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2篇 您的检索式:作者名="Xuran Han"
    题名 作者 年代 出处 被引量
1Lithiophilic hyperbranched Cu nanostructure for stable Li metal anodes显示文摘Porous copper(Cu)current collectors are regarded as a promising host for stabilizing lithium(Li)metal anodes but suffer from uncontrollable Li metal deposition due to the intrinsic lithiophobic nature of Cu.This study proposes a vertically aligned Cu host with hyperbranched CuxO nanostructure to provide lithiophilic nucleation sites for homogeneous Li metal deposition.Specifically,the vertically aligned Cu nanostructure dramatically reduces the local current density and brings homogeneous Li‐ion flux.The lithiophilic hyperbranched CuxO nanostructure with a low nucleation barrier could induce homogeneous Li nucleation and growth.As a result,the Cu@CuxO nanostructured host exhibits a low nucleation overpotential of 44.3 mV and achieves highly electrochemical reversibility with high Coulombic efficiency of 98.33%in a half‐cell.The Cu@CuxO nanostructured electrode is capable of working under different current densities varying from 0.5 to 5 mA/cm2 in a symmetric cell.The assembled full cell coupling of the Li/Cu@CuxO composite anode with the LiFePO4 cathode manifests stable long‐term cycling life at 1 C.This study elaborates on the synergistic effect of electrode structure design and interfacial chemistry modification to regulate the Li deposition/dissolution behavior,thus exhibiting remarkable electrochemical performances for next‐generation Li‐metal batteries.Jianyu Chen Xin Qiao Wei Fu Xuran Han Qiang Wu Yizhou Wang Yu Zhang Li Shi Jin Zhao Yanwen Ma 2023SmartMat2023,4,3:0
2Amorphous vanadium oxides for electrochemical energy storage显示文摘Vanadium oxides have attracted extensive interest as electrode materials for many electrochemical energy storage devices owing to the features of abundant reserves,low cost,and variable valence.Based on the in-depth understanding of the energy storage mechanisms and reasonable design strategies,the performances of vanadium oxides as electrodes for batteries have been significantly optimized.Compared to crystalline vanadium oxides,amorphous vanadium oxides(AVOs)show many unique properties,including large specific surface area,excellent electrochemical stability,lots of defects and active sites,fast ion kinetics,and high elasticity.This review gives a comprehensive overview of the recent progress on AVOs for different energy storage systems,such as alkali metal ion batteries,multivalent ion batteries,and supercapacitors with a special focus on the preparation strategies.The basic mechanisms for energy storage performance improvements of AVOs as compared to their crystalline counterparts are also introduced.Finally,challenges faced by AVOs are discussed and future development prospects are also proposed.This review aims to provide a comprehensive knowledge of AVOs and is expected to promote the development of high-performance electrodes for batteries.Qian He Zibo Chen Xingyu Niu Xuran Han Tian Kang Jianyu Chen Yanwen Ma Jin Zhao 2023Nano Research2023,16,7:0
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