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| 1 | The Mechanism of Cortico-Striato-Thalamo-Cortical Neurocircuitry in Response Inhibition and Emotional Responding in Attention Deficit Hyperactivity Disorder with Comorbid Disruptive Behavior Disorder显示文摘The neurocircuitries that constitute the corticostriato-thalamo-cortical(CSTC) circuit provide a framework for bridging gaps between neuroscience and executive function in attention deficit hyperactivity disorder(ADHD), but it has been difficult to identify the mechanisms for regulating emotional problems from the understanding of ADHD comorbidity with disruptive behavior disorders(DBD). Research based on 'cool'' and 'hot''executive functional theory and the dual pathway models,which are thought of as applied response inhibition and delay aversion, respectively, within the neuropsychological view of ADHD, has shed light on emotional responding before and after decontextualized stimuli, while CSTC circuit-related domains have been suggested to explain the different emotional symptoms of ADHD with or without comorbid DBD. This review discusses the role of abnormal connections in each CSTC circuit, especially in the emotion circuit, which may be responsible for targeted executive dysfunction at the neuroscience level. Thus, the two major domains – abstract thinking(cool) and emotional trait(hot) – trigger the mechanism of onset of ADHD. | Yuncheng Zhu Xixi Jiang Weidong Ji | 2018 | Neuroscience Bulletin2018，34，3： | 12 |
| 2 | SCM-198 protects endometrial stromal cells from oxidative damage through Bax/Bcl-2 and ERK signaling pathways显示文摘In creasi ng amounts of evidence dem on strated that accumulative reactive oxyge n species (ROS) and apoptosis of human endometrial stromal cells (ESCs) are closely associated with endometrial dysfunction induced by oxidative stress, which plays an important role in the pathological process of multiple gyn ecological and reproduction-related diseases. SCM-198, an alkaloid active component of Leonurus japonicas Houtt, has been reported to have anti-oxidative activity. However, the specific mechanisms of SCM-198 in the prevention of endometrial damage remain unknown. In the present study, we assessed the effect of SCM-198 on hydrogen peroxide (H2O2Hnduced oxidative injury in ESCs. ESCs were pretreated with SCM-198 for 4 h and then challenged with H2O2.Morphology ch a nges, apoptosis rate, and intracellular ROS producti on were measured to assess the level of oxidative injury. Flow cytometry and western blot analysis were performed to detect the expression levels of Bax, Bcl-2, active-caspase-3, and mitogen-activated protein kinases pathways. Classic inflammation cytokines were measured by real-time polymerase chain reactions. Our results showed that SCM-198 attenuated apoptosis and ROS generation of ESCs induced by H2O2. H2O2 induced the apparent apoptotic characteristics, including fragmentation of DNA, upregulation of Bax/Bcl2, activation of caspase-3, and secretion of inflammation cytokines, which were all ameliorated by SCM-198. Furthermore, H2O2-induced apoptosis-related ERK1/2 pathway activation was restrained by SCM-198 pretreatme nt. These fin dings suggested that SCM-198 could protect ESCs from oxidative injury, mainly by inhibiting oxidative stress and reducing apoptosis. | Yunyun Li Yikong Lin Xixi Huang Chunfang Xu Xinhua Liu Li Wang Min Yu Dajin Li Yizhun Zhu Meirong Du | 2019 | Acta Biochimica et Biophysica Sinica2019，51，6： | 10 |
| 3 | LiNbO3-coated LiNi0.8Co0.1Mn0.1O2 cathode with high discharge capacity and rate performance for all-solid-state lithium battery显示文摘In order to obtain high power density,energy density and safe energy storage lithium ion batteries(LIB)to meet growing demand for electronic products,oxide cathodes have been widely explored in all-solidstate lithium batteries(ASSLB)using sulfide solid electrolyte.However,the electrochemical performances are still not satisfactory,due to the high interfacial resistance caused by severe interfacial instability between sulfide solid electrolyte and oxide cathode,especially Ni-rich oxide cathodes,in charge-discharge process.Ni-rich LiNi0.8Co0.1Mn0.1O2(NCM811)material at present is one of the most key cathode candidates to achieve the high energy density up to 300 Wh kg^-1 in liquid LIB,but rarely investigated in ASSLB using sulfide electrolyte.To design the stable interface between NCM811 and sulfide electrolyte should be extremely necessary.In this work,in view of our previous work,LiNbO3 coating with about 1 wt% content is adopted to improve the interfacial stability and the electrochemical performances of NCM811 cathode in ASSLB using Li10GeP2S12 solid electrolyte.Consequently,LiNbO3-coated NCM811 cathode displays the higher discharge capacity and rate performance than the reported oxide electrodes in ASSLB using sulfide solid electrolyte to our knowledge. | Xuelei Li Liubing Jin Dawei Song Hongzhou Zhang Xixi Shi Zhenyu Wang Lianqi Zhang Lingyun Zhu | 2020 | Journal of Energy Chemistry2020，29，1： | 7 |
| 4 | Partial anhysteretic remanent magnetization (pARM) of synthetic single-and multidomain magnetites and its paleoenvironmental significance显示文摘In order to isolate magnetic signals carried by single-domain (SD) ferrimagnetic (FM) minerals from multi-domain (MD) FM minerals, we developed a few pa- rameters using partial anhysteretic remanent magnetization (pARM). Because MD fraction contains only soft (easy to be demagnetized) coercivity spectrum, pARM(>20 mT) was sensitive in eliminating MD contributions. Ratio of pARM(5 mT, 10 mT)/pARM(0, 5 mT) is useful in quantifying a rela- tive abundance of mass ratio between SD and MD fractions. These new proxies can quickly characterize the details of grain size distribution of magnetic minerals in paleoclimatic and paleomagnetic studies. | LIU Qingsong YU Yongjae PAN Yongxin ZHU Rixiang ZHAO Xixi | 2005 | Chinese Science Bulletin2005，50，20： | 3 |
| 5 | Discovery and identification of EIF2AK2 as a direct key target of berberine for anti-inflammatory effects显示文摘Using chemoproteomic techniques,we first identified EIF2AK2,eEF1A1,PRDX3 and VPS4B as direct targets of berberine(BBR)for its synergistically anti-inflammatory effects.Of them,BBR has the strongest affinity with EIF2AK2 via two ionic bonds,and regulates several key inflammatory pathways through EIF2AK2,indicating the dominant role of EIF2AK2.Also,BBR could subtly inhibit the dimerization of EIF2AK2,rather than its enzyme activity,to selectively modulate its downstream pathways including JNK,NF-κB,AKT and NLRP3,with an advantage of good safety profile.In EIF2AK2 gene knockdown mice,the inhibitory IL-1β,IL-6,IL-18 and TNF-a secretion of BBR was obviously attenuated,confirming an EIF2AK2-dependent anti-inflammatory efficacy.The results highlight the BBR's network mechanism on anti-inflammatory effects in which EIF2AK2 is a key target,and inhibition of EIF2AK2 dimerization has a potential to be a therapeutic strategy against inflammationrelated disorders. | Wei Wei Qingxuan Zeng Yan Wang Xixi Guo Tianyun Fan Yinghong Li Hongbin Deng Liping Zhao Xintong Zhang Yonghua Liu Yulong Shi Jingyang Zhu Xican Ma Yanxiang Wang Jiandong Jiang Danqing Song | 2023 | Acta Pharmaceutica Sinica B2023，13，5： | 2 |
| 6 | Morphologically templated nucleation of primary Si on AlP in hypereutectic Al-Si alloys显示文摘AlP has been widely used as an effective heterogenous nucleus for primary Si phase in hypereutectic AlSi alloys,but the morphological correlation between AlP and primary Si is still confusing.In the present work,the morphologies of AlP crystals were studied comprehensively by experimental observation and theorical prediction.It is found that AlP collected from an Al-0.03 P melt could be divided into two categories:spinel twin crystals and non-twin crystals.During the nucleation process,these two kinds of AlP crystals triggered morphologically templated nucleation of primary Si phase,resulting in the formation of hexagonal primary Si twin and octahedral non-twin crystals,respectively.As such,the percentage of primary Si twin crystals in the experimental Al-18 Si alloy was also increased obviously after the morphologically templated nucleation via Al P.The morphologically templated nucleation also eliminated the dendritic growth of primary Si phase and the formation of hopper structures inside primary Si,forcing primary Si to maintain to be faceted solid crystals through layer-by-layer growing mechanism.The insight into morphologically templated nucleation offers a new view in understanding the mechanism of heterogeneous nucleation of primary Si phase on AlP nuclei. | Xiangzhen Zhu Shihao Wang Xixi Dong Xiangfa Liu Shouxun Ji | 2022 | Journal of Materials Science & Technology2022，，5： | 2 |
| 7 | The effect of basal dislocation on {11■1} twin boundary evolution in a Mg-Gd-Y-Zr alloy显示文摘This study aims to understand the features of{11■1}twin boundaries in a high strain rate compressed Mg-10 Gd-3Y-0.4Zr using electron backscatter diffraction(EBSD)and transmission electron microscopy(TEM).Based on the Schmid factor calculations,the basal dislocations are easily activated within the{11■1}twin and suppressed in the surrounding matrix.The consequent basal dislocation-twin interaction during deformation can lead to the misorentiation deviation of{11■1}twin boundaries,accompanying with the formation of a step at the twin boundary.Such a{11■1}twin boundary evolution mechanism provides a new vision of twinning behavior in Mg alloys. | Huan Zhang Yangxin Li Yuxuan Liu Qingchun Zhu Xixi Qi Gaoming Zhu Jinhui Wang Peipeng Jin Xiaoqin Zeng | 2021 | Journal of Materials Science & Technology2021，，22： | 2 |
| 8 | A Secret Confusion Based Energy-Saving and Privacy-Preserving Data Aggregation Algorithm显示文摘To reduce communication overhead on the premise of privacy protection, this study presents a novel secret Confusion based energy-saving and privacypreserving data aggregation algorithm(CESPT). In confusion phase, CESPT confuses real sensory data and their sources by positive-negative pairs and a confusion factor is introduced to determine the quantity of pairs generated by a sensor, the exchange rounds and the threshold of data exchange, which affect communication overhead and privacy intensity of a Wireless sensor network(WSN). In aggregation phase, CESPT adopts a positive-negative neutralization strategy and a well-designed time slice allocation mechanism to reduce network traffic and message collision.In a word, CESPT can greatly reduce data traffic and energy consumption and obtain accurate statistical results on the basis of data privacy. | ZHANG Jun ZHU Jianghao JIA Zongpu YAN Xixi | 2017 | Chinese Journal of Electronics2017，26，4： | 2 |
| 9 | Risk Prevention and Control for Agricultural Non-Point Source Pollution Based on the Process of Pressure-Transformation-Absorption in Chongqing, China显示文摘According to China’s second national survey of pollution sources, the contribution of agricultural non-point sources(ANS) to water pollution is still high. Risk prevention and control are the main means to control costs and improve the efficiency of ANS, but most studies directly take pollution load as the risk standard, leading to a considerable misjudgment of the actual pollution risk. To objectively reflect the risk of agricultural non-point source pollution(ANSP) in Chongqing, China, we investigated the influences of initial source input, intermediate transformation, and terminal absorption of pollutants via literature research and the Delphi method and built a PTA(pressure kinetic energy, transformation kinetic energy, and absorption kinetic energy) model that covers 12 factors, with the support of geographical information system(GIS) technology. The terrain factor calculation results and the calculation results of other factors were optimized by Python tools to reduce human error and workload. Via centroid migration analysis and Kernel density analysis, the risk level, spatial aggregation degree, and key prevention and control regions could be accurately determined. There was a positive correlation between the water quality of the rivers in Chongqing and the risk assessment results of different periods, indirectly reflecting the reliability of the assessment results by the proposed model. There was an obvious tendency for the low-risk regions transforming into high-risk regions. The proportion of high-risk regions and extremely high-risk regions increased from 17.82% and 16.63%in 2000 to 18.10% and 16.76% in 2015, respectively. And the risk level in the main urban areas was significantly higher than that in the southeastern and northeastern areas of Chongqing. The centroids of all grades of risky areas presented a successive distribution from west to east, and the centroids of high-risk and extremely high-risk regions shifted eastward. From 2000 to 2015, the centroids of highrisk and extremely high-risk regions moved 4.63 km(1.68°) and 4.48 km(12.08°) east by north, respectively. The kernel density analysis results showed that the high-risk regions were mainly concentrated in the main urban areas and that the distribution of agglomeration areas overall displayed a transition trend from contiguous distribution to decentralized concentration. The risk levels of the regions with a high proportion of cultivated land and artificial surface were significantly increased, and the occupation of cultivated land in the process of urbanization promoted the movement of the centroids of high-risk and extremely high-risk regions. The identification of key areas for risk prevention and control provides data scientific basis for the development of prevention and control strategies. | ZHU Kangwen CHEN Yucheng ZHANG Sheng YANG Zhimin HUANG Lei LEI Bo XIONG Hailing WU Sheng LI Xixi | 2021 | Chinese Geographical Science2021，31，4： | 1 |
| 10 | A pH-responsive mesoporous silica nanoparticles-based drug delivery system with controlled release of andrographolide for OA treatment显示文摘Andrographolide(AG)has favorable anti-inflammatory and antioxidative capacity.However,it has low bioavailability due to high lipophilicity and can be easily cleared by the synovial fluid after intra-articular injection,leading to low therapeutic efficiency in osteoarthritis(OA).Herein,we designed a nano-sized pH-responsive drug delivery system(DDS)for OA treatment by using modified mesoporous silica nanoparticles(MSNs)with pH-responsive polyacrylic acid(PAA)for loading of AG to form AG@MSNs-PAA nanoplatform.The nanoparticles have uniform size(120 nm),high drug loading efficiency(22.3860.71%)and pH-responsive properties,beneficial to sustained release in OA environment.Compared with AG,AG@MSNs-PAA showed enhanced antiarthritic efficacy and chondro-protective capacity based on IL-1b-stimulated chondrocytes and anterior cruciate ligament transection-induced rat OA model,as demonstrated by lower expression of inflammatory factors and better prevention of proteoglycan loss.Therefore,the AG@MSNs-PAA nanoplatform may be developed as a promising OA-specific and on-demand DDS. | Mingwei He Zainen Qin Xiaonan Liang Xixi He Bikang Zhu Zhenhui Lu Qingjun Wei Li Zheng | 2021 | Regenerative Biomaterials2021，8，4： | 1 |
| 11 | Cenozoic Vertical-Axis Rotations of the Hoh Xil Basin, Central–Northern Tibet显示文摘Understanding the Cenozoic vertical-axis rotation in the Tibetan Plateau is crucial for continental dynamic evolution. Paleomagnetic and rock magnetic investigations were carried out for the Oligocene and Miocene continental rocks of the Hoh Xil basin in order to better understand the tectonic rotations of central Tibet. The study area was located in the Tongtianhe area located in the southern part of the Hoh Xil basin and northern margin of the Tanggula thrust system in central-northern Tibet. A total of 160 independently oriented paleomagnetic samples were drilled from the Tongtianhe section for this study. The magnetic properties of magnetite and hematite have been recognized by measurements of magnetic susceptibility vs. temperature curves and unblocking temperatures. The mean directions of the Oligocene Yaxicuo Group in stratigraphic coordinates(Declination/Inclination = 354.9°/29.3°, k = 33.0, α_(95) = 13.5°, N =5 Sites) and of the Miocene Wudaoliang Group in stratigraphic coordinates(Declination/Inclination = 3.6°/36.4°, k = 161.0, α_(95) = 9.7°, N =3 Sites) pass reversal tests, indicating the primary nature of the characteristic magnetizations. Our results suggested that the sampled areas in the Tuotuohe depression of the Hoh Xil basin have undergone no paleomagnetically detectable rotations under single thrusting from the Tanggula thrust system. Our findings, together with constraints from other tectonic characteristics reported by previous paleomagnetic studies, suggest tectonic rotations in the Cuoredejia and Wudaoliang depressions of the Hoh Xil basin were affected by strike-slip faulting of the Fenghuo Shan-Nangqian thrust systems. A closer examination of geological data and different vertical-axis rotation magnitudes suggest the tectonic history of the Hoh Xil basin may be controlled by thrust and strike-slip faulting since the Eocene. | RAN Bo ZHAO Xixi LIU Zhifei WANG Chengshan ZHU Lidong JIN Wei LI Yalin | 2016 | Acta Geologica Sinica(English Edition)2016，90，3： | 1 |
| 12 | Constraints on the early uplift history of the Tibetan Plateau显示文摘 | Wang Chengshan Zhao Xixi Liu Zhifei Lippert P C Graham S A Coe R S Yi Haisheng Zhu Lidong Liu Shun Li Yalin | 2008 | PNAS2008，105，13： | 1 |
| 13 | Ionic Liquid-assisted Formation of Lanthanide Metal-organic Framework Nano/Microrods for Superefficient Removal of Congo Red显示文摘 | XIAO Yi CHEN Fang ZHU Xixi QIN Hongling HUANG Hongmei ZHANG Youyu YIN Dulin HE Xiaoxiao WANG Kemin | 2015 | Chemical Research in Chinese Universities2015，31，6： | 1 |
| 14 | Runoff sensitivity to climate changes in the Longitudinal Range-Gorge Region (LRGR): An example of the Longchuan Basin in the Upper Yangtze显示文摘 | ZHU Yunmei LU Xixi ZHOU Yue LIONG Shie-Yui | 2006 | Chinese Science Bulletin2006，51，B11： | 1 |
| 15 | Study on preparation and interlayer ion state of Fe/Ni pillared motmorillonite显示文摘 | Zhu Xixi Wang Li Gao Weijia | 2014 | Advanced Materials Research2014，873，： | 1 |
| 16 | Dissecting the epigenomic dynamics of human fetal germ cell development at single-cell resolution显示文摘Proper development of fetal germ cells(FGCs)is vital for the precise transmission of genetic and epigenetic information through generations.The transcriptional landscapes of human FGC development have been revealed;however,the epigenetic reprogramming process of FGCs remains elusive.Here,we profiled the genome-wide DNA methylation and chromatin accessibility of human FGCs at different phases as well as gonadal niche cells at single-cell resolution.First,we found that DNA methylation levels of FGCs changed in a temporal manner,whereas FGCs at different phases in the same embryo exhibited comparable DNA methylation levels and patterns.Second,we revealed the phase-specific chromatin accessibility signatures at the promoter regions of a large set of critical transcription factors and signaling pathway genes.We also identified potential distal regulatory elements including enhancers in FGCs.Third,compared with other hominid-specific retrotransposons,SVA_D might have a broad spectrum of binding capacity for transcription factors,including SOX15 and SOX17.Finally,using an in vitro culture system of human FGCs,we showed that the BMP signaling pathway promoted the cell proliferation of FGCs,and regulated the WNT signaling pathway by orchestrating the chromatin accessibility of its ligand genes.Our single-cell epigenomic atlas and functional assays provide valuable insights for understanding the strongly heterogeneous,unsynchronized,yet highly robust nature of human germ cell development. | Li Li Lin Li Qingqing Li Xixi Liu Xinyi Ma Jun Yong Shuai Gao Xinglong Wu Yuan Wei Xiaoye Wang Wei Wang Rong Li Jie Yan Xiaohui Zhu Lu Wen Jie Qiao Liying Yan Fuchou Tang | 2021 | Cell Research2021，31，4： | 1 |
| 17 | Two-step colloidal synthesis of micron-scale Bi_(2)O_(2)Se nanosheets and their electrostatic assembly for thin-film photodetectors with fast response显示文摘Recently discovered bismuth oxychalcogenide(Bi_(2) O_(2) Se) has aroused great interest due to its ultrahigh carrier mobility,tunable band gap and good environmental stability,making it a promising candidate for high-performance electronics and optoelectronics.Their synthesis by colloidal approaches represents a cost-effective alternative to well-established chemical vapor deposition methods,and the resulting electronic-grade inks are important for large-area printed or wearable electronics.However,it is still challenging to control the colloidal growth of Bi_(2) O_(2) Se nanosheets in solution in addition to their assembly into high-performance thin films.Here,we report a two-step colloidal synthesis of Bi_(2) O_(2) Se nanosheets by separating the seeding and growth steps,thereby achieving controllable production of nanosheets with a lateral size of 1.4 mm and a thickness of 10 nm at optimized reaction conditions.These Bi_(2) O_(2) Se nanosheets are electrostatically assembled into large-area thin films,from which a photodetector is fabricated with a responsivity of 6.1 A/W and a short response time of 368 ms under the 520-nm laser illumination.The device exhibits fast response to modulations as high as 100 k Hz,along with a à3 dB bandwidth of 1 kHz.This work provides an important understanding of the controlled colloidal synthesis of Bi_(2) O_(2) Se nanosheets,and demonstrates their potential applications in fast photodetectors. | Xixi Pang Yingtao Zhao Xiangxiang Gao Guoqi Wang Hao Sun Jun Yin Jian Zhu | 2021 | Chinese Chemical Letters2021，32，10： | 1 |
| 18 | Stacking monolayers at will:A scalable device optimization strategy for two-dimensional semiconductors显示文摘In comparison to monolayer(1L),multilayer(ML)two-dimensional(2D)semiconducting transition metal dichalcogenides(TMDs)exhibit more application potential for electronic and optoelectronic devices due to their improved current carrying capability,higher mobility,and broader spectral response.However,the investigation of devices based on wafer-scale ML-TMDs is still restricted by the synthesis of uniform and high-quality ML films.In this work,we propose a strategy of stacking MoS_(2) monolayers via a vacuum transfer method,by which one could obtain wafer-scale high-quality MoS_(2) films with the desired number of layers at will.The optical characteristics of these stacked ML-MoS_(2) films(>2L)indicate a weak interlayer coupling.The stacked MLMoS_(2) phototransistors show improved optoelectrical performances and a broader spectral response(approximately 300-1,000 nm)than that of 1L-MoS_(2).Additionally,the dual-gate ML-MoS_(2) transistors enable enhanced electrostatic control over the stacked ML-MoS_(2) channel,and the 3L and 4L thicknesses exhibit the optimal device performances according to the turning point of the current on/off ratio and the subthreshold swing. | Xiaojiao Guo Honglei Chen Jihong Bian Fuyou Liao Jingyi Ma Simeng Zhang Xinzhi Zhang Junqiang Zhu Chen Luo Zijian Zhang Lingyi Zong Yin Xia Chuming Sheng Zihan Xu Saifei Gou Xinyu Wang Peng Gong Liwei Liu Xixi Jiang Zhenghua An Chunxiao Cong Zhijun Qiu Xing Wu Peng Zhou Xinyu Chen Ling Tong Wenzhong Bao | 2022 | Nano Research2022，15，7： | 0 |
| 19 | In situ decorating the surface and interlayer of montmorillonite with Co_(0.5)Ni_(0.5)Fe_(2)O_(4) nanoparticles: A sustainable, biocompatible colorimetric platform for H_(2)O_(2) and acetylcholine显示文摘Originated from nature and used for nature is a way of sustainable development.In this work,montmorillonite(MMT),a natural two-dimensional(2D)layered mineral,the surface and interlayer of which were nano-decorated by chemical synthesis technique was applied in biological detection field.Magnetic ferrite(Co_(0.5)Ni_(0.5)Fe_(2)O_(4))was anchored on the surface and intercalated in the interlayer of montmorillonite,which served as a competitive candidate of enzyme mimics.Cytotoxicity test toward HUVEC and Hela cells verified the good biocompatibility of Co_(0.5)Ni_(0.5)Fe_(2)O_(4)-MMT,guaranteeing its safety in biological applications.Based on the peroxidase-like activity of Co_(0.5)Ni_(0.5)Fe_(2)O_(4)-MMT,a colorimetric sensing platform for H_(2)O_(2) was established by a facile mix-anddetect approach with the detection limit of 0.565μM(3σ/slope).It was implied that the peroxidase-like activity of Co_(0.5)Ni_(0.5)Fe_(2)O_(4)-MMT was originated from generation of·OH and·O_(2)–produced from catalytic decomposition process of H_(2)O_(2).Coupled with cascaded catalytic reactions of ACh,a facile and efficient sensing platform for ACh with satisfactory anti-interference ability was established.Thus,all these remarkable features highlighted the superiority of Co_(0.5)Ni_(0.5)Fe_(2)O_(4)-MMT,and endowed it with a powerful competitiveness in the fields of environmental assessing,biosensing,and disease monitoring. | Xixi Zhu Hongyu Li Tao Wu Hui Zhao Kaili Wu Wenjing Xu Fengjuan Qin Wenxing Chen Jinlong Zheng Qingyun Liu | 2022 | Nano Research2022，15，10： | 0 |
| 20 | Electrostatically connected nanoarchitected electrocatalytic films for boosted water splitting显示文摘Active sites of two-dimensional(2D)electrocatalysts are often partially blocked owing to their inevitable stacking and hydrophobic polymeric binders in macroscale electrodes,therefore impeding their applications in efficient electrolyzers.Here,using layered double hydroxide(LDH)nanosheets as a model 2D electrocatalyst,we demonstrate that their performance toward water splitting can be boosted when they are electrostatically assembled into an organized structure pillared by hydrophilic polyelectrolytes or nanoparticles in a layer-by-layer(LbL)fashion.In particular,their mass activity on a planar electrode can be as large as 2.267 mA·μg^(-1) toward oxygen evolution reaction(OER),when NiFe-LDH nanosheets are electrostatically connected by poly(sodium 4-styrenesulfonate)(PSS),while drop-casted NiFe-LDH nanosheets only have a mass activity of 0.116 mA·μg^(-1).In addition,these homogeneous NiFe-LDH nanofilms can be easily deposited on three-dimensional(3D)surfaces with high areas,such as carbon cloths,to serve as practical electrodes with overpotentials of 328 mV at a current density of 100 mA·cm^(-2),and stability for 40 h.Furthermore,Pt nanoparticles can be LbL assembled with NiFe-LDH as bifunctional electrodes for synergistically boosted oxygen and hydrogen evolution reactions(HER),leading to successful overall water splitting powered by a 1.5 V battery.This study heralds the spatial control of 2D nanomaterials in nanoscale precision as an efficient strategy for the design of advanced electrocatalysts. | Chao-Peng Wang Hao Sun Gang Bian Jia-Xi Wang Xixi Pang Guoqi Wang Jian Zhu Xian-He Bu | 2024 | Nano Research2024，17，3： | 0 |
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