|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Catalytic oxidation of benzene over Ce-Mn oxides synthesized by flame spray pyrolysis显示文摘Flame spray pyrolysis(FSP) was utilized to synthesize Ce-Mn oxides in one step for catalytic oxidation of benzene.Cerium acetate and manganese acetate were used as precursors.The materials synthesized were characterized using X-ray diffraction(XRD),N_2 adsorption,X-ray photoelectron spectroscopy(XPS).transmission electron microscopy(TEM),Raman spectroscopy,and Fh-temperature programmed reduction(H_2-TPR) and their benzene catalytic oxidation behavior was evaluated.Mn ions were evidenced in multiple chemical states.Crystalline Ce-Mn oxides consist of particles with size <40 nm and specific surface areas(SSA) of 20-50m^2/g.Raman spectrums and H_2-TPR results indicated the interaction between cerium and manganese oxides.Flame-made 12.5%-Ce-Mn oxide exhibited excellent catalytic activity at relatively low temperatures(T95 about 260 C) compared to other Ce-Mn oxides with different ceriumto-manganese ratios.Redox mechanism and strong interaction conform to structure analysis that Ce-Mn strong interaction formed during the high temperature flame process and the results were used to explain catalytic oxidation of benzene. | Gang Liu Renliang Yue Yi Jia Yong Ni Jie Yang Haidi Liu Zhen Wang Xiaofeng Wu Yunfa Chen | 2013 | Particuology2013，11，4： | 17 |
| 2 | Effects of cerium incorporation on the catalytic oxidation of benzene over flame-made perovskite La_(1-x)Ce_xMnO_3 catalysts显示文摘Perovskite-type La_(1-x)Ce_xMnO_3(x = 0-10%) catalysts were prepared by flame spray pyrolysis and their activities during the catalytic oxidation of benzene were examined over the temperature range of100-450℃.The structural properties and reducibility of these materials were also characterized by X-ray diffraction(XRD),N_2 adsorption/desorption,H_2 temperature-programmed reduction(H_2-TPR) and X-ray photoelectron spectroscopy(XPS).The incorporation of Ce was found to improve the benzene oxidation activity,and the perovskite in which x was 0.1 exhibited the highest activity.Phase composition and surface elemental analyses indicated that non-stoichiometric compounds were present.The incorporation of Ce had a negligible effect on the specific surface area of the perovskites and hence this factor has little impact on the catalytic activity.Introduction of Ce4^(4+) resulted in modification of the chemical states of both B-site ions and oxygen species and facilitated the reducibility of the perovskite.The surface Mn^(4+)/Mn^(3+)ratio was increased as a result of Ce^(4+) substitution,while a decrease in the surface-adsorbed O/lattice O(O_(ads)/O_(latt)) ratio was observed.The relationship between the surface elemental ratios and catalytic activity was established to allow a better understanding of the process by which benzene is oxidized over perovskites. | Gang Liu Jiaqi Li Kun Yang Wenxiang Tang Haidi Liu Jun Yang Renliang Yue Yunfa Chen | 2015 | Particuology2015，13，2： | 6 |
| 3 | Sonication-assisted dispersion of carbon nanotubes in aqueous solutions of the anionic surfactant SDBS:The role of sonication energy显示文摘Sonication is a powerful technique to promote the dispersion of carbon nanotubes(CNTs) and enhance their solubility;this is necessary for CNT applications,especially in the biochemical and biomedical fields.In this study,batch experiments were conducted to evaluate the role of sonication energy on the dispersion of CNTs in the presence of a widely used anionic surfactant,sodium dodecylbenzene sulfonate(SDBS).It was observed that the concentration of dispersed CNTs in the SDBS solution depended on the sonication energy,but not the sonication time or output power of the sonicator alone.The amount of dispersed CNTs was positively correlated with the concentrations of SDBS and CNTs,and the length of the CNTs.The promotion of oxygen-containing functional groups on the dispersed CNTs was observed at relatively low sonication energies.The optimal energy,i.e.the minimum energy supplied by sonication to achieve a saturated suspension of dispersed CNTs in the SDBS solution,was CNT diameter-dependent,because of the larger vdW forces between tubes of smaller diameter.An exponential decay curve was constructed for the optimal energy values as a function of the outer CNT diameter,to assist in determining the energy needed to disperse CNTs. | YANG Kun YI ZiLi JING QingFeng YUE RenLiang JIANG Wei LIN DaoHui | 2013 | Chinese Science Bulletin2013，58，18： | 5 |
| 4 | Filter paper-templated preparation of ZnO thin films and examination of their gas-sensing properties显示文摘ZnO thin films prepared by using quantitative filter paper as a template and Zn(CH3CO2) 2·2H2O ethanol precursor solution were characterized by scanning electron microscopy(SEM) and X-ray diffraction(XRD) . The effects of sample calcination temperature,precursor concentration and filter paper types were studied,and the growth process was investigated by infra-red(IR) spectroscopy and thermogravimetric analysis/differential thermal analysis(TGA/DTA) . The results show that samples soaked in a 1.5 mol/L Zn(CH3CO2) 2·2H2O ethanol solution and calcined at 600 °C yield ZnO films of uniform particle size,approx-imately 30,40 and 50 nm,for fast-,medium-and slow-speed filter papers,respectively. The formaldehyde gas sensing properties of the ZnO nanoparticles were tested,showing that the material prepared from fast-speed filter paper has a higher response to 120-205 ppm formaldehyde at 400 °C than that prepared from medium-or slow-speed paper,which depends on the particle size. | Bao Wang Ning Han Dong Meng Renliang Yue Jinghui Yan Yunfa Chen | 2011 | Particuology2011，9，3： | 2 |
| 5 | CrO x –CeO 2 binary oxide as a superior catalyst for NO reduction with NH 3 at low temperature in presence of CO显示文摘 | Haidi Liu Lianqi Wei Renliang Yue Yunfa Chen | 2010 | Catalysis Communications2010，，9： | 1 |
您所在的机构暂未开通此部分的功能，请联系管理员