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| 1 | Synthesis and electrocatalytic activity of Au@Pd coreshell nanothorns for the oxygen reduction reaction显示文摘有多孔的表面的二金属的核心壳 nanostructures 在各种各样的领域里由于他们的有希望的应用引起了可观的注意,包括催化作用和电子学。在这个工作,有不平、多孔的表面的 Au@Pd 核心壳 nanothorns (CSNT ) 面对 polyallylamine hydrochloride 通过一个灵巧的合作化学药品减小方法第一次被综合(哼) 并且乙烯乙二醇(例如) 在房间温度。Au@Pd CSNT 的尺寸,形态学,和作文被传播电子显微镜学(TEM ) 调查, X 光检查衍射(XRD ) ,精力散光谱学(EDX ) ,印射的 EDX,和 X 光检查光电子光谱学(XPS ) 。同样综合的 Au@Pd CSNT 的电气化学的性质被各种各样的电气化学的技术也学习。Au@Pd CSNT 在碱的媒介为氧减小反应(ORR ) 展出了显著地高的 electrocatalytic 活动和耐久性,由于在 Au 核心和 Pd 壳之间的唯一的多孔的结构和 synergistic 效果。 | Gengtao Fu Zhenyuan Liu Yu Chen Jun Lin Yawen Tang Tianhong Lu | 2014 | Nano Research2014,7,8: | 15 |
| 2 | GBSS-BINDING PROTEIN,encoding a CBM48 domain-containing protein,affects rice quality and yield^∞显示文摘The percentage of amylose in the endosperm of rice(Oryza sativa)largely determines grain cooking and eating qualities.Granule-bound starch synthase I(GBSSI)and GBSSII are responsible for amylose biosynthesis in the endosperm and leaf,respectively.Here,we identified OsGBP,a rice GBSS-binding protein that interacted with GBSSI and GBSSII in vitro and in vivo.The total starch and amylose contents in osgbp mutants were significantly lower than those of wild type in leaves and grains,resulting in reduced grain weight and quality.The carbohydrate-binding module 48(CBM48)domain present in the C-terminus of OsGBP is crucial for OsGBP binding to starch.In the osgbp mutant,the extent of GBSSI and GBSSII binding to starch in the leaf and endospermwas significantly lower than wild type.Our data suggest that OsGBP plays an important role in leaf and endosperm starch biosynthesis by mediating the binding of GBSS proteins to developing starch granules.This elucidation of the function of OsGBP enhances our understanding of the molecular basis of starch biosyn-thesis in rice and contributes information that can be potentially used for the genetic improvement of yield and grain quality. | Wei Wang Xiangjin Wei Guiai Jiao Wenqiang Chen Yawen Wu Zhonghua Sheng Shikai Hu Lihong Xie Jiayu Wang Shaoqing Tang Peisong Hu | 2020 | Journal of Integrative Plant Biology2020,62,7: | 12 |
| 3 | Ultrathin AgPt alloy nanowires as a high-performance electrocatalyst for formic acid oxidation显示文摘探讨不够的 electrocatalytic 活动和蚁的酸氧化反应(FAOR ) 的稳定性 electrocatalysts,以及他们的高度花费了,我们此处表明 ultrathin AgPt 合金 nanowires 的灵巧的热水的合成用终止胺 poly (N-isopropylacrylamide )(PNIPAM-NH 2) 作为一个指导结构的代理人。AgCl 的起始的产生猛抛, AgPt nanoparticles 的随后的形成,和他们的面向的附件说明 ultrathin AgPt 合金 nanowires 的形成。得益于他们的唯一的 1D anisotropy 和 alloyed 作文,准备 ultrathin AgPt nanowires 展览为 FAOR 的一项优异 electrocatalytic 活动和更好的公司忍耐,到达 1.6 褶层和 3.7 褶层更高特定的当前的密度比 AgPt nanoparticles 和商业磅黑人催化剂分别地。另外, ultrathin AgPt 合金 nanowires 在 electrocatalysis 期间表明优异电气化学的稳定性和结构的坚韧性,使他们成为有希望的 FAOR electrocatalyst。这个工作不仅为高贵基于金属的 ultrathin nanowires 的合成提供可靠策略,而且在新窗户中为燃料房间 systems.Open 图象向有效 electrocatalysts | Xian Jiang Gengtao Fu Xia Wu Yang Liu Mingyi Zhang Dongmei Sun Lin Xu Yawen Tang | 2018 | Nano Research2018,11,1: | 9 |
| 4 | Spinel MnCo2O4 nanoparticles cross-linked with two-dimensional porous carbon nanosheets as a high-efficiency oxygen reduction electrocatalyst显示文摘为氧减小反应(ORR ) 的催化剂在燃料房间起一个重要作用。有到基于磅的催化剂的可比较的 ORR 活动的其他的非宝贵的金属催化剂为燃料房间的发展是高度合乎需要的。在这个工作,我们第一次报导尖晶石 MnCo 2 O 4/C ORR 催化剂由一致 MnCo 2 O 4 nanoparticles cross-linked 与二维( 2D )多孔的碳 nanosheets (缩短的同样多孔的 MnCo 2 O 4/C nanosheets ),在哪个葡萄糖作为模板被用作碳来源和 NaCl 。获得的多孔的 MnCo 2 在场的 O 4/C nanosheets 互连的多孔的体系结构和一个大表面区域的联合性质(175.3 m 2( | Gengtao Fu Zhenyuan Liu Jingfei Zhang Jiayan Wu Lin Xu Dongmei Sun Jubing Zhang Yawen Tang Pei Chen | 2016 | Nano Research2016,9,7: | 7 |
| 5 | Facile synthesis based on novel carbon-supported cyanogel of structurally ordered Pd3Fe/C as electrocatalyst for formic acid oxidation显示文摘 | Zhenyuan Liu Gengtao Fu Jiahui Li Zhenqi Liu Lin Xu Dongmei Sun Yawen Tang | 2018 | Nano Research2018,11,9: | 6 |
| 6 | Dendritic platinum-copper bimetallic nanoassemblies with tunable composition and structure: Arginine-driven self-assembly and enhanced electrocatalytic activity显示文摘 | Gengtao Fu Huimin Liu Nika You Jiayan Wu Dongmei Sun Lin Xu Yawen Tang Yu Chen | 2016 | Nano Research2016,9,3: | 6 |
| 7 | OsVP1 activates Sdr4 expression to control rice seed dormancy via the ABA signaling pathway显示文摘Pre-harvest sprouting(PHS)is a disadvantageous trait in cereal production worldwide,causing large economic losses each year.Its regulation mechanism is still unclear.We generated the Oryza sativa Viviparous1(OsVP1)mutant using gene editing technique,which shows increased PHS compared with that of the wild type Nipponbare.OsVP1 is localized mainly in the nucleus and expressed in various tissues and organs.Expression of Seed dormancy 4(Sdr4),a key gene controlling PHS,was sharply reduced in OsVP1 mutants.OsVP1 bound to the specific motif CACCTG in the promoter of Sdr4 and activated its expression in rice protoplasts.Overexpression of Sdr4 reduced the high seed germination rate of OsVP1 mutant cr-osvp1-1,showing that Sdr4 acts as a downstream target of OsVP1.Both OsVP1 and Sdr4 loss-of-function mutants were insensitive to exogenous ABA and employed the ABA signaling pathway in regulating seed dormancy.These findings shed light on the control of seed dormancy aimed at preventing PHS in rice. | Wenqiang Chen Wei Wang Yusong Lyu Yawen Wu Pingliang Huang Shikai Hu Xiangjin Wei Guiai Jiao Zhonghua Sheng Shaoqing Tang Gaoneng Shao Ju Luo | 2021 | The Crop Journal2021,9,1: | 5 |
| 8 | 1-Naphthol induced PtsAg nanocorals as bifunctional cathode and anode catalysts of direct formic acid fuel cells显示文摘Developing highly efficient bifunctional cathode and anode electrocatalysts is very important for the large-scale application of direct formic acid fuel cells. However, the high-cost and poor CO-tolera nee ability of the most commonly used Pt greatly block this process. To in crease the utilizatio n efficie ncy and exte nd bifunctional properties of precious Pt, herei n, coral-like Pt3Ag nano crystals are developed as an excelle nt bifunctional electrocatalyst through a facile one-pot solvothermal method. The formation mechanism of Ptgg nanocorals has been elaborated well via a series of control experiments. It is proved that 1-naphthol serving as a guiding surfactant plays a key role in the formation of high-quality nano corals. Thanks to the unique coral-like structure and alloy effects, the developed Ptgg nano corals present sign ificantly enhanced electrocatalytic properties (including activity, stability and CO-toleranee ability) towards both the cathodic oxygen reduction and anodic formic acid oxidati on, as compared with those of commercial Pt black and Pt-based nan oparticles. The prese nt synthetic method can also be extended to fabricate other bimetallic electrocatalysts with unique morphology and structure. | Xian Jiang Yang Liu Jiaxin Wang Yufei Wang Yuexin Xiong Qun Liu Naixu Li Jiancheng Zhou Gengtao Fu Dongmei Sun Yawen Tang | 2019 | Nano Research2019,12,2: | 4 |
| 9 | Arginine-mediated synthesis of cube-like platinum nanoassemblies as efficient electrocatalysts显示文摘可控制高贵金属 nanocrystals 自己组装具有为高度活跃的 electrocatalysts 的发展的宽广兴趣。这里,我们与多孔的洞和不平的表面为像立方体的磅 nanoassemblies (Pt-CNAs ) 的产量很高的合成报导一条有效调停精氨酸的热水的途径基于零维的磅 nanocrystals 自己组装。在这进程,精氨酸充当在邻近的 nanocrystals 之间的 reductant,结构指导代理人,和连接器。有趣地, Pt-CNAs 展览单个水晶的结构与主导 { 100 } 方面由 X 光检查衍射证实了。把研究基于 electrocatalytic,同样综合的 Pt-CNAs 展览在甲醇氧化反应改进了 electrocatalytic 活动以及好稳定性和公司忍耐。Pt-CNAs 好表演被归因于他们的唯一的形态学和表面结构。我们相信这里构画出的合成策略能被递讲道理地设计的其它为在高效燃料房间的使用的一金属或二金属的 nanoassemblies。 | Gengtao Fu Qian Zhang Jiayan Wu Dongmei Sun Lin Xu Yawen Tang Yu Chen | 2015 | Nano Research2015,8,12: | 4 |
| 10 | In-situ growth of Ni nanoparticle-encapsulated N-doped carbon nanotubes on carbon nanorods for efficient hydrogen evolution electrocatalysis显示文摘Searching for inexpensive,efficient and durable electrocatalysts with earth-abundant elements toward the hydrogen evolution reaction(HER)is of vital importance for the future sustainable hydrogen economy,yet still remains a formidable challenge.Herein,a facile template-engaged strategy is demonstrated for the direct in-situ growth of Ni nanoparticles and N-doped carbon nanotubes on carbon nanorod substrates,forming a hierarchically branched architecture(abbreviated as Ni@N-C NT/NRs hereafter).The elaborate construction of such unique hierarchical structure with tightly encapsulated Ni nanoparticles and open configuration endows the as-fabricated Ni@N-C NT/NRs with abundant well-dispersed active sites,enlarged surface area,reduced resistances of charge transfer and mass diffusion,and reinforced mechanical robustness.As a consequence,the optimal Ni@N-C NT/NR catalyst demonstrates superior electrocatalytic activity with relatively low overpotential of 134 mV to deliver a current density of 10 mA·cm^-2 and excellent stability for HER in 0.1 M KOH,holding a great promise for practical scalable H2 production.More importantly,this work offers a reliable methodology for feasible fabrication of robust high-performance carbon-based hierarchical architectures for a variety of electrochemical applications. | Xiaoxiao Yan Minyi Gu Yao Wang Lin Xu Yawen Tang Renbing Wu | 2020 | Nano Research2020,13,4: | 4 |
| 11 | Trimetallic PtRhNi alloy nanoassemblies as highly active electrocatalyst for ethanol electrooxidation显示文摘尽管 nanostructures 广泛地基于高贵金属合金被利用在(电镀物品) 催化作用,他们的低温度的合成由于金属先锋的不同 Nernst 平衡潜力仍然是庞大的挑战。此处,我们用一个简单混合 cyanogel 减小方法与悦耳的 Pt/Rh 比率描述 trimetallic PtRhNi 合金 nanoassemblies (PtRhNi 言论集) 的成功的合成并且提供他们的化学作文,形态学,和结构的详细描述。另外, PtRhNi 言论集的电气化学的性质被周期的 voltammetry 检验,揭示在乙醇氧化反应(EOR ) 的作文依赖者 electrocatalytic 活动。比作商业磅黑人 electrocatalyst,优化的磅 3 Rh 1 Ni 2-ANAs 显示显著地在碱的媒介提高了 EOR electrocatalytic 性能。 | Huimin Liu Jiahui Li Lijuan Wang Yawen Tang Bao Yu Xia Yu Chen | 2017 | Nano Research2017,10,10: | 4 |
| 12 | Chemically Binding Scaffolded Anodes with 3D Graphene Architectures Realizing Fast and Stable Lithium Storage显示文摘Tree-dimensional(3D)graphene has emerged as an ideal platform to hybridize with electrochemically active materials for improved performances.However,for lithium storage,current anodic guests ofen exist in the form of nanoparticles,physically attached to graphene hosts,and therefore tend to detach from graphene matrices and aggregate into large congeries,causing considerable capacity fading upon repeated cycling.Herein,we develop a facile double-network hydrogel-enabled methodology for chemically binding anodic scafolds with 3D graphene architectures.Taking tin-based alloy anodes as an example,the doublenetwork hydrogel,containing interpenetrated cyano-bridged coordination polymer hydrogel and graphene oxide hydrogel,is directly converted to a physical-intertwined and chemical-bonded Sn−Ni alloy scafold and graphene architecture(Sn−Ni/G)dual framework.Te unique dual framework structure,with remarkable structural stability and charge-transport capability,enables the Sn−Ni/G anode to exhibit long-term cyclic life(701 mA h g^(−1) afer 200 cycles at 0.1 A g^(−1))and high rate performance(497 and 390 mA h g^(−1) at 1 and 2 A g^(−1),respectively).Tis work provides a new perspective towards chemically binding scafolded low-cost electrode and electrocatalyst materials with 3D graphene architectures for boosting energy storage and conversion. | Ping Wu Zhiwei Fang Anping Zhang Xiao Zhang Yawen Tang Yiming Zhou Guihua Yu | 2019 | Research2019,,1: | 4 |
| 13 | In situ establishment of Co/MoS_(2) heterostructures onto inverse opal‐structured N,S‐doped carbon hollow nanospheres:Interfacial and architectural dual engineering for efficient hydrogen evolution reaction显示文摘Rational design of low‐cost and high‐efficiency non‐precious metal‐based catalysts toward the hydrogen evolution reaction(HER)is of paramount significance for the sustainable development of the hydrogen economy.Interfacial manipulationinduced electronic modulation represents a sophisticated strategy to enhance the intrinsic activity of a non‐precious electrocatalyst.Herein,we demonstrate the straightforward construction of Co/MoS_(2) hetero‐nanoparticles anchored on inverse opal‐structured N,S‐doped carbon hollow nanospheres with an ordered macroporous framework(denoted as Co/MoS_(2)@N,S-CHNSs hereafter)via a templateassisted method.Systematic experimental evidence and theoretical calculations reveal that the formation of Co/MoS_(2) heterojunctions can effectively modulate the electronic configuration of active sites and optimize the reaction pathways,remarkably boosting the intrinsic activity.Moreover,the inverse opal‐structured carbon substrate with an ordered porous framework is favorable to enlarge the accessible surface area and provide multidimensional mass transport channels,dramatically expediting the reaction kinetics.Thanks to the compositional synergy and structural superiority,the fabricated Co/MoS_(2)@N,S-CHNSs exhibit excellent HER activity with a low overpotential of 105mV to afford a current density of 10 mA/cm^(2).The rationale of interface manipulation and architectural design herein is anticipated to be inspirable for the future development of efficient and earth‐abundant electrocatalysts for a variety of energy conversion systems. | Tingyu Lu Tongfei Li Desheng Shi Jialin Sun Huan Pang Lin Xu Jun Yang Yawen Tang | 2021 | SmartMat2021,2,4: | 3 |
| 14 | Trimetallic Au@PdPb nanowires for oxygen reduction reaction显示文摘The development of highly efficient and stable Pd-based catalysts is crucial to improve their sluggish oxygen reduction reaction(ORR)kinetics in acid media.To improve ORR activity and utilization efficiency of Pd,an ideal catalyst should have ORR-favorable chemical environment,optimized geometric structure,and long periods of operation.In this work,we first synthesize a novel trimetallic Au@PdPb core–shell catalyst consisting of PdPb alloy nano-layers grown on the surface of ultrathin Au nanowires(NWs)by a two-step water-bath method.The Au@PdPb NWs have the merits of anisotropic one-dimensional nanostructure,high utilization efficiency of Pd atoms and doping of Pb atoms.Because of the structural and multiple compositional advantages,Au@PdPb NWs exhibit remarkably enhanced ORR activity with a high haIf-wave potential(0.827 V),much better than those of commercial Pd black(0.788 V)and bimetallic Au@Pd NWs(0.803 V).Moreover,Au@PdPb NWs display better electrocatalytic stability for the ORR than those of Pd black and Au@Pd NWs.This study demonstrates the validity of our approach for deriving highly ORR-active Pd-based catalysts by modifying their structure and composition. | Xian Jiang Yuexin Xiong Ruopeng Zhao Jiancheng Zhou Jong-Min Lee Yawen Tang | 2020 | Nano Research2020,13,10: | 3 |
| 15 | Hollow PtNi alloy nanospheres with enhanced activity and methanol tolerance for the oxygen reduction reaction显示文摘为氧减小反应(ORR ) 的活跃、甲醇容忍的阴极 electrocatalysts 的发展为加速直接甲醇燃料房间(DMFC ) 的商业生存能力是极其重要的。在这个工作,我们在场为氰化物(CN ) 的灵巧的合成的一条有效、没有模板的线路有用在房间温度的一个简单 cyanogel 减小方法的高 alloying 度的 -functionalized PtNi 空 nanospheres (PtNi@CN HNS ) 。物理并且 PtNi@CN HNS 的 electrocatalytic 性质被各种各样的物理、电气化学的技术调查。当与商业磅黑色相比,并且这样他们为 DMFC 正在答应阴极 electrocatalysts,显著地展出的 PtNi@CN HNS 为 ORR 提高了 electrocatalytic 活动,耐久性,和特别甲醇忍耐。 | Huimin Liu Xinyu Liu Yumei Li Yufeng Jia Yawen Tang Yu Chen | 2016 | Nano Research2016,9,11: | 2 |
| 16 | Improvement and mechanism of electrocatalytic performance of Pd–Ni/C anodic catalyst in direct formic acid fuel cell显示文摘 | Liping Shen Huanzhi Li Liang Lu Yafen Luo Yawen Tang Yu Chen Tianhong Lu | 2013 | Electrochimica Acta2013,,: | 2 |
| 17 | Fine mapping a QTL qCTB7 for cold tolerance at the booting stage on rice chromosome 7 using a near-isogenic line显示文摘 | Lei Zhou Yawen Zeng Weiwei Zheng Bo Tang Shuming Yang Hongliang Zhang Jinjie Li Zichao Li | 2010 | Theoretical and Applied Genetics2010,,5: | 2 |
| 18 | A carbon-sup- ported Pd-P catalyst as the anodic catalyst in a direct formic acid fuel cell显示文摘 | Lingling Zhang Yawen Tang Jianchun Bao et a/ | 2006 | Power Sources2006,162,: | 1 |
| 19 | Solution processed low power organic field-effect transistor bio-chemical sensor of high transconductance efficiency显示文摘Developing organic field-effect transistor(OFET)biosensors for customizable detection of biomarkers for many diseases would provide a low-cost and convenient tool for both biological studies and clinical diagnosis.In this work,design principles of the OFET transducer for biosensors were derived to relate the signal-to-noise ratio(SNR)to the device-performance parameters.Steep subthreshold swing(SS),proper threshold voltage(Vth),good-enough bias-stress stability,and mechanical durability are shown to be the key prerequisites for realizing OFET bio-sensors of high transconductance efficiency(gm/ID)for large SNR.Combining a low trap-density channel and a high-k/low-k gate dielectric layer,low-temperature(<100℃)solution-processed flexible OFETs can meet the performance requirements to maximize the gm/ID.An extended gate-structure OFET biosensor was further implemented for label-free detection of miR-21,achieving a detection limit below 10 pM with high selectivity at a low operation voltage(<1 V). | Wei Tang Ying Fu Yukun Huang Yuanzhe Li Yawen Song Xin Xi Yude Yu Yuezeng Su Feng Yan Xiaojun Guo | 2022 | npj Flexible Electronics2022,6,1: | 1 |
| 20 | Freestanding Pt nanosheets with high porosity and improved electrocatalytic performance toward the oxygen reduction reaction显示文摘Because of the intriguing electronic properties, high specific surface areas and confinement effect, two-dimensional(2D) noble metal nanosheets usually exhibit fascinating physicochemical properties and thus hold great promises in fuel cell devices and beyond. Herein, 2D porous Pt nanosheets composed by interweaved ultrathin nanowires are successfully fabricated via a facile NaCl-templated process. Controlled experiments demonstrate that the adoption of NaCl and appropriate ratio of NaCl and Pt precursor are indispensable for the formation of porous Pt nanosheets. Impressively, the cost-effective NaCl template can be recyclable through a simple recrystallization procedure, which may greatly reduce the synthetic cost. By virtue of their structural merits, including high porosity, 2D anisotropy and abundant defects, the resultant porous Pt nanosheets exhibit superior activity and enhanced stability towards the oxygen reduction reaction(ORR) compared to the commercial Pt black in alkaline medium. The present study not only offers a high-performance electrocatalyst for fuel cell devices, but also provides a new perspective toward the rational synthesis of 2D noble metal nanosheets with high porosity and diverse functionalities. | Chuang Fan Zihan Huang Xianyu Hu Zhaoping Shi Tianyang Shen Yawen Tang Xiaojun Wang Lin Xu | 2018 | Green Energy & Environment2018,3,4: | 1 |