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| 1 | Preliminary investigation of phosphorus adsorption onto two types of iron oxide-organic matter complexes显示文摘Iron oxide(FeO)coated by natural organic matter(NOM)is ubiquitous.The associations of minerals with organic matter(OM)significantly changes their surface properties and reactivity,and thus affect the environmental fate of pollutants,including nutrients(e.g.,phosphorus(P)).In this study,ferrihydrite/goethite-humic acid(FH/GE–HA)complexes were prepared and their adsorption characteristics on P at various p H and ionic strength were investigated.The results indicated that the Fe O–OM complexes showed a decreased P adsorption capacity in comparison with bare Fe O.The maximum adsorption capacity(Q_(max))decreased in the order of FH(22.17 mg/g)>FH-HA(5.43 mg/g)>GE(4.67 mg/g)>GE-HA(3.27 mg/g).After coating with HA,the amorphous FH–HA complex still showed higher P adsorption than the crystalline GE–HA complex.The decreased P adsorption observed might be attributed to changes of the Fe O surface charges caused by OM association.The dependence of P adsorption on the specific surface area of adsorbents suggests that the Fe O component in the complexes is still the main contributor for the adsorption surfaces.The P adsorptions on Fe O–HA complexes decreased with increasing initial p H or decreasing initial ionic strength.A strong dependence of P adsorption on ionic strength and p H may demonstrate that outer-sphere complexes between the OM component on the surface and P possibly coexist with inner-sphere surface complexes between the Fe O component and P.Therefore,previous over-emphasis on the contributions of original minerals to P immobilization possibly over-estimates the P loading capacity of soils,especially in humic-rich areas. | Jinlong Yan Tao Jiang Ying Yao Song Lu Qilei Wang Shiqiang Wei | 2016 | Journal of Environmental Sciences2016，28，4： | 9 |
| 2 | High-performance Zn battery with transition metal ions co-regulated electrolytic MnO_(2)显示文摘Electrolytic MnO_(2)/Zn batteries have attracted extensive attention for use in large-scale energy storage applications due to their low cost,high output voltage,safety,and environmental friendliness.However,the poor electrical conductivity of MnO_(2)limits its deposition and dissolution at large capacities,which leads to sluggish reaction kinetics and drastic capacity decay.Here,we report a theory-guided design principle for an electrolytic MnO_(2)/Zn battery co-regulated with transition metal ions that has improved electrochemical performance in terms of deposition and stripping chemistries.We start with first-principles calculations to predict the electrolytic effects of regulating transition metal ions in the deposition/stripping chemistry of the MnO_(2)cathode.The results indicate that with the simultaneous incorporation of strongly electronegative Co and Ni,the MnO_(2)cathode tends to possess more active electron states,faster charge-transfer kinetics,and better electrical conductivity than either MnO_(2)regulated with Co or Ni on their own,or pristine MnO_(2);hence,this co-regulation is beneficial for the cathode solid/liquid MnO_(2)/Mn2t reactions.We then fabricate and demonstrate a novel Co2t and Ni2t coregulated MnO_(2)/Zn(Co-Ni-MnO_(2)/Zn)battery that yields significantly better electrochemical performance,finding that the synergistic regulation of Co and Ni on MnO_(2)can significantly increase its intrinsic conductivity and achieve high rates and Coulombic efficiencies at large capacities.The aqueous Co-Ni-MnO_(2)/Zn battery exhibits a high rate(10C,100 mA cm^(-2)),high Coulombic efficiency(91.89%),and excellent cycling stability(600 cycles without decay)at a large areal capacity of 10 mAh cm^(-2).Our proposed strategy of co-regulation with transition metal ions offers a versatile approach for improving the electrochemical performance of aqueous electrolytic MnO_(2)/Zn batteries in large-scale energy storage applications. | Mingyan Chuai Jinlong Yang Mingming Wang Yuan Yuan Zaichun Liu Yan Xu Yichen Yin Jifei Sun Xinhua Zheng Na Chen Wei Chen | 2021 | eScience2021，1，2： | 8 |
| 3 | Recent developments in electrocatalysts and future prospects for oxygen reduction reaction in polymer electrolyte membrane fuel cells显示文摘The main difficulty in the extensive commercial use of polymer electrolyte membrane fuel cells(PEMFCs)is the use of noble metals such as Pt-based electrocatalyst at the cathode, which is essential to ease the oxygen reduction reaction(ORR) in fuel cells(FCs). To eliminate the high loading of Pt-based electrocatalysts to minimize the cost, extensive study has been carried out over the previous decades on the non-noble metal catalysts. Development in enhancing the ORR performance of FCs is mainly due to the doped carbon materials, Fe and Co-based electrocatalysts, these materials could be considered as probable substitutes for Pt-based catalysts. But the stability of these non-noble metal electrocatalysts is low and the durability of these metals remains unclear. The three basic reasons of instability are:(i) oxidative occurrence by H_2O_2,(ii) leakage of the metal site and(iii) protonation by probable anion adsorption of the active site. Whereas leakage of the metal site has been almost solved, more work is required to understand and avoid losses from oxidative attack and protonation. The ORR performance such as stability tests are usually run at low current densities and the lifetime is much shorter than desired need. Therefore,improvement in the ORR activity and stability are the key issues of the non-noble metal electrocatalyst.Based on the consequences obtained in this area, numerous future research directions are projected and discussed in this paper. Hence, this review is focused on improvement of stability and durability of the non-noble metal electrocatalyst. | Maryam Kiani Jie Zhang Yan Luo Chunping Jiang Jinlong Fan Gang Wang Jinwei Chen Ruilin Wang | 2018 | Journal of Energy Chemistry2018，27，4： | 7 |
| 4 | Underestimation of phosphorus fraction change in the supernatant after phosphorus adsorption onto iron oxides and iron oxide–natural organic matter complexes显示文摘The phosphorus(P) fraction distribution and formation mechanism in the supernatant after P adsorption onto iron oxides and iron oxide-humic acid(HA) complexes were analyzed using the ultrafiltration method in this study.With an initial P concentration of 20 mg/L(I =0.01 mol/L and pH = 7),it was shown that the colloid(1 kDa-0.45 μm) component of P accounted for 10.6%,11.6%,6.5%,and 4.0%of remaining total P concentration in the supernatant after P adsorption onto ferrihydrite(FH),goethite(GE),ferrihydrite-humic acid complex(FH-HA),goethite-humic acid complex(GE-HA),respectively.The <1 kDa component of P was still the predominant fraction in the supernatant,and underestimated colloidal P accounted for 2.2%,55.1%,45.5%,and 38.7%of P adsorption onto the solid surface of FH,FH-HA,GE and GE-HA,respectively.Thus,the colloid P could not be neglected.Notably,it could be interpreted that Fe^(3+) hydrolysis from the adsorbents followed by the formation of colloidal hydrous ferric oxide aggregates was the main mechanism for the formation of the colloid P in the supernatant.And colloidal adsorbent particles co-existing in the supernatant were another important reason for it.Additionally,dissolve organic matter dissolved from iron oxide-HA complexes could occupy large adsorption sites of colloidal iron causing less colloid P in the supernatant.Ultimately,we believe that the findings can provide a new way to deeply interpret the geochemical cycling of P,even when considering other contaminants such as organic pollutants,heavy metal ions,and arsenate at the sediment/soil-water interface in the real environment. | Jinlong Yan Tao Jiang Ying Yao Jun Wang Yuanli Cai Nelson W.Green Shiqiang Wei | 2017 | Journal of Environmental Sciences2017，29，5： | 7 |
| 5 | Synthesis of low-cost porous ceramic microspheres from waste gangue for dye adsorption显示文摘Low-cost porous ceramic microspheres from waste gangue were prepared by simple spray drying and subsequent calcination. Effects of calcination temperature on phase and microstructure evolution, specific surface area, pore structure, and dye adsorption mechanism of the microspheres were investigated systematically. Results showed that the microspheres were spherical, with some mesopores both on the surface and inside the spheres. The phase kept kaolinite after calcined at 800 and 900 ℃ and transformed into mullite at 1000 ℃. The microspheres calcined at 800 ℃ showed larger adsorption capacity and removal efficiency than those calcined at higher temperatures. Methylene blue(MB) and basic fuchsin(BF) removal efficiency reached 100% and 99.9% with the microsphere dosage of 20 g/L, respectively, which was comparable to that of other low-cost waste adsorbents used to remove dyes in the literature. Adsorption kinetics data followed the pseudosecond-order kinetic model, and the isotherm data fit the Langmuir isotherm model. The adsorption process was attributed to multiple adsorption mechanisms including physical adsorption, hydrogen bonding, and electrostatic interactions between dyes and gangue microspheres. The low-cost porous microspheres with excellent cyclic regeneration properties are promising absorbent for dyes in wastewater filtration and adsorption treatment. | Shu YAN Yiming PAN Lu WANG Jingjing LIU Zaijuan ZHANG Wenlong HUO Jinlong YANG Yong HUANG | 2018 | Journal of Advanced Ceramics2018，7，1： | 6 |
| 6 | First light of the 1.8-m solar telescope–CLST显示文摘Large-aperture solar telescopes play an important role in solar observations and research,and require high temporal and spatial resolution[1].To solve some fundamental problems such as the solar dynamo,coronal heating,and the triggering of major solar eruptions,the spatial resolution for solar-atmosphere observation should reach at least 0.1 arcsec[2]. | ChangHui Rao NaiTing Gu XueJun Rao Cheng Li LanQiang Zhang JinLong Huang Lin Kong Ming Zhang YunTao Cheng Yi Pu Hua Bao YouMing Guo YangYi Liu JinSheng Yang LiBo Zhong ChangJun Wang Kai Fang XiaoJun Zhang DongHong Chen Cheng Wang XinLong Fan ZhiWu Yan KeLe Chen XiYa Wei Lei Zhu Hong Liu YongJian Wan Hao Xian WenLi Ma | 2020 | Science China(Physics,Mechanics & Astronomy)2020，63，10： | 6 |
| 7 | Effects of cerium precursors on surface properties of mesoporous CeMnO_x catalysts for toluene combustion显示文摘Mesoporous CeMnOx composite oxides catalysts were prepared by surfactant-assisted co-precipitation method and used for the catalytic oxidation of toluene.The effect of different cerium precursors[Ce(NO3)3 and(NH4)2 Ce(NO3)6] on catalyst structure,surface properties and toluene combustion activities of mesoporous CeMnOx catalysts were investigated.The Ce(Ⅲ)MnOx catalyst prepared from Ce(NO3)3 precursor shows higher catalytic activity,with a 90% conversion temperature of 240℃,which is better than the Ce(Ⅳ)MnOx catalyst derived from[(NH4)2 Ce(NO3)6] precursor.On the basis of characterizations,it reveals that abundant surface content of Mn4+,better redox behavior and larger concentration of surface active oxygen species are responsible for the excellent catalytic performance. | Changyu Zhang Wei Chu Feng Chen Lei Li Ruiyu Jiang Jinlong Yan | 2020 | Journal of Rare Earths2020，38，1： | 4 |
| 8 | Experimental and Simulation Studies on Cold Welding Sealing Process of Heat Pipes显示文摘Sealing quality strongly affects heat pipe performance, but few studies focus on the process of heat pipe sealing. Cold welding sealing technology based on a stamping process is applied for heat pipe sealing. The bonding mechanism of the cold welding sealing process(CWSP) is investigated and compared with the experimental results obtained from the bonding interface analysis. An orthogonal experiment is conducted to observe the effects of various parameters, including the sealing gap,sealing length, sealing diameter, and sealing velocity on bonding strength. A method with the utilization of saturated vapor pressure inside a copper tube is proposed to evaluate bonding strength. A corresponding finite element model is developed to investigate the effects of sealing gap and sealing velocity on plastic deformation during the cold welding process. Effects of various parameters on the bonding strength are determined and it is found that the sealing gap is the most critical factor and that the sealing velocity contributes the least effect. The best parameter combination(A_1B_3C_1D_3, with a 0.5 mm sealing gap, 6 mm sealing length, 3.8 mm sealing diameter, and 50 mm/s sealing velocity) is derived within the experimental parameters. Plastic deformation results derived from the finite element model are consistent with those from the experiment. The instruction for the CWSP of heat pipes and the design of sealing dies of heat pipes are provided. | Yong LI Shengle CHEN Jinlong HUANG Yuying YAN Zhixin ZENG | 2017 | Chinese Journal of Mechanical Engineering2017，30，2： | 4 |
| 9 | Thermo-and pH-dual responsive inorganic-organic hybrid hydrogels with tunable luminescence显示文摘A thermo-and pH-dual responsive luminescent hydrogel was successfully constructed by coupling dysprosium-containing polyoxometalates Na_9 DyW_(10) O_(36)(DyW_(10)) with the ABA triblock copolymer, where the B block is PEO and the A block is the thermosensitive poly(methoxydi(ethylene glycol) methacrylate-co-N,N-dimethylaminoethyl methacrylate). The complex hybrid underwent a sol-gel phase transition above the lower critical solution temperature(LCST) of the A block. DyW_(10) was electrostatically encapsulated into the hydrophobic domain of the A block with enhanced photoluminescence. When temperature cooled down, the luminescence could be restored. By addition of acids to protonate the A block, and emission of DyW_(10) was simultaneously enhanced. Sensitivity of poly(N,N-dimethy laminoethyl methacrylate)(PDMAEMA) to pH also enabled the emission of DyW_(10)/copolymer hydrogel to be reversibly switched by alternating acid/base treatments. | Jinlong Zhang Haibing Wei Junyan Tan Weihong Qiao Yan Guan Jie Zhang | 2018 | Science China Chemistry2018，61，3： | 2 |
| 10 | Lower abundance of Bacteroides and metabolic dysfunction are highly associated with the post-weaning diarrhea in piglets显示文摘Growing evidences show a direct link between diarrhea and disorders of gut microbiota in pigs.However,whether there are microbial markers associated with post-weaning diarrhea remains unknown.In the current study,we compared the microbial community,functions and metabolites between healthy weaned piglets(group H,n=7)and piglets with post-weaning diarrhea(group D,n=7),in order to find out diarrhea associated microbial markers.Each of 7 fecal samples was collected from H and D piglets(weaned at 21 d and sampled at 26 d).The metagenomic and untargeted metabolomic analysis revealed that the microbial composition,function and metabolic profile in D pigs was considerably reshaped,including the reduced abundance and number of Bacteroides,which significantly correlated with the diarrhea status of host.The carbohydrate metabolism,biosynthesis and metabolism,lipid metabolism,amino acid metabolism,and the activity of glycan and carbohydrates digestion related enzymes showed extensively down-regulated in D pigs compared with H pigs.Diarrhea significantly changed the metabolic profiles of fecal microbiota,and most of the altered metabolites were negatively or positively correlated with the change in the abundance of Bacteroides.In conclusion,the lower abundance of Bacteroides and its associated metabolic dysfunction may be regarded as microbial markers of physiological post-weaning diarrhea in piglets. | Wen Ren Bing Yu Jie Yu Ping Zheng Zhiqing Huang Junqiu Luo Xiangbing Mao Jun He Hui Yan Jinlong Wu Daiwen Chen Yuheng Luo | 2022 | Science China(Life Sciences)2022，65，10： | 2 |
| 11 | Efficient production of pronuclear embryos in breeding and nonbreeding season for generating transgenic sheep overexpressing TLR4显示文摘Background: Brucella is a zoonotic Gram-negative pathogen that causes abortion and infertility in ruminants and humans. TLR4 is the receptor for LPS which can recognize Brucella and initiate antigen-presenting cell activities that affect both innate and adaptive immunity. Consequently, transgenic sheep over-expressing TLR4 are an suitable model to investigate the effects of TLR4 on preventing Brucellosis. In this study, we generated transgenic sheep overexpressing TLR4 and aimed to evaluate the effects of different seasons(breeding and non-breeding season) on superovulation and the imported exogenous gene on growth.Results: In total of 43 donor ewes and 166 recipient ewes in breeding season, 37 donor ewes and 144 recipient ewes in non-breeding season were selected for super-ovulation and injected embryo transfer to generate transgenic sheep.Our results indicated the no. of embryos recovered of donors and the rate of pronuclear embryos did not show any significant difference between breeding and non-breeding seasons(P > 0.05). The positive rate of exogenous TLR4 tested were 21.21 % and 22.58 % in breeding and non-breeding season by Southern blot. The expression level of TLR4 in the transgenic sheep was 1.5 times higher than in the non-transgenic group(P < 0.05). The lambs overexpressing TLR4 had similar growth performance with non-transgenic lambs, and the blood physiological parameters of transgenic and non-transgenic were both in the normal range and did not show any difference.Conclusions: Here we establish an efficient platform for the production of transgenic sheep by the microinjection of pronuclear embryos during the whole year. The over-expression of TLR4 had no adverse effect on the growth of the sheep. | Yan Li Di Lian Shoulong Deng Xiaosheng Zhang Jinlong Zhang Wenting Li Hai Bai Zhixian Wang Hongping Wu Juncai Fu Hongbing Han Jianzhong Feng Guoshi Liu Ling Lian Zhengxing Lian | 2017 | Journal of Animal Science and Biotechnology2017，8，1： | 2 |
| 12 | Influence of biochar on microbial activities of heavy metals contaminated paddy fields 显示文摘 | CUI Liqiang YAN Jinlong YANG Yage | 2013 | Bioresources2013，8，4： | 1 |
| 13 | Graphene-Based Photo-Fenton Catalysts for Pollutant Control显示文摘Water pollution is a global environmental issue with multi-dimensional infl uences on human life.Some strategies,such as photo-Fenton reaction,have been employed to remove recalcitrant pollutants.Two-dimensional(2D)graphene and its threedimensional(3D)confi gurations have attracted considerable attention as emerging carbon-based catalysts in photo-Fenton fi elds owing to their alluring properties in electron transfer,reactant adsorption,and light response.This review summarizes the recent developments in 2D and 3D graphene-based catalysts for photo-Fenton reactions.Their structures,characteristics,activity,and mechanisms are discussed.The conclusions and outlooks are proposed for the profound understanding of challenges and future directions. | Yan Bao Qingyun Yan Jiahui Ji Bocheng Qiu Jinlong Zhang Mingyang Xing | 2021 | Transactions of Tianjin University2021，27，2： | 1 |
| 14 | Effects of the combined pollution of lead and cadmium on soil urease activity and nitrification 显示文摘 | YAN Jinlong QUAN Guixiang DING Cheng | 2013 | Procedia Environmental Sciences2013，18，： | 1 |
| 15 | Binding constants of lead by humic and fulvic acids studied by anodic stripping square wave voltammetry显示文摘 | Guixiang Quan Jinlong Yan | 2010 | Russian Journal of Electrochemistry2010，，1： | 1 |
| 16 | Hydrogenation of dimethyl oxalate to ethylene glycol over mesoporous Cu ‐ MCM ‐41 catalysts显示文摘 | Xinbin Ma Hanwen Chi Hairong Yue Yujun Zhao Yan Xu Jing Lv Shengping Wang Jinlong Gong | 2013 | AIChE J2013，，7： | 1 |
| 17 | Characteristics of the sea ice reflectance spectrum polluted by oil spills based on field experiments in the Bohai Sea显示文摘Oil spilled on the sea ice surface in the Bohai Sea of China is studied through the field measurements of the reflectance of a simulated sea ice-oil film mixed pixel. The reflection characteristics of sea ice and oil film are also analyzed. It is found that the mixed pixel of sea ice and oil film is a linear mixed pixel. The means of extracting sea ice pixels containing oil film is presented using a double-band ratio oil-film sea-ice index(DROSI) and a normalized difference oil-film sea-ice index(NDOSI) through the analysis of the reflectance curves of the sea iceoil film pixel for different ratios of oil film. The area proportion of the oil film in the sea ice-oil film pixel can be accurately estimated by the average reflectance of the band of 1 610–1 630 nm, and the volume of the spilled oil can be further estimated. The method of the sea ice-oil film pixel extraction and the models to estimate the proportion of oil film area in the sea ice-oil film pixel can be applied to the oil spill monitoring of the ice-covered area in the Bohai Sea using multispectral or hyperspectral remote sensing images in the shortwave infrared band(1 500–1 780 nm). | CHAO Jinlong LIU Chengyu LI Ying LIN Xia YAN Yu | 2017 | Acta Oceanologica Sinica2017，36，1： | 1 |
| 18 | Effect of F-Rich Fluids on the A-Type Magmatism and Related Metal Mobilization:New Insights from the Fogang-Nankunshan-Yajishan Igneous Rocks in Southeast China显示文摘About 45%of tungsten,~20%of tin,and~9%of fluorite of known world reserves are associated with Late Mesozoic igneous rocks,Southeast(SE)China.Here we demonstrate that Fogang granite,the largest inland batholith,is mainly of A2-type that is commonly found in post-orogenic settings and experienced plate subduction induced metasomatism.In contrast,the Yajishan syenite and Nankunshan granite intruding the Fogang granite~20 Ma later are of A1-type formed in intraplate settings.We found that F-rich fluid fractionation,which could make the decline of Ga/Al ratio,total(Nb+Y+Ce+Zr)and Zr concentrations,Nb/Ta and Zr/Hf ratios,leads to chemical variations of a few Fogang granites changing from A2-type to highly fractionated or I-and S-type granitoids.Crystal and Frich fluid fractionations,as well as crustal contamination most likely derived from the Fogang granite,result in some Nankunshan granites developing from A1-type into A2-type.These late-or post-magmatic processes should be taken into account carefully when discriminating the petrogenetic types of igneous rocks,especially for the A2-type suites.Combining with the distribution of 180-140 Ma A1-and A2-type igneous rocks,rare metal deposits,and fluorite deposits in SE China,we highlight the significant role of slab-released F-rich fluids in formation of A-type suites and subsequent chemical differentiation and rare metal and fluorine mineralization.A model of flat-slab northeastward rollback is thus proposed,in which the subduction front reached somewhere near Fogang and then started to roll back at~165 Ma.The inland Jurassic granites of SE China represent a unique locality for formation of A-type suites and their associated mineralization.These granites are not anorogenic,but they are the result of slab rollback from a flat slab,founding of that slab at shallow levels,and metasomatism of by F-rich fluids related to slab heating by the asthenosphere. | Xing Ding Koulin Su Haibo Yan Jinlong Liang Weidong Sun | 2022 | Journal of Earth Science2022，33，3： | 1 |
| 19 | Cu-doped zeolites for catalytic oxidative carbonylation: The role of Br?nsted acids显示文摘 | Shouying Huang Yue Wang Zengzhu Wang Bing Yan Shengping Wang Jinlong Gong Xinbin Ma | 2012 | Applied Catalysis A General2012，，： | 1 |
| 20 | Novel Substrate PN Junction Isolation for RF Integrated Inductors on Silicon显示文摘 | Liu Chang Chen Xueliang Yan Jinlong | 2001 | Chinese J of Semicon ductors2001，22，12： | 1 |
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