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1Response to climate change of different tree species and NDVI variation since 1923 in the middle arid region of Ningxia,China显示文摘The normalized difference vegetation index(NDVI)is used extensively to describe vegetation cover and ecological environment change.The purpose of this study was to contrast the response of different tree species growing in the same habitat to climate change and retrieve past NDVI using tree-ring width data from tree cores collected from the transitional zone of Pinus tabulaeformis and Picea crassifolia in the Luoshan Mountains in the middle arid region of Ningxia.Correlation analysis indicated that radial growth of P.tabulaeformis is more sensitive to precipitation and temperature change than that of P.crassifolia.Natural factors such as water availability and heat at this elevation are more suited to the growth of P.crassifolia,and are more advantageous to its renewal and succession.P.crassifolia is probably the better of the two species for protecting the forest ecosystem and conserving water in the Luoshan desertification area.Ring width of P.crassifolia correlates significantly with average NDVI for April–May(r=0.641,p<0.01),and both of them are influenced positively by precipitation in April–May.The reconstructed NDVI for 1923–2007 shows the relatively low vegetation cover occurred in the 1920s–1930s,the1960s–1970s,and the early 21st century.The reconstructed NDVI better reflected the drought climate in the study area.YaJun Wang RuiJie Lu YuZhen Ma HongWei Meng ShangYu Gao 2014Research in Cold and Arid Regions2014,6,1:6
2High-performance all-polymer solar cells enabled by a novel low bandgap non-fully conjugated polymer acceptor显示文摘The non-fully conjugated polymer as a new class of acceptor materials has shown some advantages over its small molecular counterpart when used in photoactive layers for all-polymer solar cells(all-PSCs),despite a low power conversion efficiency(PCE)caused by its narrow absorption spectra.Herein,a novel non-fully conjugated polymer acceptor PFY-2TS with a low bandgap of~1.40 eV was developed,via polymerizing a largeπ-fused small molecule acceptor(SMA)building block(namely YBO)with a non-conjugated thioalkyl linkage.Compared with its precursor YBO,PFY-2TS retains a similar low bandgap but a higher LUMO level.Moreover,compared with the structural analog of YBO-based fully conjugated polymer acceptor PFY-DTC,PFY-2TS shows a similar absorption spectrum and electron mobility,but significantly different molecular crystallinity and aggregation properties,which results in optimal blend morphology with a polymer donor PBDB-T and physical processes of the device in all-PSCs.As a result,PFY-2TS-based all-PSCs achieved a PCE of 12.31%with a small energy loss of 0.56 eV enabled by the reduced non-radiative energy loss(0.24 eV),which is better than that of 11.08%for the PFY-DTC-based ones.Our work clearly demonstrated that non-fully conjugated polymers as a new class of acceptor materials are very promising for the development of high-performance all-PSCs.Qunping Fan Ruijie Ma Tao Liu Jianwei Yu Yiqun Xiao Wenyan Su Guilong Cai Yuxiang Li Wenhong Peng Tao Guo Zhenghui Luo Huiliang Sun Lintao Hou Weiguo Zhu Xinhui Lu Feng Gao Ellen Moons Donghong Yu He Yan Ergang Wang 2021Science China Chemistry2021,64,8:3
3Reconstructing the annual precipitation variation since 1899 based on tree-ring width in the western Hedong sandy land of Ningxia显示文摘Based on the analysis of the correlation between the tree-ring width of Pinus tabulaeformis and the climate factors in the western Hedong sandy land of Ningxia, a conversion equation between the annual precipitation and the tree-ring width since 1899 was reconstructed. The results of cross verification indicated that the conversion equation is stable and the reconstructed results are reliable. The result of reconstructed annual precipitation showed the remarkable fluctuation of precipitation and dry-to-wet variation before the 1940s. The smaller fluctuation and high frequent changes of precipitation occurred during the period of 1940s-1980s and after the 1980s the change trend of the precipitation became high periodic extent and low frequent. The study found that there were some coincidences with the climate change in Changling Mountains, Helan Mountains and the east of Qilian Mountains. The relatively dry periods in the beginning of 20th century, 1920s to 1930s, the end of the 20th century and 2004 to 2006 in the western Hedong sandy land of Ningxia accelerated the desertification, while the relatively humid period during the periods of the 1910s-1920s, 1930s-1940s and 1990s is favorable to prevent and control the desertification, and to weaken the climate warming and drying. The periods of annual precipitation variation in the western Hedong sandy land of Ningxia since 1899 are approximately 2-4 years, 5-7 years and 10 years.Wang, YaJun Gao, ShangYu Ma, YuZhen Lu, RuiJie Sang, YanLi Meng, HongWei 2010Journal of Arid Land2010,2,4:3
4Paleoclimatic evolution indicated by major geochemical elements from aeolian sediments on the east of Qinghai Lake显示文摘As the largest inland lake of China, along with its unique landscape and geographical location, Qinghai Lake has got much atten- tion of the scientists for a long time. The precursors have done substantive researches by using the lake sediment, which deepen our understanding of the climate changes in this region. Although sand dunes and loess sediment are widely distributed around the lake, so far the researches on geochemical elements from aeolian sediment have been less reported. In this paper, we selected a typical aeolian profile on the east of Qinghai Lake. Based on systematic sampling and analysis of seven major geochemical elements, combined with OSL dating and previous researches, this paper discusses climate changes in the Qinghai Lake area since 12.5 ka B.P.. Our conclusions are: (1) Before 12.5 ka B.P., the climate in this region was dry, cold, and accompanied by strong wind-sand activities. (2) During 12.5-11.9 ka B.P., the climate became warm and wet. However, there was an abrupt climate cooling event during 12.2-11.9 ka B.P., which likely corresponded to the Younger Dryas event. (3) During 11.9-8.0 ka B.P., the climate fluctuated greatly and frequently from warm to cold, and three cooling events occurred. (4) During 8.0-2.6 ka B.P., the climate was warm and humid. (5) Since 2.6 ka B.P., similar to the modern climate, the climate was mainly dry and cold.Yuan Shang RuiJie Lu FeiFei Jia LiHui Tian QingLiang Tang Yuan Chen Chao Zhao WangYang Wu 2013Research in Cold and Arid Regions2013,5,3:2
5Highly crystalline acceptor materials based on benzodithiophene with different amount of fluorine substitution on alkoxyphenyl conjugated side chains for organic photovoltaics显示文摘Organic solar cells based on narrow bandgap small-molecule acceptors(SMAs)with highly crystalline characteristics have attracted great attentions for their superiority in obtaining high photovoltaic efficiency.Employing highly crystalline SMAs to enhance power conversion efficiencies(PCEs)by regulating and controlling morphology and compatibility of donor and acceptor materials has turned out to be an effective approach.In this study,we synthesized three different crystalline SMAs by using fluorine substitution on alkoxyphenyl conjugated side chains to modulate the relationship of crystallinity and morphologies,namely ZY1(zero F atoms),ZY2(two F atoms),and ZY3(four F atoms).The three SMAs show the broad absorption edges and similar frontier orbital energy levels,generating the analogical(over 0.9 V)open circuit voltage(VOC)of the polymer solar cells(PSCs).As a result,the PM6:ZY2-based PSCs yield a PCE of 10.81%with a VOC of 0.95 V,a short-circuit current density(JSC)of 16.154 mA cm^(-2),and a fill factor(FF)of 0.71,which is higher than that of 9.17%(PM6:ZY1)and 6.37%(PM6:ZY3).And the PCE(17.23%)of the PM6:Y6:ZY2 based ternary PSCs is also higher than that of 16.32%PM6:Y6 based binary device.Obviously,the results demonstrate that adding fluorine atoms on the conjugated side chains to construct high crystalline materials is a positive strategy to effectively increase the efficiencies of binary and ternary PSCs.Youdi Zhang Ruijie Ma Yong Wang Ying Wang Tao Liu Yiqun Xiao Yongjoon Cho Zhenghui Luo Xinhui Lu Lun Zhao Zhongyi Yuan Changduk Yang He Yan Yiwang Chen 2021Materials Reports(Energy)2021,1,4:1
6Green‑Solvent Processed Blade‑Coating Organic Solar Cells with an Efficiency Approaching 19%Enabled by Alkyl‑Tailored Acceptors显示文摘Power-conversion-efficiencies(PCEs)of organic solar cells(OSCs)in laboratory,normally processed by spin-coating technology with toxic halogenated solvents,have reached over 19%.However,there is usually a marked PCE drop when the bladecoating and/or green-solvents toward large-scale printing are used instead,which hampers the practical development of OSCs.Here,a new series of N-alkyl-tailored small molecule acceptors named YR-SeNF with a same molecular main backbone are developed by combining selenium-fused central-core and naphthalene-fused endgroup.Thanks to the N-alkyl engineering,NIR-absorbing YR-SeNF series show different crystallinity,packing patterns,and miscibility with polymeric donor.The studies exhibit that the molecular packing,crystallinity,and vertical distribution of active layer morphologies are well optimized by introducing newly designed guest acceptor associated with tailored N-alkyl chains,providing the improved charge transfer dynamics and stability for the PM6:L8-BO:YRSeNF-based OSCs.As a result,a record-high PCE approaching 19%is achieved in the blade-coating OSCs fabricated from a greensolvent o-xylene with high-boiling point.Notably,ternary OSCs offer robust operating stability under maximum-power-point tracking and well-keep>80%of the initial PCEs for even over 400 h.Our alkyl-tailored guest acceptor strategy provides a unique approach to develop green-solvent and blade-coating processed high-efficiency and operating stable OSCs,which paves a way for industrial development.Hairui Bai Ruijie Ma Wenyan Su Top Archie Dela Pea Tengfei Li Lingxiao Tang Jie Yang Bin Hu Yilin Wang Zhaozhao Bi Yueling Su Qi Wei Qiang Wu Yuwei Duan Yuxiang Li Jiaying Wu Zicheng Ding Xunfan Liao Yinjuan Huang Chao Gao Guanghao Lu Mingjie Li Weiguo Zhu Gang Li Qunping Fan Wei Ma 2023Nano-Micro Letters2023,15,12:1
7Holocene aeolian activity and climatic change in Qinghai Lake Basin, northeastern Qinghai-Tibetan Plateau 显示文摘LU Ruijie JIA Feifei GAO Shangyu 2015Palaeogeography Palaeoclimatology Palaeoecology2015,430,:1
8Enhanced room-temperature Naþionic conductivity in Na_(4.92)Y_(0.92)Zr_(0.08)Si_(4)O_(12)显示文摘Developing cost-effective and reliable solid-state sodium batteries with superior performance is crucial for stationary energy storage.A key component in facilitating their application is a solid-state electrolyte with high conductivity and stability.Herein,we employed aliovalent cation substitution to enhance ionic conductivity while preserving the crystal structure.Optimized substitution of Y^(3+)with Zr^(4+)in Na_(5)YSi_(4)O_(12) introduced Naþion vacancies,resulting in high bulk and total conductivities of up to 6.5 and 3.3 mS cm^(-1),respectively,at room temperature with the composition Na_(4.92)Y_(0.92)Zr_(0.08)Si_(4)O_(12)(NYZS).NYZS shows exceptional electrochemical stability(up to 10 V vs.Naþ/Na),favorable interfacial compatibility with Na,and an excellent critical current density of 2.4 mA cm^(-2).The enhanced conductivity of Naþions in NYZS was elucidated using solid-state nuclear magnetic resonance techniques and theoretical simulations,revealing two migration routes facilitated by the synergistic effect of increased Naþion vacancies and improved chemical environment due to Zr^(4+)substitution.NYZS extends the list of suitable solid-state electrolytes and enables the facile synthesis of stable,low-cost Naþion silicate electrolytes.Aikai Yang Kai Yao Mareen Schaller Enkhtsetseg Dashjav Hang Li Shuo Zhao Qiu Zhang Martin Etter Xingchen Shen Huimin Song Qiongqiong Lu Ruijie Ye Igor Moudrakovski Quanquan Pang Sylvio Indris Xingchao Wang Qianli Ma Frank Tietz Jun Chen Olivier Guillon 2023eScience2023,3,6:0
9Warming hiatus of extreme temperature across China's cold regions during 1998-2018显示文摘The recent hiatus in global warming has attracted significant attention,yet whether it is a widespread global and/or regional phenomenon remains controversial.Here,we investigate the response of extreme temperature changes since 1961 across China's cold regions(CCR):Tibetan determine the spatiotemporal characteristics of extreme temperature changes across these cold regions using Mann-Kendall and wavelet transform coherence(WTC)analyses of data from 196 meteorological stations from 1961 to 2018.We further investigate the teleconnection between extreme temperatures and large-scale ocean-atmosphere circulation to determine the potential synoptic scale causes of the observed changes.The results revealed a significant warming slowdown in all extreme tempera-ture indices across CCR from 1998 to 2018.In addition,extreme temperature indices in northwest cold region(NWC)and north cold region(NC)reveal a clear winter warming slowdown and even a significant cooling trend,yet only the cold index in Tibetan Platean cold region(TPC)shows a warming hiatus.We conclude that the warming hiatus observed across these regions is primarily driven by extreme temperature index changes in winter.We also find that phase variations in the Atlantic Multi-decadal Oscillation(AMO)and Arctic Oscillation(AO)critically impact on the observed warming hiatus,but the specific atmospheric mechanisms are elusive and warrant further analysis and investigation.Luo MA Ruijie LU Dongxue CHEN 2022Frontiers of Earth Science2022,16,4:0
10Heteroheptacene-based acceptors with thieno[3,2-b]pyrrole yield high-performance polymer solar cells显示文摘Rationally utilizing and developing synthetic units is of particular significance for the design of high-performance non-fullerene small-molecule acceptors(SMAs).Here,a thieno[3,2-b]pyrrole synthetic unit was employed to develop a set of SMAs(ThPy1,ThPy2,ThPy3 and ThPy4)by changing the number or the position of the pyrrole ring in the central core based on a standard SMA of IT-4Cl,compared to which the four thieno[3,2-b]pyrrole-based acceptors exhibit bathochromic absorption and upshifted frontier orbital energy level due to the strong electron-donating ability of pyrrole.As a result,the polymer solar cells(PSCs)of the four thieno[3,2-b]pyrrole-based acceptors yield higher open-circuit voltage and lower energy loss relative to those of the IT-4Cl-based device.What is more,the ThPy3-based device achieves a power conversion efficiency(PCE)(15.3%)and an outstanding fill factor(FF)(0.771)that are superior to the IT-4Cl-based device(PCE=12.6%,FF=0.758).The ThPy4-based device realizes the lowest energy loss and the smallest optical band gap,and the ternary PSC device based on PM6:BTP-eC9:ThPy4 exhibits a PCE of 18.43%and a FF of 0.802.Overall,this work sheds light on the great potential of thieno[3,2-b]pyrrole-based SMAs in realizing low energy loss and high PCE.Zhenghui Luo Ruijie Ma Jianwei Yu Heng Liu Tao Liu Fan Ni Jiahao Hu Yang Zou Anping Zeng Chun-Jen Su U-Ser Jeng Xinhui Lu Feng Gao Chuluo Yang He Yan 2022National Science Review2022,9,7:0
11OPAQUE3, encoding a transmembrane bZIP transcription factor, regulates endosperm storage protein and starch biosynthesis in rice显示文摘Starch and storage proteins are the main components of rice(Oryza sativa L.)grains.Despite their importance,the molecular regulatory mechanisms of storage protein and starch biosynthesis remain largely elusive.Here,we identified a rice opaque endosperm mutant,opaque3(o3),that overaccumulates 57-kDa proglutelins and has significantly lower protein and starch contents than the wild type.The o3 mutant also has abnormal protein body structures and compound starch grains in its endosperm cells.OPAQUE3(O3)encodes a transmembrane basic leucine zipper(bZIP)transcription factor(OsbZIP60)and is localized in the endoplasmic reticulum(ER)and the nucleus,but it is localized mostly in the nucleus under ER stress.We demonstrated that O3 could activate the expression of several starch synthesis-related genes(GBSSI,AGPL2,SBEI,and ISA2)and storage protein synthesis-related genes(OsGluA2,Prol14,and Glb1).O3 also plays an important role in protein processing and export in the ER by directly binding to the promoters and activating the expression of OsBIP1 and PDIL1-1,two major chaperones that assist with folding of immature secretory proteins in the ER of rice endosperm cells.High-temperature conditions aggravate ER stress and result in more abnormal grain development in o3 mutants.We also revealed that OsbZIP50 can assist O3 in response to ER stress,especially under high-temperature conditions.We thus demonstrate that O3 plays a central role in rice grain development by participating simultaneously in the regulation of storage protein and starch biosynthesis and the maintenance of ER homeostasis in endosperm cells.Ruijie Cao Shaolu Zhao Guiai Jiao Yingqing Duan Liuyang Ma Nannan Dong Feifei Lu Mingdong Zhu Gaoneng Shao Shikai Hu Zhonghua Sheng Jian Zhang Shaoqing Tang Xiangjin Wei Peisong Hu 2022Plant Communications2022,3,6:0
12Achieving 16.68% efficiency ternary as-cast organic solar cells显示文摘State-of-the-art organic solar cells(OSCs)often require the use of high-boiling point additive or post-treatment such as temperature annealing and solvent vapor annealing to achieve the best efficiency.However,additives are not desirable in largescale industrial printing process,while post-treatment also increases the production cost.In this article,we report highly efficient ternary OSCs based on PM6:BTP-Cl Br1:BTP-2O-4Cl-C12(weight ratio=1:1:0.2),with 16.68%power conversion efficiency(PCE)for as-cast device,relatively close to its annealed counterpart(17.19%).Apart from obvious energy tuning effect and complementary absorption spectra,the improved PCE of ternary device is mainly attributed to improved morphological properties including the more favorable materials miscibility,crystallinity,domain size and vertical phase separation,which endorse suppressed recombination.The result of this work provides understanding and guidance for high-performance as-cast OSCs through the ternary strategy.Ruijie Ma Yang Tao Yuzhong Chen Tao Liu Zhenghui Luo Yuan Guo Yiqun Xiao Jin Fang Guangye Zhang Xiaojun Li Xia Guo Yuanping Yi Maojie Zhang Xinhui Lu Yongfang Li He Yan 2021Science China Chemistry2021,64,4:0
13Air-Processed Efficient Organic Solar Cells from Aromatic Hydrocarbon Solvent without Solvent Additive or Post-Treatment:Insights into Solvent Effect on Morphology显示文摘Most of the recent organic solar cells(OSCs)with top-of-the-line efficiencies are processed from organic solvents with a high vapor pressure such as CF in nitrogen-filled glovebox,which is not feasible for large-area manufacturing.Herein,we cast active layers with both aromatic hydrocarbon solvents and halogenated solvents without any solvent additive or post-treatment,as well as interlayers with water and methanol in air(35%relative humidity)for efficient OSCs,except cathode electrode's evaporation is in vacuum.Compared to the PM6:Y6 system that is processed from CF,the PM6:BTP-ClBr2 system demonstrates good efficiency of 16.28%processed from CB and the device based on PM6:BTP-4Cl achieves 16.33%using TMB as its solvent for the active layer.These are among the highest efficiencies for CB-and TMB-processed binary OSCs to date.The molecular packing and phase separation length scales of each combination depend strongly on the solvent,and the overall morphology is the result of the interplay between solvent evaporation(kinetics)and materials miscibility(thermodynamics).Different solvents are required to realize the optimal morphology due to the different miscibility between the donor and acceptor.Finally,17.36%efficiency was achieved by incorporating PC71BM for TMB-processed devices.Our result provides insights into the effect of processing solvent and shows the potential of realizing high-performance OSCs in conditions relevant for industrial fabrication.Ruijie Ma Tao Yang Yiqun Xiao Tao Liu Guangye Zhang Zhenghui Luo Gang Li Xinhui Lu He Yan Bo Tang 2022Energy & Environmental Materials2022,5,3:0
14Isolation,Identification and Characteristics of Cellulose-degrading Bacteria显示文摘[Objectives]To isolate and identify characteristics of the cellulose-degrading bacteria.[Methods]In view of the poor effect of crop straw composting,the strains which can degrade cellulose were isolated and purified from the soil piled with rice straw,and the strains A2 and A5 with high efficiency of cellulose degradation were finally screened through the transparent circle,cellulase activity and filter paper disintegration experiments.[Results]It was confirmed that the strains A2 and A5 could degrade cellulose well.The results of 16s rDNA showed that A2 was Pseudoxanthomonas mexicana and A5 was Bacillus cibi.[Conclusions]The results of this study are expected to provide high-quality strain resources for the degradation of cellulose in straw,and have important application value for improving the efficiency of straw composting.Shasha LIU Ruiji LU Nuo CHEN 2023Asian Agricultural Research2023,15,12:0
15Pressureless all-solid-state Na/S batteries with self-supporting Na_(5)YSi_(4)O_(12) scaffolds显示文摘The development of reliable and affordable all-solid-state sodium metal batteries(ASS-SMBs)requires suitable solid-state electrolytes with cost-efficient processing and stabilized electrode/electrolyte interfaces.Here,an integrated porous/dense/porous Na_(5)YSi_(4)O_(12)(NYS)trilayered scaffold is designed and fabricated by tape casting using aqueous slurries.In this template-based NYS scaffold,the dense layer in the middle serves as a separator and the porous layers on both sides accommodate the active materials with their volume changes during the charge/discharge processes,increasing the contact area and thus enhancing the utilization rate and homogenizing the current distribution.The Na/NYS/Na symmetric cells with the Pb-coated NYS scaffold exhibit significantly reduced interfacial impedance and superior critical current density of up to 3.0 mA cm^(-2)against Na metal owing to enhanced wettability.Furthermore,the assembled Na/NYS/S full cells operated without external pressure at room temperature showed a high initial discharge capacity of 970 mAh g^(-1)and good cycling stability with a capacity of 600 mAh g^(-1)after 150 cycles(based on the mass of sulfur).This approach paves the way for the realization of economical and practical ASS-SMBs from the perspective of ceramic manufacturing.Aikai Yang Ruijie Ye Huimin Song Qiongqiong Lu Xingchao Wang Enkhtsetseg Dashjav Kai Yao Daniel Grüner Qianli Ma Frank Tietz Olivier Guillon 2023Carbon Energy2023,5,12:0
16Projection of China’s future runoff based on the CMIP6 mid-high warming scenarios显示文摘The latest Coupled Model Intercomparison Project Phase 6(CMIP6)proposes new shared pathways(SSPs)that incorporate socioeconomic development with more comprehensive and scientific experimental designs;however,few studies have been performed on the projection of future multibasin hydrological changes in China based on CMIP6 models.In this paper,we use the Equidistant Cumulative Distribution Function method(EDCDFm)to perform downscaling and bias correction in daily precipitation,daily maximum temperature,and daily minimum temperature for six CMIP6 models based on the historical gridded data from the high-resolution China Meteorological Forcing Dataset(CMFD).We use the bias-corrected precipitation,temperature,and daily mean wind speed to drive the variable infiltration capacity(VIC)hydrological model,and study the changes in multiyear average annual precipitation,annual evapotranspiration and total annual runoff depth relative to the historical baseline period(1985–2014)for the Chinese mainland,basins and grid scales in the 21st century future under the SSP2-4.5 and SSP5-8.5 scenarios.The study shows that the VIC model accurately simulates runoff in major Chinese basins;the model data accuracy improves substantially after downscaling bias correction;and the future multimodel-mean multiyear average annual precipitation,annual evapotranspiration,and total annual runoff depth for the Chinese mainland and each basin increase relative to the historical period in near future(2020–2049)and far future(2070–2099)under the SSP2-4.5 and SSP5-8.5scenarios.The new CMIP6-based results of this paper can provide a strong reference for extreme event prevention,water resource utilization and management in China in the 21st century.Jiayue ZHOU Hui LU Kun YANG Ruijie JIANG Yuan YANG Wei WANG Xuejun ZHANG 2023Science China Earth Sciences2023,66,3:0
17All-polymer solar cells with over 16%efficiency and enhanced stability enabled by compatible solvent and polymer additives显示文摘Considering the robust and stable nature of the active layers,advancing the power conversion efficiency(PCE)has long been the priority for all-polymer solar cells(all-PSCs).Despite the recent surge of PCE,the photovoltaic parameters of the stateof-the-art all-PSC still lag those of the polymer:small molecule-based devices.To compete with the counterparts,judicious modulation of the morphology and thus the device electrical properties are needed.It is difficult to improve all the parameters concurrently for the all-PSCs with advanced efficiency,and one increase is typically accompanied by the drop of the other(s).In this work,with the aids of the solvent additive(1-chloronaphthalene)and the n-type polymer additive(N2200),we can fine-tune the morphology of the active layer and demonstrate a 16.04%efficient all-PSC based on the PM6:PY-IT active layer.The grazing incidence wideangle X-ray scattering measurements show that the shape of the crystallites can be altered,and the reshaped crystallites lead to enhanced and more balanced charge transport,reduced recombination,and suppressed energy loss,which lead to concurrently improved and device efficiency and stability.Ruijie Ma Jianwei Yu Tao Liu Guangye Zhang Yiqun Xiao Zhenghui Luo Gaoda Chai Yuzhong Chen Qunping Fan Wenyan Su Gang Li Ergang Wang Xinhui Lu Feng Gao Bo Tang He Yan 2022Aggregate2022,3,3:0
18Fine-tuning HOMO energy levels between PM6 and PBDB-T polymer donors via ternary copolymerization显示文摘To achieve high-efficiency polymer solar cells(PSCs),it is not only important to develop high-performance small molecule acceptors(SMAs)but also to find a matching polymer donor to achieve optimal morphology and matching electronic properties.Currently,state-of-the-art SMAs mostly rely on a donor polymer named PM6.However,as the family of SMAs continues to expend,PM6 may not be the perfect polymer donor due to the requirement of energy level matching.In this work,we tune the energy level of PM6 via the strategy of ternary copolymerization.We achieve two donor polymers(named PL-1 and PL-2)with upshifted HOMO(the highest occupied molecular orbital)energy level(compared with PM6),and can thus match with the SMAs with upshifted HOMO energy levels compared with Y6.These two copolymers exhibit slightly higher order of molecular packing and similar charge transport properties,which demonstrate that the method of ternary copolymerization can fine tune the HOMO level of donor polymers,while the morphology and mobility of the blend film remain mostly unaffected.Among them,the best device based on PL-1:Y6 exhibits power conversion efficiencies(PCEs)of 16.37%with lower open circuit voltage(Voc)but higher short circuit current voltage(Jsc)and fill factor(FF)than that of the device based on PM6:Y6.This work provides an effective approach to find polymer matches for the SMAs with upshifted HOMO levels.Xiaojun Li Ruijie Ma Tao Liu Yiqun Xiao Gaoda Chai Xinhui Lu He Yan Yongfang Li 2020Science China Chemistry2020,63,9:0
19Effects of yellow and green light stress on emergence,feeding and mating of Anomala corpulenta Motschulsky and Holotrichia parallela Motschulsky(Coleoptera:Scarabaeidae)显示文摘Light is one of the key environmental factors for insects to survive.Artificial light sources different from natural environmental light can cause light stress in insects.Yellow and green light stress can interfere with the diurnal rhythm of nocturnal moths and their mating,oviposition,and adult longevity.The scarabaeid beetles Anomala corpulenta Motschulsky and Holotrichia parallela Motschulsky are widely distributed,and they are very harmful underground pests.In order to clarify the effects of light stress on their behaviors,individuals of both species were exposed to yellow light(565-585 nm)and green light(525-545 nm),with different light intensity gradients of yellow light in a laboratory setting.The short-term light stress treatment of A.corpulenta and H.parallela was carried out at night.The number of beetles emerging per half an hour was recorded,and mating pairs and feeding activity in 24 h were counted.The results showed that yellow and green light stress significantly changed the rhythm and reduced the rate of beetle emergence in the two beetle species investigated.Also,the peak emergence activity was delayed and the feeding and mating activities were significantly reduced.When treated with different intensities of yellow light,it was found that the rate of emergence of A.corpulenta under 10 lx was close to the control groups.The rate of emergence in H.parallela was significantly lower than the control groups before 0:00,in the 60 lx and 110 lx treatment groups,but after 0:00,the emergence rate of H.parallela was significantly higher in the 60 lx and 110 lx treatment groups than other treatments.However,the emergence rhythms in the three light intensity treatment groups are basically the same as in the control groups.The feeding amount and mating beetles in the three light intensity treatment groups were significantly lower than in the control groups.There were no significant differences in the three treatments.The results show that light stress above 10 lx significantly interferes with the behavioral activities of the two beetle species,investigated.This study provides a new approach for a light control technology for nocturnal beetle pest species.Yueli Jiang Qiuying Huang Guoshu Wei Zhongjun Gong Tong Li Jin Miao Ruijie Lu Shiqiong Mei Xueqin Wang Yun Duan Yuqing Wu Chuantao Lu 2023International Journal of Agricultural and Biological Engineering2023,16,1:0
20NDVI Variation of Tree Rings between March and May since 1915 in the Eastern Part of the Qilian Mountains of China显示文摘[Objective] The aim was to analyze the correlation between tree-ring width of Picea crassifolia in the east of Qilian Mountains and the precipitation, temperature and the normalized difference vegetation index (NDVI). [Method] The correlation analysis and the regression analysis were used in this study. [Result] The tree-ring width was significantly correlated with the autumn precipitation and the spring average NDVI. The conversion equation between tree-ring width and spring NDVI (R2 = 48.5% , R2adj =46.2% , F =21.627, P <0.001) was developed and NDVI sequence was reconstructed during the period 1915 -2007. The drought in the 1920s was pronounced. Vegetation cover in the Qilian Mountains increased during the period 1922-1934, 1940-1957, 1965-1969, 1984-1988 and 1995-1997, but decreased during 1935 -1939, 1958 -1964, 1970 -1983, 1989 -1994 and 1998 -2005. [Conclusion] The reconstructed NDVI showed the drought evolution in the study area.Yajun WANG Ruijie LU Hongwei MENG Yanli SANG 2013Agricultural Science & Technology2013,14,6:0
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