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Microbial Geochemical Characteristics of the Coalbed Methane in the Shizhuangnan Block of Qinshui Basin, North China and their Geological Implications

查看全文 作  者:LI [1,2,3]Yang;SHI [1,2,3]Wei;TANG [1,2,3]Shuheng 高影响力作者 机构地区:[1]School of Energy Resource,China University of Geosciences,Beijing 100083,China;[2]Key Laboratory of Marine Reservoir Evolution and Hydrocarbon Enrichment Mechanism,Ministry of Education,Beijing 100083,China;[3]Key Laboratory of Strategy Evaluation for Shale Gas,Ministry of Land and Resources,Beijing 100083,China高影响力机构 出  处:《Acta Geologica Sinica(English Edition)》索引2019年第93卷第3期,共15页高影响力期刊 基  金:granted by the National Science and Technology Major Project of China (grant No. 2017ZX05064003);the National Natural Science Foundation of China (grant No. 41772159/D0208);the Fundamental Research Funds for the Central Universities (grant No. 2652018233) 摘  要:Methanogens and sulfate reducing bacteria were detected by the 16SrRNA sequencing of coalbed methane(CBM)co-produced water in the south of the Qinshui Basin,which is indicative of the presence of secondary biological gas in the south of this basin,in contradiction to the previous understanding of thermogenic gas.This work systematically collected water samples from the CBM wells in the Shizhuangnan Block and analyzed the microbial geochemical characteristics from the aspects of water ions,hydrogen and oxygen isotopes,dissolved inorganic carbon and microbial diversity.It is shown that the Shizhuangnan Block has a nearly SN-trending monoclinic structure,and the elevation of coal seam decreases gradually from the east to west.Because of the water blocking effect of Sitou fault in the west,the precipitation flowed from the east to west,and gradually transited to stagnant flow area.The concentration variation of some ions such as Na^+,K^+,Ca2^+,Mg2^+,Cl^-,HCO3^-and total dissolved solids(TDS)suggest the variation of redox condition in the coal reservoir water.The 16SrDNA sequencing analysis of the collected water samples detected the presence of methanogens and sulfate reduction bacteria.The presence of methane production zone and sulfate methane transition zone(SMTZ)was identified.The effect of methanogens in the methane production zone leads to an increase in the methane concentration,resulting in a high gas content in the study area.In the SMTZ,most methane is consumed by anaerobic oxidation due to high sulfate concentrations. 关 键 词:CBM co-produced water MICROBIAL geochemistry sulfate methane transition zone Shizhuangnan BLOCK
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