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| 1 | The Genome of Medicinal Plant Macleaya cordata Provides New Insights into Benzylisoquinoline Alkaloids Metabolism显示文摘在动物农业和药的抗菌素的 overuse 引起了一系列潜在的威胁到公共健康。Macleaya cordata 是从 Papaveraceae 家庭的药用的植物种,提供为抗菌剂的制造的一个安全资源为家畜喂添加剂。从 M. 的活跃成分 ? cordata 被知道包括 benzylisoquinoline 碱(偏爱) 象 sanguinarine (圣) 和 chelerythrine (CHE ) 那样的 ?,而是他们的新陈代谢的小径还得在这非模型植物被学习。在 M. 的圣和 CHE 的活跃生合成 ? cordata 被喂 13标记 C 的酷氨酸。为了增加,推进卓见,我们 de novo 定序 M 的整个染色体。cordata,第一从 Papaveraceae 家庭被定序。M.? 盖住 378 Mb 的 cordata 染色体与 43.5%being 编码 22,328 预言的编码蛋白质的基因 transposable 元素。作为基础 eudicot 的一个成员, M.? cordata 染色体缺乏 ? 发生在几乎所有 eudicots 的 paleohexaploidy 事件。从 genomics 数据, 16 的一个完全的集合 ? 新陈代谢 ? 为圣和 CHE 生合成的基因被检索,并且 14 项他们的生物化学的活动被验证。这些 genomics 和新陈代谢的数据在 M. 显示出保存 BIA 新陈代谢的小径 ? cordata 并且由庄稼改进或微生物引起的小径重建为圣和 CHE 的未来生产提供知识基础。 | Xiubin Liu Yisong Liu Peng Huang Yongshuo Ma Zhixing Qing Qi Tang Huifen Cao Pi Cheng Yajie Zheng Zejun Yuan Yuan Zhou Jinfeng Liu Zhaoshan Tang Yixiu Zhuo Yancong Zhang Linlan Yu Jialu Huang Peng Yang Qiong Peng dinbo Zhang Wenkai Jiang Zhonghua Zhang Kui Lin Dae-Kyun Ro Xiaoya Chen Xingyao Xiong Yi Shang Sanwen Huang Jianguo Zeng | 2017 | Molecular Plant2017,10,7: | 19 |
| 2 | Growth mechanism of palladium clusters on rutile TiO_2 (110) surface显示文摘Oxide-supported transition metal systems have been the subject of enormous interest due to the improvement of catalytic properties relative to the separate metal.Thus in this paper,we embark on a systematic study for Pd n (n=1-5) clusters adsorbed on TiO2 (110) surface based on DFT-GGA calculations utilizing periodic supercell models.A single Pd adatom on the defect-free surface prefers to adsorb at a hollow site bridging a protruded oxygen and a five-fold titanium atom along the [110] direction,while Pd dimer is located on the channels with the Pd-Pd bond parallel to the surface.According to the transition states (TSs) search,the adsorbed Pd trimer tends to triangular growth mode,rather than linear mode,while the Pd4 and Pd5 clusters prefer three-dimensional (3D) models.However,the oxygen vacancy has almost no influence on the promotion of Pd n cluster nucleation.Additionally,of particular significance is that the Pd-TiO2 interaction is the main driving force at the beginning of Pd nucleation,whereas the Pd-Pd interaction gets down to control the growth process of Pd cluster as the cluster gets larger.It is hoped that our theoretical study would shed light on further designing high-performance TiO2 supported Pd-based catalysts. | Weina Zhao Huaxiang Lin Yi Li Yongfan Zhang Xin Huang Wenkai Chen | 2012 | Journal of Natural Gas Chemistry2012,21,5: | 3 |
| 3 | Large Room-Temperature Magnetoresistance in van der Waals Ferromagnet/Semiconductor Junctions显示文摘A magnetic tunnel junction(MTJ)is the core component in memory technologies,such as the magnetic random-access memory,magnetic sensors and programmable logic devices.In particular,MTJs based on twodimensional van der Waals(vd W)heterostructures offer unprecedented opportunities for low power consumption and miniaturization of spintronic devices.However,their operation at room temperature remains a challenge.Here,we report a large tunnel magnetoresistance(TMR)of up to 85%at room temperature(T=300 K)in vdW MTJs based on a thin(<10 nm)semiconductor spacer WSe_(2)layer embedded between two Fe_(3)GaTe_(2e)lectrodes with intrinsic above-room-temperature ferromagnetism.The TMR in the MTJ increases with decreasing temperature up to 164%at T=10 K.The demonstration of TMR in ultra-thin MTJs at room temperature opens a realistic and promising route for next-generation spintronic applications beyond the current state of the art. | Wenkai Zhu Shihong Xie Hailong Lin Gaojie Zhang Hao Wu Tiangui Hu Ziao Wang Xiaomin Zhang Jiahan Xu Yujing Wang Yuanhui Zheng Faguang Yan Jing Zhang Lixia Zhao Amalia Patanè Jia Zhang Haixin Chang Kaiyou Wang | 2022 | Chinese Physics Letters2022,39,12: | 2 |
| 4 | 8.0% Efficient all-polymer solar cells based on novel starburst polymer acceptors显示文摘The polymer N2200, with its π-conjugated backbone composed of alternating naphthalene diimide(NDI) and bithiophene(DT)units, has been widely used as an acceptor for all-polymer solar cells(all-PSCs) owing to its high electron mobility and suitable ionization potential and electron affinity. Here, we developed two naphthalene diimide derivatives by modifying the molecular geometry of N2200 through the incorporation of a truxene unit as the core and NDI-DTas the branches. These starburst polymers exhibited absorption spectra and molecular orbital energy levels that were comparable to N2200. These copolymers were paired with the wide-bandgap polymer donor PTz BI-O to fabricate all-polymer solar cells(all-PSCs), which displayed impressive power conversion efficiencies up to 8.00%. The improved photovoltaic performances of all-PSCs based on these newly developed starburst acceptors can be ascribed to the combination of increased charge carrier mobilities, reduced bimolecular recombination, and formation of more favorable film morphology. These findings demonstrate that the construction of starburst polymer acceptors is a feasible strategy for the fabrication of high-performance all-PSCs. | Kang Li Ruihao Xie Wenkai Zhong Kaiwen Lin Lei Ying Fei Huang Yong Cao | 2018 | Science China Chemistry2018,61,5: | 2 |
| 5 | Mapping of genome-wide resistance gene analogs (RGAs) in maize (Zea mays L.)显示文摘 | Wenkai Xiao Jing Zhao Shengci Fan Lin Li Jinrui Dai Mingliang Xu | 2007 | Theoretical and Applied Genetics2007,,4: | 1 |
| 6 | An in vitro synergetic evaluation of the use of nisin and sodium fluoride or chlorhexidine against Streptococcus mutans显示文摘 | Zhong C T Lin Z Wenkai J | 2011 | Peptides2011,,32: | 1 |
| 7 | Particle-in-cell simulation of the focusing properties of high power electron beam in plasma ion channel显示文摘 | Meng Lin Xie Wenkai Liu Shenggang | 1999 | Int J of IR/MM Waves1999,20,8: | 1 |
| 8 | Research on etch rate of reactive ion etching of GaAs,AlAs and DBR显示文摘 | Lin Shiming Wu Shu | 2001 | Chinese Journal of Semiconductors2001,22,9: | 1 |
| 9 | Large-scale controllable fabrication of aluminum nanobowls for surface plasmon-enhanced fluorescence显示文摘Al nanoparticles(NPs)exhibit excellent localized surface plasmon resonance(LSPR)properties and have been considered a promising alternative to plasmonic Au or Ag NPs.However,it remains difficult to fabricate Al NPs with uniform size and controllable morphology over a large area on substrates,which seriously hinders the in-depth exploration of their properties and applications.Herein,we have developed a self-assembly nanoparticle template method to realize the controllable preparation of bowl-shaped Al NPs(Al nanobowls(Al NBs))with tunable sizes from 36 to 131 nm on the substrate surface,accompanied by tunable LSPR spectral responses from 272 to 480 nm.Among them,131 nm Al NBs exhibit superior fluorescence enhancement ability(1932.2-fold)and a low detection limit(78.6 pM)towards 5-carboxyfluorescein,exceeding comparable Ag NBs and Au nanospheres(NSs).This can be attributed to the strong electromagnetic enhancement induced by the LSPR effect and the effective inhibition of fluorescence quenching caused by the self-passivated oxide layer.Therefore,the successful fabrication of Al NBs on substrates is of vital significance for their promising applications,including surface-enhanced spectroscopy,sensitive fluorescence detection,light-harvesting devices,biosensing,and ultraviolet(UV)plasmonics. | Yawen Wang Heng Gao Yuanlan Liu Dong Li Bo Zhao Wenkai Liang Yinghui Sun Lin Jiang | 2023 | Nano Research2023,16,7: | 0 |
| 10 | Highly efficient solution-processed organic photovoltaics enabled by improving packing behavior of organic semiconductors显示文摘Solution processability is a unique property of organic semiconductors. The compact and regular π-π stacking between molecules is paramount in the performance of organic optoelectronic devices. However, it is still a challenge to improve their stacking quality without sacrificing the solution-processability from the aspect of materials design. Here, delicately engineered additives are presented to promote the formation of ordered aggregation of conjugated molecules by regulating their nucleation and growth dynamics. Intriguingly, the long-chain BTP-eC9-4F molecules can realize ordered aggregation comparable to short-chain ones without sacrificing processability. The domain size of BTP-eC9-4F aggregation is enlarged from 24.2 to 32.2 nm in blend films.Thereby exciton diffusion and charge transport become faster, contributing to the suppression of recombination losses. As a result, a power conversion efficiency of 19.2% is achieved in D18:BTP-eC9-4F based organic photovoltaics. Our findings demonstrate a facile strategy to improve the packing quality of solution-processed organic semiconductors for high-efficiency photovoltaics and beyond photovoltaics. | Xinyue Cui Hongxiang Li Hao Lu Yuqiang Liu Guangliu Ran Rui Liu Huarui Zhang Xueqing Ma Dawei Li Yi Lin Jifa Yu Wenkai Zhang Lei Cai Yahui Liu Pei Cheng Andong Zhang Zaifei Ma Guanghao Lu Zhishan Bo | 2024 | Science China Chemistry2024,67,3: | 0 |
| 11 | Facile fabrication of a single-particle platform with high throughput via substrate surface potential regulated large-spacing nanoparticle assembly显示文摘Nanodevices based on the single nanoparticle represent innovative and promising technology,which could satisfy the increasing requirements of high accuracy,low energy consumption,and small volume.However,the acquisition of single particles involves complex operation,and the corresponding nanodevices display low-throughput.Herein,we present a facile strategy to construct a single-particle platform with high throughput via substrate surface potential modulated a large-area and large-spacing nanoparticle assembly.Such platform not only avoids optic interference but also ensures the independent electrically conductive channel of single particle on substrate.Therefore,the dark-field microscopic imaging and single-particle scattering signals collecting of individual nanoparticles with plasmonic effect are satisfactory achieved based on the platform,and the first success in the fabrication of nano-organic-light-emitting-diodes with single nanoparticle resolution in nanoscale.All the results indicate that the strategy may find promising applications in the in situ single-particle research such as single-particle detection,singleparticle catalysis,and optoelectronics. | Dong Li Yinghui Sun Yawen Wang Yuanlan Liu Bo Zhao Wenkai Liang Heng Gao Lin Jiang | 2022 | Nano Research2022,15,7: | 0 |
| 12 | DPB3 and DPB4 proteins regulate Medicago flowering and leaf anthocyanin biosynthesis显示文摘As important subunits of the leading-strand DNA polymerase epsilon,chromatin remodeling,and histone acetylation complexes,the H2A/H2B-like histone-fold domain-containing proteins DNA PO-LYMERASE II SUBUNIT B3(DPB3)and DPB4 play key roles in nucleosome assembly and heterochromatin maintenance during DNA replication in yeast,Drosophila,and mammals(He et al.,2017;Bellelli et al.,2018;Yu et al.,2018;Casari et al.,2021). | Yingying Meng Chongnan Wang Qiqi Li Wenkai Ji Jiangqi Wen Kirankumar S.Mysore Yanxi Pei Lifang Niu Hao Lin | 2023 | Journal of Genetics and Genomics2023,50,6: | 0 |
| 13 | Detour-phased perovskite ultrathin planar lens using direct femtosecond laser writing显示文摘Perovskite-enabled optical devices have drawn intensive interest and have been considered promising candidates for integrated optoelectronic systems.As one of the important photonic functions,optical phase modulation previously was demonstrated with perovskite substrate and complex refractive index engineering with laser scribing.Here we report on the new scheme of achieving efficient phase modulation by combining detour phase design with 40 nm ultrathin perovskite films composed of nanosized crystalline particles.Phase modulation was realized by binary amplitude patterning,which significantly simplifies the fabrication process.Perovskite nanocrystal films exhibit significantly weak ion migration effects under femtosecond laser writing,resulting in smooth edges along the laser ablated area and high diffractive optical quality.Fabrication of a detour-phased perovskite ultrathin planar lens with a diameter of 150μm using femtosecond laser scribing was experimentally demonstrated.A high-performance 3D focus was observed,and the fabrication showed a high tolerance with different laser writing powers.Furthermore,the high-quality imaging capability of perovskite ultrathin planar lenses with a suppressed background was also demonstrated. | WENKAI YANG LIGE LIU DASHAN DONG XIN ZHANG HAN LIN YUNKUN WANG HONG YANG YUNAN GAO HAIZHENG ZHONG BAOHUA JIA KEBIN SHI | 2022 | Photonics Research2022,10,12: | 0 |
| 14 | Targeting the Central Histamine H, Receptor: New Hope for Schizophrenia?显示文摘Histamine is a neurotransmitter and neuromodulator in the central nervous system,which plays its function through binding with diferent histamine receptors,such as H_(1)receptor(H_(1)R),H_(2)receptor(H_(2)R),H_(3)receptor(H_(3)R),and H_(4)receptor(H_(4)R)[1,2].Although both H_(1)R and H_(2)R,as post-synaptic receptors,are expressed in most brain areas,they captured different attention from scientists.H,R is well stud-ied and believed to play critical roles in many physiological and pathological processes,including sleep and wakefulness. | Wenkai Lin Xuemin Yu Xinyan Zhu | 2024 | Neuroscience Bulletin2024,40,1: | 0 |
| 15 | Doped-nitrogen enhanced the performance of Nb_(2)CT_(x)on the electrocatalytic synthesis of H_(2)O_(2)显示文摘Electrochemical oxygen reduction reaction(ORR)for preparing hydrogen peroxide(H_(2)O_(2))is a promising way to replace the anthraquinone method.The key to H_(2)O_(2)production is the development of catalysts to regulate the oxygen reduction reaction pathway.Here,nitrogen-doped Nb_(2)CT_(x)was prepared by NH3 annealing method.Compared with precursor Nb_(2)AlC(67.01%)and pure Nb_(2)CT_(x)(75.70%),nitrogen-doped Nb_(2)CT_(x)exhibited excellent performance for 2e−ORR with>90%H_(2)O_(2)selectivity(at 0.4 V vs.reversible hydrogen electrode(RHE)).Faradic efficiency of nitrogen-doped Nb_(2)CT_(x)reached 80.75%,whereas those for Nb2AlC and Nb_(2)CT_(x)were 60.35%and 39.27%,respectively.A desirable catalytic stability for 50 h was observed.Density functional theory(DFT)calculations indicated excellent activity of the nitrogen-doped Nb_(2)CT_(x)was attributed to the introduction of N.This excellent activity was conducive to the adsorption of oxygen and promoted the formation of the OOH intermediate.This work can serve as an important reference for regulating the electronic structure of MXene to expand the application area in the electrochemical field. | Shijie Zhang Jingnan Zheng Junming Lin Yuanan Li Zhikang Bao Xiaoge Peng Wenkai Ji Lei Ding Zaixiang Xu Guoliang Wang Xing Zhong Jianguo Wang | 2023 | Nano Research2023,16,5: | 0 |
| 16 | Rational Design of Plasmonic Metal Nanostructures for Solar Energy Conversion显示文摘Plasmonic metal nanostructures,possessing unique surface plasmon resonance properties,show excellent capabilities for light trapping and coupling.On this basis,various plasmonic metal nanostructures offer extraordinary opportunities to promote the conversion efficiency of solar energy to electric energy,hydrogen energy or thermal energy,and so on.In this review article,we highlight a number of recent research achievements on the rational design of plasmonic metal nanostructures so as to maximize the utilization of the entire solar spectrum.Compared with single metal nanoparticles,multiplex(such as multicompositions,sizes,or shapes)nanoparticle structures emphasize advantages in broadening the absorption range and improving light-utilization efficiency.This review concludes with discussions regarding challenges in this research field and proposals of prospects for future directions. | Yawen Wang Junchang Zhang Wenkai Liang He Yang Tianfu Guan Bo Zhao Yinghui Sun Lifeng Chi Lin Jiang | 2022 | CCS Chemistry2022,4,4: | 0 |
| 17 | Optimizing the morphology of all-polymer solar cells for enhanced photovoltaic performance and thermal stability显示文摘Due to the complicated film formation kinetics, morphology control remains a major challenge for the development of efficient and stable all-polymer solar cells(all-PSCs). To overcome this obstacle, the sequential deposition method is used to fabricate the photoactive layers of all-PSCs comprising a polymer donor PTzBI-oF and a polymer acceptor PS1. The film morphology can be manipulated by incorporating amounts of a dibenzyl ether additive into the PS1 layer. Detailed morphology investigations by grazing incidence wide-angle X-ray scattering and a transmission electron microscope reveal that the combination merits of sequential deposition and DBE additive can render favorable crystalline properties as well as phase separation for PTzBI-oF:PS1 blends. Consequently, the optimized all-PSCs delivered an enhanced power conversion efficiency(PCE) of 15.21%along with improved carrier extraction and suppressed charge recombination. More importantly, the optimized all-PSCs remain over 90% of their initial PCEs under continuous thermal stress at 65 °C for over 500 h. This work validates that control over microstructure morphology via a sequential deposition process is a promising strategy for fabricating highly efficient and stable all-PSCs. | Kang An Wenkai Zhong Chunguang Zhu Feng Peng Lei Xu Zhiwei Lin Lei Wang Cheng Zhou Lei Ying Ning Li Fei Huang | 2023 | Journal of Semiconductors2023,44,5: | 0 |