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287篇 您的检索式:作者名="Xiaodong Ma"
    题名 作者 年代 出处 被引量
1Nitric oxide suppresses NLRP3 inflammasome activation and protects against LPS-induced septic shock显示文摘Inflammasomes 是触发 caspase-1 的激活和 interleukin-1β 的成熟的多蛋白质建筑群;(IL-1β) ,然而,这些建筑群的规定仍然保持糟糕描绘了。这里,我们显示出那氮的氧化物(没有) 禁止了调停 NLRP3 的 ASC pyroptosome 形成, caspase-1 激活和 IL-1β在从老鼠和人的 myeloid 房间的分泌物。同时,内长不否定地也源于 iNOS (没有 synthase 的可诱导的形式) 调整 NLRP3 inflammasome 激活。iNOS 的弄空响应 LPS 和 ATP 导致了不正常的线粒体的增加的累积,它为增加的 IL-1β 负责;生产和 caspase-1 激活。没有生产的 iNOS 缺乏或药理学抑制在 vivo 提高了 NLRP3 依赖的 cytokine 生产,因此在老鼠从导致 LPS 的败血增加死亡,它被 NLRP3 阻止缺乏。我们的结果因此经由线粒体的稳定作为 NLRP3 inflammasome 的一个批评否定管理者不识别。这研究有重要含意让新策略的设计控制 NLRP3 相关的疾病。Kairui Mao Shuzhen Chen Mingkuan Chen Yonglei Ma Yan Wang Bo Huang Zhengyu He Yan Zeng Yu Htl Shuhui Sun Jing Li Xiaodong Wu Xiangrui Wang Warren Strober Chang Chen Guangxun Meng Bing Sun 2013Cell Research2013,23,2:59
2Focal depth research of earthquakes in China's Mainland: Implication for tectonics显示文摘Focal depth data of earthquakes in China's Mainland are processed and analyzed in this paper, as well as the relationship between the focal depths and large-scale tectonic structures. As a basic parameter for earthquakes, focal depth is used to investigate deep environment of seis-mogenic regions, tectonic backgrounds for concentration and release of seismic energy, the inner crustal deformation and its mechanic features. Depth data of 31282 ML≥2.0 events with 1st class and 2nd class precision in China's Mainland from Jan. 1, 1970 to May 31, 2000 are used to get spatial features of earthquakes distributed with depth and to provide average depth for each grid area throughout China. Researches show that the average depth (D) for all the earthquakes used in this paper is (16±7) km, and (13±6) km and (18±8) km for the events in eastern China and western China, respectively. The area with the deepest focal depth is located in southwest Xinjiang region, near the western and southwestern ends of the TarimZHANG Guomin WANG Suyun LI Li ZHANG Xiaodong MA Hongsheng 2002Chinese Science Bulletin2002,47,12:38
3Low-temperature SCR activity and SO_2 deactivation mechanism of Ce-modified V_2O_5–WO_3/TiO_2 catalyst显示文摘The promotion effect of ceria modi fi cation on the low-temperature activity of V2O5-WO3/TiO2 catalyst was evaluated for the selective catalytic reduction of NO with NH3(NH3-SCR). The catalytic activity of 1 wt% V2O5-WO3/TiO2 was signi fi cantly enhanced by the addition of 8 wt%ceria, which exhibited a NO x conversion above 80% in a broad temperature range 190–450 1C. This performance was comparable with 3 wt%V2O5-WO3/TiO2, indicating that the addition of ceria contributed to reducing the usage of toxic vanadia in developing low-temperature SCR catalysts. Moreover, V1 Ce WTi exhibited approximately 10% decrease in NOx conversion in the presence of 60 ppm SO2. The characterization results indicated that active components of V, W and Ce were well dispersed on TiO2 support. The synergetic interaction between Ce and V species by forming V–O–Ce bridges enhanced the reducibility of VCe WTi catalyst and thus improved the low-temperature activity. The sulfur poisoning mechanism was also presented on a basis of the designed TPDC(temperature-programmed decomposition) and TPSR(temperatureprogrammed surface reaction) experiments. The deposition of(NH4)2SO4on V1 Ce WTi catalyst was much smaller compared with that on V1 Ti.On the other hand, the oxidation of SO2 to SO3was signi fi cantly promoted on the CeO2-modi fi ed catalyst, accompanied by the formation of cerium sulfates. Therefore, the deactivation of this catalyst was mainly attributed to the vanishing of the V–Ce interaction and the sulfation of active ceria.Ziran Ma Xiaodong Wu Ya Feng Zhichun Si Duan Weng Lei Shi 2015Progress in Natural Science:Materials International2015,25,4:29
4The variation in soil moisture and the appropriate groundwater table for desert riparian forest along the Lower Tarim River显示文摘基于在五年监视更低的 Tarim 河收集的数据,我们由使用变化(Cv ) 的系数的方法分析了土壤潮湿内容(SMC ) 和在 SMC,地下水表格深度(GWD ) 和植被之间的关系的可变性,皮尔森关联和回归。SMC 的可变性的结果显示它随 060 厘米的土壤层的土壤层 SMC 的深度的增加升起了与在在可变性显示出重要增加的 100260 厘米的土壤层的 SMC 相比是相对小的。SMC 和 GWD 在生态的水消遣在 Yingsu 横断和它水路的附近的地点展出了重要差别前后,特别在 100260 厘米的土壤层的 SMC 与 GWD 的重要上升显著地增加了并且在大约 4 m 的 GWD 到达了最大的价值。显著地随 100260 厘米的土壤层的 SMC 的增加改进的植物范围和种类差异,他们俩接近了最大的价值,当 SMC 是时, 92.3% 主要植物种类能成长 >10% 。沿着更低的 Tarim 河恢复荒芜的河边的森林的生态系统, GWD 必须被维持在 < 在水路并且在为这个干旱区域的其余部分的大约 4 m 的附近的 4 m。MA Xiaodong CHEN Yaning ZHU Chenggang LI Weihong 2011Journal of Geographical Sciences2011,21,1:23
5Effects of WOx modification on the activity, adsorption and redox properties of CeO_2 catalyst for NO_x reduction with ammonia显示文摘A series of WO3/CeO2 (WOx/CeO2) catalysts were synthesized by wet impregnation of ammonium metatungstate on a CeO2 support. The resulting solid acid catalysts were characterized by X-ray diffraction (XRD), UV-Vis spectroscopy (UV-Vis), Raman spectroscopy (Raman), in-situ Fourier transform infrared spectroscopy (in-situ FT-IR) of ammonia adsorption, NH3-TPD, H2 temperature-programmed reduction (H2-TPR), NH3/NO oxidation and activity measurements for NOx reduction by NH3 (NH3-SCR). The results show that polytungstate (WOx) species are the main species of tungsten oxide on the surface of ceria. The addition of tungsten oxide enhances the Bro¨nsted acidity of ceria catalysts remarkably and decreases the amount of surface oxygen on ceria, with strong interaction between CeO2 and WOx. As a result, the N2 selectivity of NH3 oxidation and NH3-SCR at high temperatures (> 300℃) is enhanced. Therefore, a wide working temperature window in which NOx conversion exceeds 80% (NOx conversion > 80%) from 200 to 450℃, is achieved over 10 wt.% WOx/CeO2 catalyst. A tentative model of the NH3-SCR reaction route on WOx/CeO2 catalysts is presented.Ziran Ma Duan Weng Xiaodong Wu Zhichun Si 2012Journal of Environmental Sciences2012,24,7:23
6Hydrometallurgical purification of metallurgical grade silicon显示文摘The effects of the particle size of ground metallurgical grade silicon (MG-Si), the sort of acids, and the type of stirring on the purified efficiency of MG-Si were investigated. It was found that a particle size less than 0.1 mm was most effective for acid leaching; the extraction yield of impurities was increased by 9% with HF leaching compared with HCl leaching and HNO3 leaching, and increased by 7% with ultrasonic stirring compared with mechanical stirring. The principle of hydrometallurgical purification of metallurgical grade silicon under ultrasonic fields was also discussed.MA Xiaodong ZHANG Jian WANG Tongmin LI Tingju 2009Rare Metals2009,28,3:20
7Achieve Personalized Anonymity Through Query Blocks Exchanging显示文摘In cyberspace security,the privacy in location-based services(LBSs) becomes more critical. In previous solutions,a trusted third party(TTP) was usually employed to provide disturbance or obfuscation,but it may become the single point of failure or service bottleneck. In order to cope with this drawback,we focus on another important class,establishing anonymous group through short-range communication to achieve k-anonymity with collaborative users. Along with the analysis of existing algorithms,we found users in the group must share the same maximum anonymity degree,and they could not ease the process of preservation in a lower one. To cope with this problem,we proposed a random-QBE algorithm to put up with personalized anonymity in user collaboration algorithms,and this algorithm could preserve both query privacy and location privacy. Then we studied the attacks from passive and active adversaries and used entropy to measure user's privacy level. Finally,experimental evaluations further verify its effectiveness and efficiency.Chunguang Ma Lei Zhang Songtao Yang Xiaodong Zheng Pinhui Ke 2016China Communications2016,13,11:13
8Phosphorus oxoanion-intercalated layered double hydroxides for high-performance oxygen evolution显示文摘合理设计和为氧进化反应(OER ) 的有效、划算的电极的控制制造为探讨崭新的精力危机是批评的。有特定的夹层阴离子的镍铁分层的双氢氧化物(NiFe-LDHs )( 即磷酸盐,亚磷酸盐,和次磷酸盐) 被一个一起沉淀方法制作并且作为氧进化 electrocatalysts 调查了。磷 oxoanion 的置闰在一个碱的答案提高了 OER 活动;最佳的表演(即, 215 mV, 37.7 mV/dec 的一个小 Tafel 斜坡,和稳定的电气化学的行为的一个低发作潜力) 与设置次磷酸盐的 NiFe-LDH 催化剂被完成,在传统的设置碳酸盐的 NiFe-LDH 上的示威戏剧的改进以活动和耐久性。这提高的表演被归因于在设置的磷的 oxoanions 和分享边的瞬间 6 之间的相互作用(M = Ni, Fe ) 层,它修改表面 Ni 地点的电子结构。这个概念应该为更有效的基于 LDH 的氧进化 electrocatalysts 的设计是鼓舞人心的。Ma Luo Zhao Cai Cheng Wang Yongmin Bi Li Qian Yongchao Hao Li Li Yun Kuang Yaping Li Xiaodong Lei Ziyang HUO Wen Liu Hailiang Wang Xiaoming Sun Xue Duan 2017Nano Research2017,10,5:12
9Quick ice mass loss and abrupt retreat of the maritime glaciers in the Kangri Karpo Mountains, southeast Tibetan Plateau显示文摘The maritime glaciers are sensitive to climate change because of high annual precipitation and high air temperature in the region. A combined comprehensive study was carried out based on glacier mass balance observation, GPS-based glacier terminus position survey, glacier Ground Penetrating Radar, topography maps and RS satellite images in the Kangri Karpo Mountains, Southeast Tibet. The study revealed a strong ice mass loss and quick glacier retreat since the 1970s. Ata Glacier, one glacier from the south slope of the Kangri Karpo Mountains, has formed a 6-km-long terminal moraine zone at the end of the glacier since the 1970s, and the accelerating retreat is largely due to the strong glacier sur- face melting. Mass balance study on the other four glaciers on the northern side of the Kangri Karpo Mountains shows that they are in large negative mass balance and the glaciers had retreated 15―19 m from May 2006 to May 2007. The in-situ glacier observation also shows that the glacier retreat is more obvious in small glaciers. The enhanced ice mass deficit caused by climate warming and the ongoing extinction of many small glaciers in this region could seriously affect the water resources, environ- ments, local climate and regional sustainable development in the near future.YANG Wei YAO TanDong XU BaiQing WU GuangJian MA LingLong XIN XiaoDong 2008Chinese Science Bulletin2008,53,16:11
10High-precision pose measurement method in wind tunnels based on laser-aided vision technology显示文摘The measurement of position and attitude parameters for the isolated target from a highspeed aircraft is a great challenge in the field of wind tunnel simulation technology.In this paper,firstly, an image acquisition method for small high-speed targets with multi-dimensional movement in wind tunnel environment is proposed based on laser-aided vision technology.Combining with the trajectory simulation of the isolated model, the reasonably distributed laser stripes and selfluminous markers are utilized to capture clear images of the object.Then, after image processing,feature extraction, stereo correspondence and reconstruction, three-dimensional information of laser stripes and self-luminous markers are calculated.Besides, a pose solution method based on projected laser stripes and self-luminous markers is proposed.Finally, simulation experiments on measuring the position and attitude of high-speed rolling targets are conducted, as well as accuracy verification experiments.Experimental results indicate that the proposed method is feasible and efficient for measuring the pose parameters of rolling targets in wind tunnels.Liu Wei Ma Xin Li Xiao Chen Ling Zhang Yang Li Xiaodong Shang Zhiliang Jia Zhenyuan 2015Chinese Journal of Aeronautics2015,28,4:11
11A Critical Time-Window for the Selective Induction of Hippocampal Memory Consolidation by a Brief Episode of Slow-Wave Sleep显示文摘Although extensively studied, the exact role of sleep in learning and memory is still not very clear. Sleep deprivation has been most frequently used to explore the effects of sleep on learning and memory, but the results from such studies are inevitably complicated by concurrent stress and distress. Furthermore, it is not clear whether there is a strict time-window between sleep and memory consolidation. In the present study we were able to induce time-locked slow-wave sleep(SWS) in mice by optogenetically stimulating GABAergic neurons in the parafacial zone(PZ), providing a direct approach to analyze the influences of SWS on learning and memory with precise time-windows. We found that SWS induced by light for 30 min immediately or 15 min after the training phase of the object-in-place task significantly prolonged the memory from 30 min to 6 h. However, induction of SWS 30 min after the training phase did not improve memory, suggesting a critical time-window between the induction of a brief episode of SWS and learning for memory consolidation.Application of a gentle touch to the mice during light stimulation to prevent SWS induction also failed to improve memory, indicating the specific role of SWS,but not the activation of PZ GABAergic neurons itself, in memory consolidation. Similar influences of light-induced SWS on memory consolidation also occurred for Y-maze spatial memory and contextual fear memory, but not for cued fear memory. SWS induction immediately before the test phase had no effect on memory performance, indicating that SWS does not affect memory retrieval. Thus, by induction of a brief-episode SWS we have revealed a critical time window for the consolidation of hippocampusdependent memory.Yi Lu Zheng-Gang Zhu Qing-Qing Ma Yun-Ting Su Yong Han Xiaodong Wang Shumin Duan Yan-Qin Yu 2018Neuroscience Bulletin2018,34,6:9
12Paleomagnetic data from the Late Carboniferous-Late Permian rocks in eastern Tibet and their implications for tectonic evolution of the northern Qiangtang-Qamdo block显示文摘We report paleomagnetic results from the Late Carboniferous-Late Permian strata in eastern Tibet (China), and aim to clarify the tectonic and paleogeographic evolution of the northern Qiangtang-Qamdo block, which is the key to the study of plate boundary between the Gondwanaland and the Eurasia during the late Paleozoic. Two hundred and nineteen samples-including limestone, muddy siltstone, basalt, lava, and tuff-were collected at 24 sites in the Upper Carboniferous and Middle-Upper Permian successions. A systematic study of rock magnetism and paleomagnetism yields three reliable paleomagnetic pole positions. Both hematite and magnetite occurred in the Late Carboniferous limestone samples. The demagnetization curve shows a characteristic double-component, with the remanent magnetization (ChRM) exhibiting a positive polarity (negative inclination). In the Late Permian limestone, tuff, and basalt, magnetic information were recorded primarily in magnetite, although a small fraction of them was found in hematite in basalt. The demagnetization curve illustrates a double or single component, with the ChRM showing a negative polarity (positive inclination), which has passed the classic fold test successfully. The single polarity features of the ChRM directions of the Late Carboniferous and Middle-Late Permian rocks are respectively related to the Kiaman positive and reversed polarities under the stratigraphic coordinates. This, in turn, indicates that both ChRMs directions represent the original remanence directions. By comparison with the previously published paleomagnetic results from the late Paleozoic rocks in the northern Qiangtang Range, we suggest that: (1) Qamdo and northern Qiangtang block were independent of each other during the Late Carboniferous to the Early Permian periods. The north Lancangjiang ocean basin between the two blocks may have closed before the Middle Permian and been involved in the continent-continent collision stage in the Late Permian-Early Triassic periods. (2) The northern Qiangtang-Qamdo Block paleogeographically was situated at low to intermediate latitudes in the Southern Hemisphere in the Late Carboniferous-Late Permian periods, and began to displace northward in the Early Triassic, with an amount of more than 5000 km northward transport from its current location.CHENG Xin WU HanNing DIAO ZongBao WANG HaiJun MA Lun ZHANG XiaoDong YANG Gang HONG JingJing JI WenHua LI RongShe CHEN ShouJian ZHAO ZhenMing 2013Science China Earth Sciences2013,56,7:8
13Removal of phosphate from wastewater using alkaline residue显示文摘Alkaline residue(AR) was found to be an efficient adsorbent for phosphate removal from wastewater. The kinetic and equilibrium of phosphate removal were investigated to evaluate the performance of modified alkaline residue. After treatment by NaOH(AR-NaOH), removal performance was significantly improved, while removal performance was almost completely lost after treatment by HCl(AR-HCl). The kinetics of the removal process by all adsorbents was well characterized by the pseudo second-order model. The Langmuir model exhibited the best correlation for AR-HCl, while AR was effectively described by Freundlich model. Both models were well fitted to AR-NaOH. The maximum adsorption capacities calculated from Langmuir equation were in following manner: AR-NaOH > AR > AR-HCl. Phosphate removal by alkaline residue was pH dependent process. Mechanisms for phosphate removal mainly involved adsorption and precipitation, varied with equilibrium pH of solution. For AR-HCl, the acid equilibrium pH(< 6.0) was unfavorable for the formation of Ca-P precipitate, with adsorption as the key mechanism for phosphate removal. In contrast, for AR and ARNaOH, precipitation was the dominant mechanism for phosphate removal, due to the incrase on pH(> 8.0) after phosphate removal. The results of both XRD and SEM analysis confirmed CaHPO4·2H2O formation after phosphate removal by AR and AR-NaOH.Yubo Yan Xiuyun Sun Fangbian Ma Jiansheng Li Jinyou Shen Weiqing Han Xiaodong Liu Lianjun Wang 2014Journal of Environmental Sciences2014,26,5:8
14Dynamically controlling terahertz wavefronts with cascaded metasurfaces显示文摘Dynamically controlling terahertz(THz)wavefronts in a designable fashion is highly desired in practice.However,available methods working at microwave frequencies do not work well in the THz regime due to lacking suitable tunable elements with submicrometer sizes.Here,instead of locally controlling individual meta-atoms in a THz metasurface,we show that rotating different layers(each exhibiting a particular phase profile)in a cascaded metadevice at different speeds can dynamically change the effective Jonesmatrix property of the whole device,thus enabling extraordinary manipulations on the wavefront and polarization characteristics of a THz beam impinging on the device.After illustrating our strategy based on model calculations,we experimentally demonstrate two proof-of-concept metadevices,each consisting of two carefully designed all-silicon transmissive metasurfaces exhibiting different phase profiles.Rotating two metasurfaces inside the fabricated devices at different speeds,we experimentally demonstrate that the first metadevice can efficiently redirect a normally incident THz beam to scan over a wide solid-angle range,while the second one can dynamically manipulate both the wavefront and polarization of a THz beam.Our results pave the way to achieving dynamic control of THz beams,which is useful in many applications,such as THz radar,and bio-and chemical sensing and imaging.Xiaodong Cai Rong Tang Haoyang Zhou Qiushi Li Shaojie Ma Dongyi Wang Tong Liu Xiaohui Ling Wei Tan Qiong He Shiyi Xiao Lei Zhou 2021Advanced Photonics2021,3,3:8
15Spatial Pattern and Regional Types of Rural Settlements in Xuzhou City,Jiangsu Province,China显示文摘This paper principally focuses on the morphological differences,spatial pattern and regional types of rural settlements in Xuzhou City of Jiangsu Province in China.Using satellite images of Xuzhou City taken in 2007 and 2008 and models of exploratory spatial data analysis(ESDA) and spatial metrics,the paper conducts a quantitative analysis of the morphological pattern of rural settlements,and finds significant characteristics.First,rural settlements in Xuzhou City are significantly agglomerated in terms of their spatial distribution;meanwhile,there is significant variation in the geographical density distribution.Second,the scale of rural settlements in Xuzhou City is larger than the average in Jiangsu Province,and the histogram of the scale data is more even and more like a gamma distribution.There are a significant high-value cluster in the scale distribution,and local negative correlation between the scale and density distribution of rural settlements in Xuzhou City.Third,the morphology of rural settlements in Xuzhou City shows relative regularity with good connection and integrity,but the spatial variation of the morphology is anisotropic.Finally,according to the characteristics of density,scale,and form of rural settlements,the rural settlements of Xuzhou City are divided into three types:A high-density and point-scattered type,a low-density and cluster-like type and a mass-like and sparse type.The research findings could be used as the scientific foundation for rural planning and community rebuilding,particularly in less-developed areas.MA Xiaodong QIU Fangdao LI Quanlin SHAN Yongbin CAO Yong 2013Chinese Geographical Science2013,23,4:7
16Advances in crop phenotyping and multi-environment trials显示文摘Efficient evaluation of crop phenotypes is a prerequisite for breeding, cultivar adoption, genomics and phenomics study. Plant genotyping is developing rapidly through the use of high-throughput sequencing techniques,while plant phenotyping has lagged far behind and it has become the rate-limiting factor in genetics, large-scale breeding and development of new cultivars. In this paper,we consider crop phenotyping technology under three categories. The first is high-throughput phenotyping techniques in controlled environments such as greenhouses or specifically designed platforms. The second is a phenotypic strengthening test in semi-controlled environments, especially for traits that are difficult to be tested in multi-environment trials(MET), such as lodging, drought and disease resistance. The third is MET in uncontrolled environments, in which crop plants are managed according to farmer's cultural practices. Research and application of these phenotyping techniques are reviewed and methods for MET improvement proposed.Zhe LIU Fan ZHANG Qin MA Dong AN Lin LI Xiaodong ZHANG Dehai ZHU Shaoming LI 2015Frontiers of Agricultural Science and Engineering2015,2,1:7
17Novel synthesis of N-doped graphene as an efficient electrocatalyst towards oxygen reduction显示文摘做氮的 graphene (NG ) 被一个新奇、灵巧、可伸缩的自底向上的方法成功地综合。退火的 NG (NG -- 一) 拥有的高特定的表面区域和一块层次多孔的质地,和在在碱、酸的媒介的氧减小反应的展出显著地改进的 electrocatalytic 活动。分子的动态模拟显示了的 Ab initio 那快速的 H 转移和六成员的 N 结构的热力学的稳定性在 600 敮 x 从 pyrrolic 把包含 N 种类的转变提升了到Ruguanq Ma Xiaodong Ren Bao Yu Xia Yao Zhou Chi Sun Qian Liu Jianjun Liu Jiacheng Wang 2016Nano Research2016,9,3:6
18The Expression of Manganese Superoxide Dismutase Gene from Nelumbo nucifera Responds Strongly to Chilling and Oxidative Stresses显示文摘A manganese superoxide dismutase(Mn-SOD) gene,NnMSD1,was identified from embryonic axes of the sacred lotus(Nelumbo nucifera Gaertn.) . The NnMSD1 protein contains all conserved residues of the Mn-SOD protein family,including four consensus metal binding domains and a signal peptide for mitochondrial targeting. Southern blot analysis suggests the existence of two Mn-SOD genes in sacred lotus. NnMSD1 was highly expressed in developing embryonic axes during seed development,but appeared in cotyledons only at the early stage of development and became undetectable in the cotyledons during late embryogenesis. The expression of the NnMSD1 gene in germinating embryonic axes,in response to various stresses such as heat shock,chilling,and exposure to stress-related chemicals,was also studied. Heat shock strongly inhibited the expression of the NnMSD1 gene,whereas the NnMSD1 transcript level increased strongly in chilling stress treatment. An increase in expression was also highly induced by H2O2 in germinating embryonic axes. The results suggest that the expression pattern of the NnMSD1 gene differed between developing axes and cotyledons,and that the NnMSD1 gene expression responds strongly to chilling and oxidative stress.Wen Li Lin Qi Xiaodong Lin Huhui Chen Zhanqi Ma Keqiang Wu Shangzhi Huang 2009Journal of Integrative Plant Biology2009,51,3:6
19Fe5C2 nanoparticles as low-cost HER electrocatalyst:the importance of Co substitution显示文摘Constructing and understanding the doping effect of secondary metal in transition metal carbide(TMC)catalysts is pivotal for the design of low-cost hydrogen evolution reaction(HER) electrocatalysts. In this work, we developed a wet-chemistry strategy for synthesizing Co-modified Fe_5C_2 nanoparticles((Fe_(1-x)Cox)_5C_2 NPs) as highly active HER electrocatalysts in basic solution. The structure of(Fe_(1-x)Cox)_5C_2 NPs was characterized by X-ray diffraction(XRD), extended X-ray absorption fine structure spectra(EXAFS) and scanning/transmission electron microscopy(S/TEM), indicating that the isomorphous substitution of cobalt in the lattice of Fe_5C_2.(Fe_(0.75) Co_(0.25))_5C_2 exhibited the best HER activity(174 mV for j = -10 mA/cm^2). Computational calculation results indicate that Co provides the most active site for HER. X-ray adsorption spectra(XAS) studies further suggested that the electron transfer in Fe–C bonds are enhanced by the substitution of Co, which modulates the hydrogen adsorption on the adjacent electronic-enriched carbon, and therefore promotes HER activity. Our results affirm the design of lowcost bimetallic TMCs based HER catalysts.Siwei Li Pengju Ren Ce Yang Xi Liu Zhen Yin Weizhen Li Hanjun Yang Jian Li Xiaoping Wang Yi Wang Ruochen Cao Lili Lin Siyu Yao Xiaodong Wen Ding Ma 2018Science Bulletin2018,63,20:6
20nvolvement of collagen-binding heat shock protein 47 in scleroderma-associated fibrosis显示文摘Haiyan Chu Ting Wu Wenyu Wu Wenzhen Tu Shuai Jiang Sidi Chen Yanyun Ma Qingmei Liu Xiaodong Zhoua Li Jin Jiucun Wang 2015Protein & Cell2015,6,8:5
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