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| 1 | Recent Advances and Opportunities of Lead-Free Perovskite Nanocrystal for Optoelectronic Application显示文摘Metal halide perovskite nanocrystals(NCs),as a new class of light-emitting and light-harvesting materials,have recently attracted intensive attention for an impressive variety of optoelectronic applications.However,the lead toxicity and poor stability of such materials severely restrict their practical applications and future commercialization.Lead-free perovskite NCs and their derivatives,designed by the reasonable chemical substitution of Pb with other nontoxic elements,are recently booming as an attractive alternative to lead-based counterparts.In this review,we firstly present a comprehensive overview of currently explored lead-free perovskite NCs with an emphasis on their design routes,morphologies,optoelectronic properties,and environmental stability issues.Then,we discuss the preliminary achievements of lead-free perovskite NCs in versatile optoelectronic applications,such as light-emitting devices,solar cells,photodetectors,and photocatalysis.We finish this review with a critical outlook into the currently existing challenges and possible development opportunities of this rapidly evolving field. | Fei Zhang Zhuangzhuang Ma Zhifeng Shi Xu Chen Di Wu Xinjian Li Chongxin Shan | 2021 | Energy Material Advances2021，，1： | 3 |
| 2 | Stoichiometric effect on electrical and near-infrared photodetection properties of full-composition-range GaAs1−xSbx nanowires显示文摘As one of the most important narrow bandgap ternary semiconductors, GaAs1−xSbx nanowires (NWs) have attracted extensive attention recently, due to the superior hole mobility and the tunable bandgap, which covers the whole near-infrared (NIR) region, for technological applications in next-generation high-performance electronics and NIR photodetection. However, it is still a challenge to the synthesis of high-quality GaAs1−xSbx NWs across the entire range of composition, resulting in the lack of correlation investigation among stoichiometry, microstructure, electronics, and NIR photodetection. Here, we demonstrate the success growth of high-quality GaAs1−xSbx NWs with full composition range by adopting a simple and low-cost surfactant-assisted solid source chemical vapor deposition method. All of the as-prepared NWs are uniform, smooth, and straight, without any phase segregation in all stoichiometric compositions. The lattice constants of each NW composition have been well correlated with the chemical stoichiometry and confirmed by high-resolution transmission electron microscopy, X-ray diffraction, and Raman spectrum. Moreover, with the increase of Sb concentration, the hole mobility of the as-fabricated field-effect-transistors and the responsivity and detectivity of the as-fabricated NIR photodetectors increase accordingly. All the results suggest a careful stoichiometric design is required for achieving optimal NW device performances. | Jiamin Sun Mingming Han Meng Peng Lei Zhang Dong Liu Chengcheng Miao Jiafu Ye Zhiyong Pang Longbing He Hailu Wang Qing Li Peng Wang Lin Wang Xiaoshuang Chen Chongxin Shan Litao Sun Weida Hu Zai-xing Yang | 2021 | Nano Research2021，14，11： | 1 |
| 3 | Near-infrared chemiluminescent carbon nanogels for oncology imaging and therapy显示文摘Carbon nanogels(CNGs)with dual ability of reactive oxygen species(ROS)imaging and photodynamic therapy have been designed with selfassembled chemiluminescent carbonized polymer dots(CPDs).With efficient deep-red/near-infrared chemiluminescence(CL)emission and distinctive photodynamic capacity,the H2O2-driven chemiluminescent CNGs are further designed by assembling the polymeric conjugate and CL donors,enabling an in vitro and in vivo ROS bioimaging capability in animal inflammation models and a high-performance therapy for xenograft tumors.Mechanistically,ROS generated in inflammatory sites or tumor microenvironment can trigger the chemically initiated electron exchange luminescence in the chemical reaction of peroxalate and H2O2,enabling in vivo CL imaging.Meanwhile,part of the excited-state electrons will transfer to the ambient H2O or dissolved oxygen and in turn lead to the type I and type II photochemical ROS production of hydroxyl radicals or singlet oxygen,endowing the apoptosis of tumor cells and thus enabling cancer therapy.These results open up a new avenue for the design of multifunctional nanomaterials for bioimaging and antienoplastic agents. | Chenglong Shen Tianci Jiang Qing Lou Wenbo Zhao Chaofan Lv Guangsong Zheng Hangrui Liu Pengfei Li Lingling Dai Kaikai Liu Jinhao Zang Feng Wang Lin Dong Songnan Qu Zhe Cheng Chongxin Shan | 2022 | SmartMat2022，3，2： | 1 |
| 4 | Ultra-sensitive flexible Ga_(2)O_(3)solar-blind photodetector array realized via ultra-thin absorbing medium显示文摘The quest for solar-blind photodetectors with outstanding optoelectronic properties and weak signals detection capability is essential for their applications in the field of imaging,communication,warning,etc.To date,Ga_(2)O_(3)has demonstrated potential for high-performance solar-blind photodetectors.However,the performance usually decays superlinearly at low light intensities due to carrier-trapping effect,which limits the weak signal detection capability of Ga_(2)O_(3)photodetectors.Herein,a Ga_(2)O_(3)solarblind photodetector with ultra-thin absorbing medium has been designed to restrain trapping of photo-generated carriers during the transporting process by shortening the carrier transport distance.Meanwhile,multiple-beam interference is employed to enhance the absorption efficiency of the Ga_(2)O_(3)layer using an Al/Al_(2)O_(3)/Ga_(2)O_(3)structure.Based on the ultra-thin absorbing medium with enhanced absorption efficiency,a 7×7 flexible photodetector array is developed,and the detectivity can reach 1.7×10^(15)Jones,which is among the best values ever reported for Ga_(2)O_(3)photodetectors.Notably,the performance of the photodetector decays little as the illumination intensity is as weak as 5 nW/cm2,revealing the capacity to detect ultra-weak signals.In addition,the flexible photodetector array can execute the functions of imaging,spatial distribution of light source intensity,real-time light trajectory detection,etc.Our results may provide a route to high-performance solar-blind photodetectors for ultra-weak light detection. | Yancheng Chen Xun Yang Yuan Zhang Xuexia Chen Junlu Sun Zhiyang Xu Kaiyong Li Lin Dong Chongxin Shan | 2022 | Nano Research2022，15，4： | 1 |
| 5 | Next-generation machine vision systems incorporating two-dimensional materials: Progress and perspectives显示文摘Machine vision systems(MVSs)are an important component of intelligent systems,such as autonomous vehicles and robots.However,with the continuous increase in data and new application scenarios,new requirements are put forward for the next generation of MVS.There is an urgent need to find new material systems to complement the existing semiconductor technology based on thin-film materials,and new architectures must be explored to improve efficiency.Because of their unique physical properties,two-dimensional(2D)materials have received extensive attention for use in MVSs,especially in biomimetic ones:the human visual system,which can process complex visual information with low power consumption,provides a model for next-generation MVSs.This review paper summarizes the progress and challenges of applying 2D material photodetectors in sense-memory-computational integration and biomimetic image sensors for machine vision. | Peisong Wu Ting He He Zhu Yang Wang Qing Li Zhen Wang Xiao Fu Fang Wang Peng Wang Chongxin Shan Zhiyong Fan Lei Liao Peng Zhou Weida Hu | 2022 | InfoMat2022，4，1： | 1 |
| 6 | Gold nanoparticles modified ZnO nanorods with improved photocatalytic activity显示文摘 | Lanlan Sun Dongxu Zhao Zhiming Song Chongxin Shan Zhenzhong Zhang Binghui Li Dezhen Shen | 2011 | Journal of Colloid And Interface Science2011，，1： | 1 |
| 7 | Light-modulated vertical heterojunction phototransistors with distinct logical photocurrents显示文摘The intriguing carrier dynamics in graphene heterojunctions have stimulated great interest in modulating the optoelectronic features to realize high-performance photodetectors.However,for most phototransistors,the photoresponse characteristics are modulated with an electrical gate or a static field.In this paper,we demonstrate a graphene/C_(60)/pentacene vertical phototransistor to tune both the photoresponse time and photocurrent based on light modulation.By exploiting the power-dependent multiple states of the photocurrent,remarkable logical photocurrent switching under infrared light modulation occurs in a thick C_(60) layer(11 nm)device,which implies competition of the photogenerated carriers between graphene/C_(60) and C_(60)/pentacene.Meanwhile,we observe a complete positive-negative alternating process under continuous 405 nm irradiation.Furthermore,infrared light modulation of a thin C_(60)(5 nm)device results in a photoresponsivity improvement from 3425 A/W up to 7673 A/W,and we clearly probe the primary reason for the distinct modulation results between the 5 and 11 nm C_(60) devices.In addition,the tuneable bandwidth of the infrared response from 10 to 3×10^(3) Hz under visible light modulation is explored.Such distinct types of optical modulation phenomena and logical photocurrent inversion characteristics pave the way for future tuneable logical photocurrent switching devices and high-performance phototransistors with vertical graphene heterojunction structures. | Jiayue Han Meiyu He Ming Yang Qi Han Fang Wang Fang Zhong Mengjian Xu Qing Li He Zhu Chongxin Shan Weida Hu Xiaoqing Chen Xinran Wang Jun Gou Zhiming Wu Jun Wang | 2020 | Light(Science & Applications)2020，9，1： | 1 |
| 8 | Highly sensitive humidity sensors based on hexagonal boron nitride nanosheets for contactless sensing显示文摘Humidity sensors with high sensitivity,rapid response,and facile fabrication process for contactless sensing applications have received considerable attention in recent years.Herein,humidity sensors based on hexagonal boron nitride(h-BN)nanosheets that are synthesized by a facile ultrasonic process have been fabricated,which display an ultrahigh sensitivity of 28,384%at 85%relative humidity(RH),rapid response/recovery time(3.0/5.5 s),and long-term stability in a wide humidity detection range(11%-85%RH),superior to most of the reported humidity sensors.The high sensitivity can be ascribed to the massive hydrophilic functional groups absorbed on the h-BN nanosheet surface.Benefiting from the high humidity sensing performances,contactless Morse code messaging and human writing and speech recognition have been demonstrated.This work demonstrates the great potential of the high-performance h-BN nanosheet-based humidity sensors for future contactless sensing devices. | Hang Liu Jinxu Qin Xigui Yang Chaofan Lv Wentao Huang Fukui Li Chuang Zhang Yanran Wu Lin Dong Chongxin Shan | 2023 | Nano Research2023，16，7： | 0 |
| 9 | Robust frequency-upconversion lasing operated at 400 K from inorganic perovskites microcavity显示文摘Multi-photon-pumped lasing based on metal-halide perovskites is promising for nonlinear optics and practical frequency-upconversion devices in integrated photonic systems.However,at present almost all the multi-photon-pumped lasing emissions from perovskite microcavities were limited for two-photon excitation,and also suffered from a compromise in room temperature or low temperature operation conditions.In this study,based on the vapor-phase epitaxial CsPbBr3 microplatelets with high crystallinity,self-formed high-quality microcavities,and great thermal stability,low-threshold and high-quality factor whispering gallery mode lasing was realized under single-,two-,and three-photon excitation,and the lasing action is very stable under continuous pulsed laser irradiation(~3.6×10^(7) laser shots).More importantly,the three-photon-pumped lasing can be efficiently sustained at a high temperature of~400 K,and the characteristic temperature was determined to be as high as~152.6 K,indicating the highly temperature-insensitive gain threshold.Note that this is the first report on high-temperature three-photon-pumped lasing on perovskite microcavities.Moreover,an aggressive thermal cycling test(two cycles,290-400-290 K)was further performed to indicate the stability and repeatability of the multi-photon-pumped lasing characteristics.It can be anticipated that the results obtained represent a significant step toward the temperature-insensitive frequency-upconversion lasing,inspiring the exploitation of advantageous perovskites for novel applications. | Zhifeng Shi Fei Zhang Jingjing Yan Yuan Zhang Xu Chen Shu Chen Di Wu Xinjian Li Yu Zhang Chongxin Shan | 2022 | Nano Research2022，15，1： | 0 |
| 10 | Ga2O3 solar-blind position-sensitive detectors显示文摘Monoclinic Ga2O3(β-Ga2O3)is a promising material for achieving solar-blind photodetection because of its unique characteristics,including its high breakdown electric field,radiation hardness,thermal and chemical stabilities,and intrinsic visible/solar-blind properties.Until now,several studies have investigated the development of high-performanceβ-Ga2O3 solar-blind photodetectors.However,these photodetectors can only detect the light intensity but not the light position.In this work,fourquadrant position-sensitive detectors(4Q-PSDs)were developed and demonstrated based onβ-Ga2O3.4Q-PSDs,comprising four identical metal-semiconductor-metal-structured photodetector components,demonstrate high uniformity,large signal-tonoise ratio,good ultraviolet/visible rejection ratio,and fast response/recovery time.Subsequently,the position of the illumination beam can be determined by analyzing the output signals of the four photodetector components.This work may indicate the promising application potential of the Ga2O3-based photodetectors in the fields of positioning,aligning,and monitoring the solarblind beams. | Kaiyong Li Xun Yang Yongzhi Tian Yancheng Chen Chaonan Lin Zhenfeng Zhang Zhiyang Xu Jinhao Zang Chongxin Shan | 2020 | Science China(Physics,Mechanics & Astronomy)2020，63，11： | 0 |
| 11 | Negative differential friction coefficients of two-dimensional commensurate contacts dominated by electronic phase transition显示文摘Friction force(f)usually increases with the normal load(N)macroscopically,according to the classic law of Da Vinci–Amontons(f=μN),with a positive and finite friction coefficient(μ).Herein near-zero and negative differential friction(ZNDF)coefficients are discovered in two-dimensional(2D)van der Waals(vdW)magnetic CrI_(3)commensurate contacts.It is identified that the ferromagnetic–antiferromagnetic phase transition of the interlayer couplings of the bilayer CrI_(3)can significantly reduce the interfacial sliding energy barriers and thus contribute to ZNDF.Moreover,phase transition between the in-plane(p_(x)and p_(y))and out-of-plane(p_(z))wave-functions dominates the sliding barrier evolutions,which is attributed to the delicate interplays among the interlayer vdW,electrostatic interactions,and the intralayer deformation of the CrI_(3)layers under external load.The present findings may motivate a new concept of slide-spintronics and are expected to play an instrumental role in design of novel magnetic solid lubricants applied in various spintronic nano-devices. | Kun Liu Jiangtao Cheng Xingju Zhao Yandi Zhu Xiaoyan Ren Jinlei Shi Zhengxiao Guo Chongxin Shan Hongjie Liu Shunfang Li | 2022 | Nano Research2022，15，6： | 0 |
| 12 | Revealing the atomic mechanism of diamond–iron interfacial reaction显示文摘Diamond,with ultrahigh hardness,high wear resistance,high thermal conductivity,and so forth,has attracted worldwide attention.However,researchers found emergent reactions at the interfaces between diamond and ferrous materials,which significantly affects the performance of diamond-based devices.Herein,combing experiments and theoretical calculations,taking diamond–iron(Fe)interface as a prototype,the counter-diffusion mechanism of Fe/carbon atoms has been established.Surprisingly,it is identified that Fe and diamond first form a coherent interface,and then Fe atoms diffuse into diamond and prefer the carbon vacancies sites.Meanwhile,the relaxed carbon atoms diffuse into the Fe lattice,forming Fe_(3)C.Moreover,graphite is observed at the Fe_(3)C surface when Fe_(3)C is over-saturated by carbon atoms.The present findings are expected to offer new insights into the atomic mechanism for diamondferrous material's interfacial reactions,benefiting diamond-based device applications. | Yalun Ku Kun Xu Longbin Yan Kuikui Zhang Dongsheng Song Xing Li Shunfang Li Shaobo Cheng Chongxin Shan | 2024 | Carbon Energy2024，6，3： | 0 |
| 13 | Multicolor biomass based carbon nanodots for bacterial imaging显示文摘Biomass-based carbon nanodots(CNDs) are becoming promising fluorescent materials due to their superior optical properties and excellent biocompatibility. However, most fluorescent CNDs are prepared under high temperatures with artificial chemicals as precursors. In this work, multicolor biomass-based CNDs have been prepared by employing natural biomass as precursors through an ultrasonic-assisted method at room temperature. The multicolor biomass-based CNDs can be prepared within 10 min, and cavitation produced by ultrasound in solution contributes to the polymerization of biomolecules into nanodots. The emission of the CNDs covers from blue to red region, with emission peaks centered at 410 nm, 520 nm and 670 nm, and the corresponding photoluminescence quantum yields of the CNDs are 11%, 12% and28%, respectively. Furthermore, bacterial imaging by using the biomass-based CNDs as fluorescent imaging agent has been demonstrated. This work provides a convenient ultrasonic-assisted way for fabrication multicolor and eco-friendly biomass CNDs, demonstrating their application in bacterial imaging. | Wenbo Zhao Yong Wang Kaikai Liu Rui Zhou Chongxin Shan | 2022 | Chinese Chemical Letters2022，33，2： | 0 |
| 14 | A superradiant maser with nitrogen-vacancy center spins显示文摘Recent experiments have demonstrated Rabi-oscillations, superradiant pulses and stimulated emission from negatively-charged nitrogen-vacancy(NV;) center spins in microwave resonators. These phenomena witness the kind of collective and strong coupling which has been the prerequisite for observation of superradiant lasing in the optical frequency regime. In this article, we investigate the possibility to employ coherence, present in both the collective NV-spin ensemble and the microwave field, to achieve a superradiant maser. Our calculations show that a superradiant maser with a linewidth below millihertz can be achieved with moderate kilohertz incoherent pumping of over 10;spins at room temperature. We show that the superradiant masing prevails in the presence of inhomogeneous broadening, and we present numerical and analytical studies of the dependence of the phenomenon on the various physical parameters. | Qilong Wu Yuan Zhang Xigui Yang Shi-Lei Su Chongxin Shan Klaus Mølmer | 2022 | Science China(Physics,Mechanics & Astronomy)2022，65，1： | 0 |
| 15 | Lanthanide-based ratiometric luminescence nanothermometry显示文摘Luminescent nanothermometry can precisely and remotely measure the internal temperature of objects at nanoscale precision,which,therefore,has been placed at the forefront of scientific attention.In particular,due to the high photochemical stability,low toxicity,rich working mechanisms,and superior thermometric performance,lanthanide-based ratiometric luminesencent thermometers are finding prevalent uses in integrated electronics and optoelectronics,property analysis of in-situ tracking,biomedical diagnosis and therapy,and wearable e-health monitoring.Despite recent progresses,it remains debate in terms of the underlying temperature-sensing mechanisms,the quantitative characterization of performance,and the reliability of temperature readouts.In this review,we show the origin of thermal response luminescence,rationalize the ratiometric scheme or thermometric mechanisms,delve into the problems in the characterization of thermometric performance,discuss the universal rules for the quantitative comparison,and showcase the cutting-edge design and emerging applications of lanthanide-based ratiometric thermometers.Finally,we cast a look at the challenges and emerging opportunities for further advances in this field. | Mochen Jia Xu Chen Ranran Sun Di Wu Xinjian Li Zhifeng Shi Guanying Chen Chongxin Shan | 2023 | Nano Research2023，16，2： | 0 |
| 16 | Revealing the dynamics of the alloying and segregation of Pt-Co nanoparticles via in-situ environmental transmission electron microscopy显示文摘Thermal treatment is a general and efficient way to synthesize intermetallic catalysts and may involve complicated physical processes.So far,the mechanisms leading to the size and composition heterogeneity,as well as the phase segregation behavior in Pt-Co nanoparticles(NPs)are still not well understood.Via in-situ environmental transmission electron microscopy,the formation dynamics and segregation behaviors of Pt-Co alloyed NPs during the thermal treatment were investigated.It is found that Pt-Co NPs on zeolitic imidazolate frameworks-67-derived nanocarbon(NC)are formed consecutively through both particle migration coalescence and the Ostwald ripening process.The existence of Pt NPs is found to affect the movement of Co NPs during their migration.With the help of theoretical calculations,the correlations between the composition and migration of the Pt and Co during the ripening process were uncovered.These complex alloying processes are revealed as key factors leading to the heterogeneity of the synthesized Pt-Co alloyed NPs.Under oxidation environment,the Pt-Co NPs become surface faceted gradually,which can be attributed to the oxygen facilitated relatively higher segregation rate of Co from the(111)surface.This work advances the fundamental understanding of design,synthesis,and durability of the Pt-based nanocatalysts. | Xing Li Shaobo Cheng Yanghua He Lixiang Qian Dmitri Zakharov Gang Wu Chongxin Shan Liang Zhang Dong Su | 2023 | Nano Research2023，16，2： | 0 |
| 17 | Nonequilibrium hot-electron-induced wavelength-tunable incandescent-type light sources显示文摘The collective oscillation of electrons located in the conduction band of metal nanostructures being still energized,with the energy up to the bulk plasmon frequency,are called nonequilibrium hot electrons.It can lead to the state-filling effect in the energy band of the neighboring semiconductor.Here,we report on the incandescent-type light source composed of Au nano rods decorated with single Ga-doped ZnO microwire(AuNRs@ZnO:Ga MW).Benefiting from Au nanorods with controlled aspect ratio,wavelength-tunable incandescent-type lighting was achieved,with the dominating emission peaks tuning from visible to near-infrared spectral regions.The intrinsic mechanism was found that tunable nonequilibrium distribution of hot electrons in ZnO:Ga MW,injected from Au nanorods,can be responsible for the tuning emission features.Apart from the modification over the composition,bandgap engineering,doping level,etc.,the realization of electrically driving the generation and injection of nonequilibrium hot electrons from single ZnO:Ga MW with Au nanostructure coating may provide a promising platform to construct electronics and optoelectronics devices,such as electric spasers and hot-carrier-induced tunneling diodes. | ZHIPENG SUN MINGMING JIANG WANGQI MAO CAIXIA KAN CHONGXIN SHAN DEZHEN SHEN | 2020 | Photonics Research2020，8，1： | 0 |
| 18 | In Situ Electrochemical Transmission Electron Microscopy for Sodium-Ion Batteries显示文摘Sodium-ion batteries(SIBs)possess promising application prospects for large-scale energy storage systems due to the abundance of sodium ions as a resource and their low cost.Development of advanced SIBs requires a clear understanding of the structures and kinetic/dynamic processes occurring in the cells during the charging/discharging process.In situ transmission electron microscopy(TEM)is a powerful tool for direct visualization of the phase transitions as well as morphological and structural evolutions of the electrodes during the electrochemical reaction process.Herein,we summarize the state-of-the-art in situ TEM studies on SIBs with a specific focus on real-time observations of the electrochemical behavior of battery materials.This review emphasizes the necessity of in situ TEM to elucidate fundamental issues regarding the reaction mechanism,phase transformation,structural evolution,and performance degradation of SIBs.Finally,critical challenges and emerging opportunities for in situ TEM research about SIBs are discussed. | Shuge Dai Jingwen Zhang Jiaqi Qu Xing Li Shaobo Cheng Chongxin Shan | 2023 | Renewables2023，1，1： | 0 |
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