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| 1 | Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting显示文摘 | Wenfu Xie Zhenhua Li Mingfei Shao Min Wei | 2018 | Frontiers of Chemical Science and Engineering2018，12，3： | 9 |
| 2 | Advances in efficient electrocatalysts based on layered double hydroxides and their derivatives显示文摘The explore and development of electrocatalysts have gained significant attention due to their indispensable status in energy storage and conversion systems, such as fuel cells, metal–air batteries and solar water splitting cells. Layered double hydroxides(LDHs) and their derivatives(e.g., transition metal alloys, oxides, sulfides, nitrides and phosphides) have been adopted as catalysts for various electrochemical reactions, such as oxygen reduction, oxygen evolution, hydrogen evolution, and CO_2 reduction, which show excellent activity and remarkable durability in electrocatalytic process. In this review, the synthesis strategies, structural characters and electrochemical performances for the LDHs and their derivatives are described. In addition, we also discussed the effect of electronic and geometry structures to their electrocatalytic activity. The further development of high-performance electrocatalysts based on LDHs and their derivatives is covered by both a short summary and future outlook from the viewpoint of the material design and practical application. | Lei Zhou Mingfei Shao Min Wei Xue Duan | 2017 | Journal of Energy Chemistry2017，26，6： | 9 |
| 3 | One-step synthesis of Fe-Ni hydroxide nanosheets derived from bimetallic foam for efficient electrocatalytic oxygen evolution and overall water splitting显示文摘The research of superior water oxidation electrodes is essential for the green energy in the form of hydrogen by way of electrolytic water splitting, and still remains challenging. Based upon dealloying foam, Fe-Ni hydroxide nanosheets network structure is designed on the surface of Fe-Ni alloy foam. The ratio of Ni/Fe elements was adjusted to realize the optimal catalytic activities for oxygen evolution reaction(OER) and hydrogen evolution reaction(HER). The obtained electrode of Fe-Ni hydroxide nanosheets/Fe-Ni alloy foam-60% Fe(FN LDH/FNF-60, 60 is the percentage of Fe content) possess low overpotential of 261 mV to reach 10 mA/cm^2, small Tafel slope(85.5 mV/dec), and superior long-term stability(remaining 10 mA/cm^2 for over 14 h without attenuation) toward OER in 1.0 mol/L KOH.Moreover, an alkaline water electrolyzer is constructed with the FN LDH/FNF-60 as anode and Ni(OH)_2/Fe-Ni alloy foam-25% Fe(Ni(OH)_2/FNF-25) as cathode, which displays superior electrolytic performance(affording 10 mA/cm^2 at 1.62 V) and lasting durability. | Lili Zeng Linjing Yang Jia Lu Jin Jia Jiayuan Yu Yunqie Deng Mingfei Shao Weijia Zhou | 2018 | Chinese Chemical Letters2018，29，12： | 7 |
| 4 | Hierarchical Carbon Microtube@Nanotube Core-Shell Structure for High-Performance Oxygen Electrocatalysis and Zn-Air Battery显示文摘Zinc-air batteries(ZABs)hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness.However,the performance of practical ZABs is still unsatisfactory because of the inevitably decreased activity of electrocatalysts when assembly into a thick electrode with high mass loading.Herein,we report a hierarchical electrocatalyst based on carbon microtube@nanotube core-shell nanostructure(CMT@CNT),which demonstrates superior electrocatalytic activity for oxygen reduction reaction and oxygen evolution reaction with a small potential gap of 0.678 V.Remarkably,when being employed as air-cathode in ZAB,the CMT@CNT presents an excellent performance with a high power density(160.6 mW cm^−2),specific capacity(781.7 mAhgZn^−1)as well as long cycle stability(117 h,351 cycles).Moreover,the ZAB performance of CMT@CNT is maintained well even under high mass loading(3 mg cm−2,three times as much as traditional usage),which could afford high power density and energy density for advanced electronic equipment.We believe that this work is promising for the rational design of hierarchical structured electrocatalysts for advanced metal-air batteries. | Wenfu Xie Jianming Li Yuke Song Shijin Li Jianbo Li Mingfei Shao | 2020 | Nano-Micro Letters2020，12，8： | 3 |
| 5 | 2020 Roadmap on two-dimensional nanomaterials for environmental catalysis显示文摘Environmental catalysis has drawn a great deal ofattention due to its clean ways to produce useful chemicals or carry out some chemical processes.Photocatalysis and electrocatalysis play important roles in these fields.They can decompose and remove organic pollutants from the aqueous environment,and prepare some fine chemicals.Moreover,they also can carry out some important reactions,such as 02 reduction reaction(ORR),O2 evolution reaction(OER),H2 evolution reaction(HER),CO2 reduction reaction(C02 RR),and N2 fixation(NRR).For catalytic reactions,it is the key to develop high-performance catalysts to meet the demand fortargeted reactions.In recentyears,two-dimensional(2 D) materials have attracted great interest in environmental catalysis due to their unique layered structures,which offer us to make use of their electronic and structural characteristics.Great progress has been made so far,including graphene,black phosphorus,oxides,layered double hydroxides(LDHs),chalcogenides,bismuth-based layered compounds,MXenes,metal organic frameworks(MOFs),covalent organic frameworks(COFs),and others.This content drives us to invite many famous groups in these fields to write the roadmap on two-dimensional nanomaterials for environmental catalysis.We hope that this roadmap can give the useful guidance to researchers in future researches,and provide the research directions. | Yulu Yang Mingguang Wu Xingwang Zhu Hui Xu Si Ma Yongfeng Zhi Hong Xia Xiaoming Liu Jun Pan Jie-Yinn Tang Siang-Piao Chai Leonardo Palmisano Francesco Parrino Junli Liu Jianzhong Ma Ze-Lin Wang Ling Tan Yu-Fei Zhao Yu-Fei Song Pardeep Singh Pankaj Raizada Deli Jiang Di Li R.A.Geioushy Jizhen Ma Jintao Zhang Song Hu Rongjuan Feng Gang Liu Minghua Liu Zhenhua Li Mingfei Shao Neng Li Jiahe Peng Wee-Jun Ong Nikolay Kornienko Zhenyu Xing Xiujun Fan Jianmin Ma | 2019 | Chinese Chemical Letters2019，30，12： | 2 |
| 6 | Active facet determination of layered double hydroxide for oxygen evolution reaction显示文摘Oxygen evolution reaction(OER) plays an indispensable role in developing renewable clean energy resources. One of the critical bottlenecks for the reaction is the development of highly efficient electrocatalyst to decrease the high overpotentials of four-electron transfer process of OER. Recently, layered double hydroxides(LDHs) have been widely investigated among the most promising electrocatalysts for OER due to their high intrinsic activity, excellent stability as well as low-cost. However, it remains unclear how the exposed facet of the LDHs affects their electrocatalytic activity. Here we elucidate the active edge facet of LDHs towards OER by combining the finely control of edge facet ratio coupled with molecular probe method and computational calculation. The LDHs with higher edge facet area ratio show superior activity with low onset potential as well as decreased Tafel slope. The active edge site is further proved by blocking the unsaturated edge sites with cyanate probe anion, of which the adsorption largely inhibits OER activity. Furthermore, based on density functional theory(DFT) calculation, twodimensional map of theoretical overpotentials as a function of Gibbs free energy reveals that the edge(100) facet exhibits a much higher OER activity than basal plane(001) facet. | Yunqi Zhang Wenfu Xie Jialing Ma Lifang Chen Chunyuan Chen Xin Zhang Mingfei Shao | 2021 | Journal of Energy Chemistry2021，30，9： | 2 |
| 7 | Electrosynthesis of hierarchical NiLa-layered double hydroxide electrode for efficient oxygen evolution reaction显示文摘Oxygen evolution reaction(OER) is a key process for electrochemical water splitting due to its intrinsic large overpotential. Recently, layered double hydroxides(LDHs), especially Ni Fe-LDH, have been regarded as highly performed electrocatalysts for OER in alkaline condition. Here we first present a new class of Ni La-LDH electrocatalyst synthesized by an electrochemical process for efficient water splitting. The as-prepared NiL a-LDH nanosheet arrays(NSAs) give remarkable electrochemical activity and durability under alkaline environments, with a low overpotential of 209 mV for OER to deliver a current density of 10 mA cm^-2, surpassing most of previous reported LDHs eletrocatalysts. The presence of NiLa-LDH in this work extends the studies about LDHs-based electrocatalysts, which will benefit the development of electrochemical energy storage and conversion systems. | Shan Jiang Yunke Liu Wenfu Xie Mingfei Shao | 2019 | Journal of Energy Chemistry2019，28，6： | 1 |
| 8 | Autotrophic denitrification and its effect on metal speeiation during marine sediment remediation 显示文摘 | Shao Mingfei Zhang Tong Herbert H | 2009 | Water Research2009，43，12： | 1 |
| 9 | Preparation of Fe)4@ SiO2 @ layered double hydroxide core-shell mi- crospheres for magnetic separation of proteins 显示文摘 | Shao Mingfei Ning Fanyu Zhao Jingwen | 2012 | J Am Chem Soc2012，134，2： | 1 |
| 10 | 454 Pyrose-quencing reveals bacterial diversity of activated sludge from 14 sewage treatment plants显示文摘 | ZHANG Tong SHAO Mingfei YE Lin | 2012 | ISME J2012，6，6： | 1 |
| 11 | The synthesis of hierarchical Zn-Ti layered double hydroxide for efficient visible-light photocatalysi s显示文摘 | SHAO Mingfei HAN Jingbin WEI Min | 2011 | Chemical Engineering Journal2011，168，2： | 1 |
| 12 | Autotrophic denitrification and its effect on metal speciation during marine sediment remediation显示文摘 | Mingfei Shao Tong Zhang Herbert H.P. Fang | 2009 | Water Research2009，，12： | 1 |
| 13 | 454 Pyrosequeneing reveals bacterial diversity of aetivated sludge from 14 sewage treatment plants 显示文摘 | Zhang Tong Shao Mingfei Ye Lin | 2012 | Isme Journal2012，6，6： | 1 |
| 14 | Preparation of Fe304@SiO2@Layered double hydroxide core-shell microspheres for magnetic separation of proteins显示文摘 | SHAO Mingfei NING Fanyu ZHAO Jingwen | 2012 | J Am Chem Soc2012，134，10： | 1 |
| 15 | A comparative study of the bacterial community in denitrifying and traditional enhanced biological phosphorus removal processes显示文摘 | Lü Xiaomei Shao Mingfei Li Chaolin | 2014 | Microbes and Environments2014，29，3： | 1 |
| 16 | The synthesis of hierarchical Zn-Ti layered double hydroxide for efficient visible-light photocatalysis显示文摘 | Shao Mingfei Han Jingbin Wei Min | 2011 | Chemical Engineering Journal2011，，168： | 1 |
| 17 | The synthesis of hierarchical Zn-Ti layered double hydroxide for efficient visible-light photocatalysis显示文摘 | Shao Mingfei Han Jingbin Wei Min | 2011 | Chem Eng J2011，168，2： | 1 |
| 18 | Single-atom Catalysts Based on Layered Double Hydroxides显示文摘Single-atom catalysts(SACs)have attracted much attention for their superior catalytic performance in various fields.It has been widely accepted that the selection of appropriate substrates is crucial to the fabrication and application of SACs.Layered double hydroxides(LDHs)have been developed as one of the promising substrates for single-atoms due to their unique adjustable supramolecular structures.In this review,we comprehensively sort out the research of SACs based on LDHs.By analyzing the characteristics of LDHs and the single-atoms,respectively,the preparation strategies of SACs by using LDHs are summarized.Their applications as efficient catalysts in electrocatalysis,photocatalysis and thermal catalysis are then discussed.Finally,we summarize the opportunities and challenges for the rational design and application expansion of SACs based on LDHs in the future. | FAN Kui SUN Yining XU Pengcheng GUO Jian LI Zhenhua SHAO Mingfei | 2022 | Chemical Research in Chinese Universities2022，38，5： | 0 |
| 19 | Co-thermal in-situ reduction of inorganic carbonates to reduce carbon-dioxide emission显示文摘Thermal decomposition of inorganic metal carbonates is the main path to prepare metal oxides;nonetheless,it is always accompanied by the emission of large amounts of CO_(2) as one of the gas products.This study reports a concept of co-thermal insitu reduction of inorganic carbonates by using the energy released by carbonate decomposition under pure hydrogen atmosphere,which reduces the decarboxylation temperature and significantly inhibits the CO_(2) emissions.A combination of hydrogen–deuterium exchange,isotope experiment,and density functional theory calculations demonstrates that the CO results from the selective cleavage of Ca–O bonds at the surface of CaCO_(3) via the direct hydrogenation mechanism at relatively low temperature.However,it undergoes the reverse water–gas shift reaction path at high temperature,i.e.,CO being produced by the reduction of CO_(2) released by the decomposition of carbonates.This study sheds light on the potential of green hydrogen technology for inorganic carbonate valorization toward high value-added products,which can facilitate the large-scale industrial applications. | Zhen Xue Jingyi Guo Shasha Wu Wenfu Xie Yujing Fu Xiaojie Zhao Kui Fan Ming Xu Hong Yan Mingfei Shao Xue Duan | 2023 | Science China Chemistry2023，66，4： | 0 |
| 20 | Hierarchical CoNi-LDH nanosheet array with hydrogen vacancy for high-performance aqueous battery cathode显示文摘Aqueous rechargeable multiple metal-ion storage battery (ARSB) has a large potential in energy storage devices due to their safe usage, low cost and high rate capability. Nevertheless, the performance of practical ARSB is largely restricted by low capacity and limited cathode materials. Herein, we demonstrate an efficient cathode material based on Co Ni-layered double hydroxide (LDH) nanosheets arrays with abundant hydrogen vacancy induced by electrochemical activation process for high performance of cations storage. Consequently, the electrochemical activated Co Ni-LDH (ECA-Co Ni-LDH) nanosheets arrays exhibit high metal ion (Li^(+), Na^(+), Zn^(2+), Mg^(2+) and Ca^(2+)) storage capacities, which is 9 times and 3 times higher that of unactivated Co Ni-LDH arrays and ECA-Co Ni-LDH without hierarchical structure, respectively.Moreover, the ECA-Co Fe-LDH also shows the possibility for practical applications in actual batteries.By coupling with a Fe_(2)O_(3)/C anode, the assembled aqueous battery delivered a large energy density of 184.4 Wh kg^(-1)at power density of 4 Wh kg^(-1) in high voltage range of 0–2 V. To our best knowledge, such high energy density and large working window of our assembled aqueous battery is exceeded other LDH-based aqueous battery or supercapacitor, and the energy density almost comparable than that of commercial Li-ion batteries. Moreover, almost no measurable capacitance losses can be detected even after 10000 cycles. In addition, this work also provides a strategy to develop a high energy density cathode for multiple metal-ion storage batteries. | Wang Qiao Bowen Jin Wenfu Xie Mingfei Shao Min Wei | 2022 | Journal of Energy Chemistry2022，31，6： | 0 |
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