have been greatly changed by climate change and human activity,especially water and soil conservation construction.In this study,the trends in precipitation,evapotranspiration(ET)and river runoff as well as the effects of precipitation change and human activity on runoff variation have been studied.The results showed that during 1960-2000,annual precipitation and river runoff,monthly precipitation and ET in September and October as well as monthly runoff in all months showed a significant decrease.In addition,peak flow and base flow had a large decrease.Under the joint influence of precipitation change and human activity,the mean annual runoff decreased by 35 million m3 from the baseline period(1960-1985)to the change period(1986-2000),which accounted for 60.9%and 39.1%of the total runoff decrease,respectively.Precipitation change played a primary role in the decrease of annual runoff whereas human activity,particularly water and soil conservation construction,also had remarkable impacts on runoff variation. | Dejuan Jiang Lijuan Li Jiuyi Li | 2014 | Chinese Journal of Population,Resources and Environment2014，12，2： | 1 |
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