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| 1 | Adsorptive removal of phosphate by the bimetallic hydroxide nanocomposites embedded in pomegranate peel显示文摘This study aimed to fabricate new and effective material for the efficiency of phosphate adsorption.Two types of adsorbent materials,the zirconium hydroxides embedded in pomegranate peel(Zr/Peel)and zirconium-lanthanum hydroxides embedded in pomegranate peel(Zr-La/Peel)were developed.Scanning electronic microscopy(SEM),x-ray photoelectron spectroscopy(XPS)and x-ray diffraction(XRD)were evaluated to give insight into the physicochemical properties of these adsorbents.Zr-La/Peel exceeded the adsorption efficiency of Zr/Peel adsorbents in batch adsorption experiments at the same pH level.The peel as a host can strive to have a strong'shielding effect'to increase the steadiness of the entrenched Zr and La elements.La and Zr are hydroxide metals that emit many hydrogen ions during the hydrolysis reaction,which contribute to protonation and electrostatic attraction.The highest adsorption capacity of La-Zr/Peel for phosphate was calculated to be40.21 mg/g,and pseudo second-order equation is very well fitted for kinetic adsorption.Phosphate adsorption efficiency was reduced by an increase of pH.With the background of coexisting Cl-,little effect on adsorption efficiency was observed,while adsorption capacities were reduced by almost 20-30%with the coexistence of SO42-,NO3-and humic acid(HA). | Muhammad Akram Xing Xu Baoyu Gao Qinyan Yue Shang Yanan Rizwan Khan Muhammad Ali Inam | 2020 | Journal of Environmental Sciences2020，32，5： | 8 |
| 2 | Design and Control of Thermally Coupled Reactive Distillation Sequence for Biodiesel Production显示文摘Decreasing petroleum reserves and growing alternative fuels requirements have promoted the study of biodiesel production. In this work, two thermally coupled reactive distillation designs for biodiesel production were investigated, and the sensitivity analysis was conducted to obtain the appropriate design values. The thermodynamic analysis and economics evaluation were performed to estimate the superiority of the thermally coupled designs over the base case. The proposed biodiesel production processes were simulated using the simulator Aspen Plus, and calculation results show that the exergy loss and economic cost in the two thermally coupled designs can be greatly reduced. It is found that the thermally coupled side-stripper reactive distillation design provides more economic benefits than the side-rectifier one. The dynamic performance of the thermally coupled side-stripper design was investigated and the results showed that the proposed control structure could effectively handle large feed disturbances. | Li Lumin Sun Lanyi Xie Xu Tian Yanan Shang Jianlong Tian Yuanyu | 2016 | China Petroleum Processing & Petrochemical Technology2016，18，2： | 2 |
| 3 | Carbon-based single atom catalyst: Synthesis, characterization, DFT calculations显示文摘Carbon-based single-atom catalysts(SACs) with atomic sizes of active sites have become the promising candidates for a variety of catalytic systems because of their high atom utilization, and unique electronic structures. Different types of single-atom sites can be fabricated via multiple preparation strategies, which would demonstrate distinct different coordination configurations and electronic features, and ultimately affected the structure-catalysis relationship of SACs in targeted reactions. As a result, it is necessary to identify the active sites of SACs and understand the structure-catalysis relationship of SACs at the atomic scale. In this review, a variety of preparation strategies of carbon-based SACs were documented. Then, the recent development on versatile characterization techniques and computational achievements were summarized regarding in understanding the electronic and geometric characteristics of carbon-based SACs.Finally, major challenges and development directions concerning single-atom sites identification and advanced tools development are discussed to shed light on future research of carbon-based SACs. | Yanan Shang Xiaoguang Duan Shaobin Wang Qinyan Yue Baoyu Gao Xing Xu | 2022 | Chinese Chemical Letters2022，33，2： | 2 |
| 4 | Evaluation of grain breakage sensitivity of maize varieties mechanically-harvested by combine harvester显示文摘A high grain breakage rate is the main problem that occurs during mechanical maize harvest in China.The breakage sensitivity of different varieties was significantly different,and the breakage resistance is heritable.Therefore,breakage resistant variety screening can help improve the field production efficiency and provide references for breeding work.In this study,42 varieties of maize were harvested with the same mechanical parameters and the same manipulator on a range of harvest dates at experimental stations in Xinxiang,Henan Province,in 2017 and Changji,Xinjiang Province,in 2018 to determine the sensitivity of grain moisture content on grain breakage rate during machine harvest for different varieties.The integral value of the grain breakage rate curve corresponding to the range of 15%to 30%grain moisture content was used as an index that expressed the sensitivity of maize grains to breakage depending on grain moisture content(BSW).Forty-two varieties were categorized as having weak,intermediate,or strong BSW.Among the same four varieties in the two stations,Lianchuang 825 and Lianchuang 808 were classified as sensitive and fragile varieties,Shandan 650 was classified as an intermediate variety,Zeyu 8911 was divided into weak sensitive and breakage-resistance varieties in Xinxiang and intermediate varieties in Changji.The BSW classification results at the two experimental sites were generally consistent,indicating that breakage sensitivity due to moisture content may be a relatively stable genetic characteristic.This study suggested that the integral method for determining BSW can be used to assess the resistance of different maize varieties to grain breakage during mechanical harvesting.The integral method was used to identify twelve breakage-resistant varieties in Xinxiang Station,and six breakage-resistant varieties in Changji Station.This study provides a method for screening maize varieties that are suited to mechanical grain harvesting and for studying the mechanisms of grain breakage resistance. | Yizhou Wang Lulu Li Shang Gao Yanan Guo Guoqiang Zhang Bo Ming Ruizhi Xie Jun Xue Peng Hou Keru Wang Shaokun Li | 2020 | International Journal of Agricultural and Biological Engineering2020，13，5： | 1 |
| 5 | (+)/(-)-Yanhusuosines A and B, two dimeric benzylisoquinoline-protoberberine alkaloid atropo-enantiomers featuring polycyclic skeletons from Corydalis yanhusuo显示文摘(+)/(-)-Yanhusuosines A(1) and B(2), two pairs of trace benzylisoquinoline-protoberberine atropoenantiomeric homodimers featuring an unprecedented 6/7/6/6/6/6 hexacyclic skeleton, were isolated from the tubers of Corydalis yanhusuo. The structures of(+)/(-)-1 and(+)/(-)-2 were elucidated using spectroscopic and quantum-chemical calculation approaches.(+)/(-)-Yanhusuosines A(1) and B(2)represent a new class of alkaloid dimers biogenetically constructed by a molecule of benzylisoquinoline with a unit of protoberberine via an intermolecular [4 + 3] cycloaddition. Their plausible biosynthetic pathways are discussed, and compound 2 exerted moderate inhibitory activity of NO formation in LPS induced RAW264.7 macrophages. | Guiyang Xia Biaobing Xiao Lingyan Wang Huan Xia Yuzhuo Wu Yanan Wang Hongcai Shang Sheng Lin | 2023 | Chinese Chemical Letters2023，34，7： | 1 |
| 6 | Activation and Coreceptor Expression of T Lymphocytes in HIV/AIDS Patients of China显示文摘 | Hong Shang Zining Zhang Yongjun Jiang Xiaoxu Han Yanan Wang Min Zhang Xiaohui Ye Ying Liu Yingying Diao Di Dai Wenqing Geng | 2005 | Journal of Clinical Immunology2005，，1： | 1 |
| 7 | Insights into the effect of substrate adsorption behavior over hemelike Fe_(1)/AC single-atom catalyst显示文摘Unraveling the substrate adsorption structure–performance relationship is pivotal for heterogeneous carbon supported metal single-atom catalysts(M_(1)/C SACs).However,due to the complexity of the functional groups on carbon material surface,it is still a great challenge.Herein,inspired by structure of enzymes,we used activated carbon(AC),which has adjustable surface oxygen functional groups(OFGs),supported atomically dispersed Fe-N_(4) sites as heme-like catalyst.And based on a combination of scanning transmission electron microscopy(STEM),X-ray photoelectron spectroscopy(XPS),X-ray absorption spectroscopy(XAS),Mössbauer spectroscopy,Fourier transform infrared(FT-IR)characterizations,kinetics experiments and density functional theory(DFT)calculations,we revealed the effect of substrate adsorption behavior on AC support surface,that is,with the increase of carboxyl group in OFGs,the adsorbed 3,3',5,5'-tetramethylbenzidine(TMB)molecular increased,and consequently the substrate enriched on AC surface.Such carboxyl group as well as Fe-N_(4) active sites synergistically realized high-efficiency peroxidase-like activity,just like the heme.This work suggests that simultaneously constructing metal single-atom active sites and specific functional groups on carbon support surface may open an avenue for engineering metal-support synergistic catalysis in M_(1)/C SACs,which can further improve catalytic performance. | Jianglin Duan Yanan Zhou Yujing Ren Dan Feng Jinlong Shang Huibin Ge Jie Gao Jinlong Yang Yong Qin | 2022 | Nano Research2022，15，7： | 0 |
| 8 | Comparative study of raw and HNO_(3)-modified porous carbon from waste printed circuit boards for sulfadiazine adsorption: Experiment and DFT study显示文摘A huge amount of waste printed circuit boards(WPCBs) was produced while the electronic manufacturing industry developed rapidly. WPCBs mainly consist of organic compounds, which makes it possible to prepare them into porous carbon as valuable adsorbent. However, WPCBs are also rich in valuable metals.Cu makes up the most of these metals. It is worth studying whether the residual metal will affect the application of carbon materials. In this study, the porous active carbon(AC) was prepared from WPCBs as an adsorbent. Sulfadiazine(SD), a widely detected antibiotic contaminant, was used as a target pollutant.Nitric acid(HNO_(3)) was used to modify AC(AC-HNO_(3)) to remove the residual Cu. The experiment results showed that the adsorption kinetics of SD by AC(k = 0.0025) and AC-HNO_(3)(k = 0.0029) can be described better using a pseudo-second-order kinetic equation. The adsorption isotherms of AC and AC-HNO_(3) on SD could be fitted by the Langmuir model. AC had a larger adsorption capacity than AC-HNO_(3). Density functional theory(DFT) calculation results suggested that the-OH group and Cu on the surface of AC could be the adsorption sites and promote the SD adsorption. This work provides practical methods to recycle WPCBs into wealth and realized waste control by waste. | Yujiao Kan Ruxin Zhang Xing Xu Bo Wei Yanan Shang | 2023 | Chinese Chemical Letters2023，34，7： | 0 |
| 9 | Enhancing carbon dioxide reduction electrocatalysis by tuning metal-support interactions: a first principles study显示文摘The electrochemical reduction of CO_(2) is an extremely potential technique to achieve the goal of carbon neutrality,but the development of electrocatalysts with high activity,excellent product selectivity,and long-term durability remains a great challenge.Herein,the role of metal-supports interaction(MSI)between different active sites(including single and bimetallic atom sites consisting of Cu and Ni atoms)and carbon-based supports(including C_(2) N,C_(3)N_(4),N-coordination graphene,and graphdiyne)on catalytic activity,prod-uct selectivity,and thermodynamic stability towards CO_(2) reduction reaction(CRR)is systematically investi-gated by first principles calculations.Our results show that MSI is mainly related to the charge transfer behavior from metal sites to supports,and different MSI leads to diverse magnetic moments and d-band centers.Subsequently,the adsorption and catalytic performance can be efficiently improved by tuning MSI.Notably,the bimetallic atom supported graphdiyne not only exhibits a better catalytic activity,higher product selec-tivity,and higher thermodynamic stability,but also effectively inhibits the hydrogen evolution reaction.This finding provides a new research idea and optimization strategy for the rational design of high-efficiency CRR catalysts. | Riming Hu Yanan Yu Yongcheng Li Yiran Wang Jiaxiang Shang Xuchuan Jiang | 2023 | Green Chemical Engineering2023，4，3： | 0 |
| 10 | Stability and regeneration of metal catalytic sites with different sizes in Fenton-like system显示文摘Metal-based catalysts with different site sizes(e.g.,metal nanoparticles(NPs)and single atom catalysts(SACs))demonstrated outstanding catalytic activities in versatile Fenton-like reactions.However,the surface/structural instability is a critical issue,which will result in rapid passivation in Fenton-like reaction and fail in long-term operation.The catalytic stability of the catalysts with different metal sizes considering versatile peroxides(H_(2)O_(2),peroxymonosulfate(PMS),and peroxodisulfate(PDS))should be analyzed.In addition,strategies for catalyst regeneration and recyclability improvement are also important to realize the metal-based catalysts for practical applications.In this review,catalytic stability of catalysts with different metal sizes in the backgrounds of versatile peroxides and water matrixes in Fenton-like reactions were first evaluated.Regeneration of metal catalytic sites with different methods were also reviewed.Finally,major challenges and development of methods concerning the stability and regeneration of metal catalytic sites with different sizes were discussed to understand the future researches of metal catalytic sites in Fenton-like reactions. | Yanan Shang Yujiao Kan Xing Xu | 2023 | Chinese Chemical Letters2023，34，8： | 0 |
| 11 | Impact of intensity variability of the Asian summer monsoon anticyclone on the chemical distribution in the upper troposphere and lower stratosphere显示文摘亚洲夏季风期,平流层-对流层物质交换过程能显著影响上对流层下平流层化学成分的浓度变化和空间分布.然而,亚洲夏季风反气旋强度的季节内变化对其内部和周围地区化学成分水平分布的影响尚不清楚.本文将亚洲夏季风反气旋划分为季节内强周期和弱周期,发现当亚洲夏季风反气旋更强时,100 hPa O_(3)低值区的面积更大,O_(3)浓度更低.但是这种影响主要体现在6月份,7,8月的O_(3)水平分布还受东南亚地区深对流的影响.这些结果表明亚洲夏季风反气旋强度和深对流的季节内变化可以显著影响亚洲夏季风期上对流层下平流层的化学分布. | Kecheng Peng Jiali Luo Jiayi Mu Xiaoqun Cao Hongying Tian Lin Shang Yanan Guo | 2022 | Atmospheric and Oceanic Science Letters2022，15，3： | 0 |
| 12 | Algorithm for simulating ocean circulation on a quantum computer显示文摘The accurate and efficient simulation of ocean circulation is a fundamental topic in marine science;however,it is also a well-known and dauntingly difficult problem that requires solving nonlinear partial differential equations with multiple variables.In this paper,we present for the first time an algorithm for simulating ocean circulation on a quantum computer to achieve a computational speedup.Our approach begins with using primitive equations describing the ocean dynamics and then discretizing these equations in time and space.It results in several linear system of equations(LSE)with sparse coefficient matrices.We solve these sparse LSE using the variational quantum linear solver that enables the present algorithm to run easily on near-term quantum computers.Additionally,we develop a scheme for manipulating the data flow in the algorithm based on the quantum random access memory and l∞norm tomography technique.The efficiency of our algorithm is verified using multiple platforms,including MATLAB,a quantum virtual simulator,and a real quantum computer.The impact of the number of shots and the noise of quantum gates on the solution accuracy is also discussed.Our findings demonstrate that error mitigation techniques can efficiently improve the solution accuracy.With the rapid advancements in quantum computing,this work represents an important first step toward solving the challenging problem of simulating ocean circulation using quantum computers. | Ruimin SHANG Zhimin WANG Shangshang SHI Jiaxin LI Yanan LI Yongjian GU | 2023 | Science China Earth Sciences2023，66，10： | 0 |
| 13 | Haplotype variation and KASP markers for SiPSY1-A key gene controlling yellow kernel pigmentation in foxtail millet显示文摘Carotenoid biosynthesis and accumulation are important in determining nutritional and commercial value of crop products.Yellow pigmentation of mature kernels caused by carotenoids is considered a vital quality trait in foxtail millet,an ancient and widely cultivated cereal crop across the world.Genomic regions associated with yellow pigment content(YPC),lutein and zeaxanthin in foxtail millet grains were identified by genome-wide association analysis(GWAS),and SiPSY1(Phytoene synthase 1 which regulates formation of the 40-carbon backbone of carotenoids)was confirmed as the main contributor to all three components by knockout and overexpression analysis.SiPSY1 was expressed in seedlings,leaves,panicles,and mature seeds,and was subcellularly localized to chloroplasts.Transcription of SiPSY1 in 15 DAP immature grains was responsible for YPC in mature seeds.Selection of SiPSY1 combined with increased YPC in mature grains during domestication of foxtail millet was confirmed.Haplotype analysis suggested that expression level of SiPSY1 could be a selection target for future breeding programs,and a KASP marker was developed for selection of favorable SiPSY1 alleles in breeding.The results of this work will benefit nutritional and commercial improvement of foxtail millet varieties,as well as other cereal crops. | Rongjun Zuo Yanyan Zhang Yanbing Yang Chunfang Wang Hui Zhi Linlin Zhang Sha Tang Yanan Guan Shunguo Li Ruhong Cheng Zhonglin Shang Guanqing Jia Xianmin Diao | 2023 | The Crop Journal2023，11，6： | 0 |
| 14 | Rational design of bimetallic atoms supported on C3N monolayer to break the linear relations for efficient electrochemical nitrogen reduction显示文摘Linear relations between the adsorption free energies of nitrogen reduction reaction(NRR)intermediates limit the catalytic activity of single atom catalysts(SACs)to reach the optimal region.Significant improvements in NRR activity require the balance of binding strength of reaction intermediates.Herein,we have investigated the C_(3)N-supported monometallic(M/C_(3)N)and bimetallic(M_(1)M_(2)/C_(3)N)atoms for the electrochemical NRR by using density functional theory(DFT)calculations.The results show that this linear relation does exist for SACs because all the intermediates bind to the same site on M/C_(3)N.But the synergistic effect of the two atoms in M_(1)M_(2)/C_(3)N can create a more flexible adsorption site for intermediates,which results in the decoupling of adsorption free energies of key intermediates.Subsequently,the fundamental limitation of scaling relations on limiting potentials is broken through.Most notably,the optimal limiting potential is increased from−0.63 V for M/C_(3)N to−0.20 V for M_(1)M_(2)/C_(3)N.In addition,the presence of bimetallic atoms can also effectively inhibit the hydrogen evolution reaction(HER)as well as improve the stability of the catalysts.This study proposes that the introduction of bimetallic atoms into C_(3)N is beneficial to break the linear relations and develop efficient NRR electrocatalysts. | Riming Hu Yanan Yu Yongcheng Li Yiran Wang Jiaxiang Shang Yong Nie Xuchuan Jiang | 2022 | Nano Research2022，15，9： | 0 |
| 15 | Machine learning and microstructure design of polymer nanocomposites for energy storage application显示文摘Film dielectric capacitors have been widely used in high‐power electronic equipment.The design of microstructure and the choice of fillers play an important role in nano-composites'energy storage density.Machine learning methods can classify and summarise the limited data and then explore the promising composite structure.In this work,a dataset has been established,which contained a large amount of data on the maximum energy storage density of nanocomposites.Though using processed visual image infor-mation to express the internal information of composite,the prediction accuracy of the prediction models built by three machine learning algorithms increase from 84.1%to 91.9%,80.9%to 68.9%,70.6%to 81.6%,respectively.By calculating the branch weight in the random forest prediction model,the influence degree of different descriptors on the energy storage performance of nanocomposites is analysed.A total of 10 groups of composites with different structure and filler amount were prepared in the laboratory,which were used to verify the reliability of prediction models.Finally,the effective filler's structure is explored by three prediction models and some suggestions for the interface design of filler are given. | Yu Feng Wenxin Tang Yue Zhang Tiandong Zhang Yanan Shang Qingguo Chi Qingguo Chen Qingquan Lei | 2022 | High Voltage2022，7，2： | 0 |
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