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53篇 您的检索式:作者名="Zhiming Xiao"
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1Changes in rice cropping systems in the Poyang Lake Region, China during 2004-2010显示文摘Rice cropping systems not only characterize comprehensive utilization intensity of agricultural resources but also serve as the basis to enhance the provision services of agro-ecosystems.Yet,it is always affected by external factors,like agricultural policies.Since 2004,seven consecutive No.1 Central Documents issued by the Central Government have focused on agricultural development in China.So far,few studies have investigated the ef-fects of these policies on the rice cropping systems.In this study,based upon the long-term field survey information on paddy rice fields,we proposed a method to discriminate the rice cropping systems with Landsat data and quantified the spatial variations of rice cropping systems in the Poyang Lake Region(PLR),China.The results revealed that:(1) from 2004 to 2010,the decrement of paddy rice field was 46.76 km2 due to the land use change.(2) The temporal dynamics of NDVI derived from Landsat historical images could well characterize the temporal development of paddy rice fields.NDVI curves of single cropping rice fields showed one peak,while NDVI curves of double cropping rice fields displayed two peaks an-nually.NDVI of fallow field fluctuated between 0.15 and 0.40.NDVI of the flooded field during the transplanting period was relatively low,about 0.20±0.05,while NDVI during the period of panicle initiation to heading reached the highest level(above 0.80).Then,several temporal windows were determined based upon the NDVI variations of different rice cropping systems.(3) With the spatial pattern of paddy rice field and the NDVI threshold within optimum tem-poral windows,the spatial variation of rice cropping systems was very obvious,with an in-creased multiple cropping index of rice about 20.2% from 2004 to 2010.The result indicates that agricultural policies have greatly enhanced the food provision services in the PLR,China.LI Peng FENG Zhiming JIANG Luguang LIU Yujie XIAO Xiangming 2012Journal of Geographical Sciences2012,22,4:23
2MiR-135a promotes growth and invasion of colorectal cancer via metastasis suppressor 1 in vitro显示文摘MicroRNAs (miRNAs ) 是参予送信人 RNA 和蛋白质合成的空间与时间的规定的小非编码的 RNA。异常 miRNA 表示导致发展畸形和疾病。miR-135a 被认为是 oncogenic;然而,在 colorectal 癌症(CRC ) 的 miR-135a 的功能和机制大部分是未知的。因此,我们调查了 miR-135a 的功能和机制,特别与转移 suppressor 的它的关系 1 (MTSS1 ) 在 CRC 的基因。当它房间增长,移植,和侵略上的效果被 MTT 决定时, miR-135a 的表达式被即时聚合酶链反应分别地决定,没有并且与 matrigel。MTSS1 的表示被西方的污点分析检测。miR-135a 表示比在非肿瘤控制织物在人的 CRC 样品是更高的,这被发现。用 SW480 和 SW620 CRC 房间行,增加了增长响应 miR-135a 被观察。我们也证明分别地, miR-135a CRC 房间有或没有 Matrigel 经由 transwell 试金支持了活动性和侵略。相反, miR-135a 的抑制减少了他们的 proliferative 和侵略能力。MTSS1 被酶报告试金作为 miR-135a 的候选人目标基因识别。西方的污点分析证明 MTSS1 的表示被 miR-135a overexpression 调整并且击倒。同样,在 MTSS1 被小介入 RNA 击倒以后, miR-135a-mediated 房间活动性和侵略被减少。这些数据显示 miR-135a 支持 CRC 细胞的生长和侵略,至少部分,通过指向 MTSS1。Weiwei Zhou Xiayu Li Fen Liu Zhiming Xiao Miao He Shourong Shen Shaojun Liu 2012Acta Biochimica et Biophysica Sinica2012,44,10:19
3Migration and accumulation of natural gas in Kela-2 gas field显示文摘With the guidance of petroleum system theory,the dynamic filling history of natural gas in the Kela-2 gasfield is analyzed by using a large suite of oil and gas geo-chemistry evidence in combination with the tectonic evolu-tion history and reservoir evolution history. It concludes thatthe Kela-2 gas field was formed by capturing the gas gener-ated during the main gas generation period, while the latekerogen cracking gas contributed a little to the gas field. Itsuggests that the gas generated during the main gas genera-tion accumulated in the early-formed wide-gentle anticline,which is the necessary condition for natural gas to re-migrateand enrich late to form the large-scale gas reservoir. Thenewest research shows that the filling history of gas in theDabei-1, Yinan-2, Tuziluoke and Dina-2 gas fields was re-lated with the natural gas accumulation in the early wide-gentle anticline as well as late re-migration and enrichmentof natural gas.WANG Zhaoming WANG Tingdong XIAO Zhongyao XU Zhiming LI Mei LIN Feng 2002Chinese Science Bulletin2002,47,S1:16
4Theoretical and numerical research of wire array Z-pinch and dynamic hohlraum at IAPCM显示文摘Dense Z-pinch plasmas are powerful and energy-efficient laboratory sources of X-rays,and show the possibility to drive inertial confinement fusion(ICF).Recent advances in wire-array Z-pinch and Z-pinch dynamic hohlraum(ZPDH)researches at the Institute of Applied Physics and Computational Mathematics are presented in this paper.Models are setup to study different physical processes.A full circuit model(FCM)was used to study the coupling between Z-pinch implosion and generator discharge.A mass injection model with azimuthal modulation was setup to simulate the wire-array plasma initiation,and the two-dimensional MHD code MARED was developed to investigate the Z-pinch implosion,MRT instability,stagnation and radiation.Implosions of nested and quasi-spherical wire arrays were also investigated theoretically and numerically.Key processes of ZPDH,such as the arrayefoam interaction,formation of the hohlraum radiation,as well as the following capsule ablation and implosion,were analyzed with different radiation magneto-hydrodynamics(RMHD)codes.An integrated 2D RMHD simulation of dynamic hohlraum driven capsule implosion provides us the physical insights of wire-array plasma acceleration,shock generation and propagation,hohlraum formation,radiation ablation,and fuel compression.Ning Ding Yang Zhang Delong Xiao Jiming Wu Zihuan Dai Li Yin Zhiming Gao Shunkai Sun Chuang Xue Cheng Ning Xiaojian Shu Jianguo Wang 2016Matter and Radiation at Extremes2016,1,3:7
5Micro-droplet Digital Polymerase Chain Reaction and Real-Time Quantitative Polymerase Chain Reaction Technologies Provide Highly Sensitive and Accurate Detection of Zika Virus显示文摘The establishment of highly sensitive diagnostic methods is critical in the early diagnosis and control of Zika virus(ZIKV)and in preventing serious neurological complications of ZIKV infection. In this study, we established micro-droplet digital polymerase chain reaction(ddPCR) and real-time quantitative PCR(RT-qPCR) protocols for the detection of ZIKV based on the amplification of the NS5 gene. For the ZIKV standard plasmid, the RT-qPCR results showed that the cycle threshold(Ct) value was linear from 10~1 to 10~8 copy/l L, with a standard curve R^2 of 0.999 and amplification efficiency of 92.203%;however, a concentration as low as 1 copy/l L could not be detected. In comparison with RT-qPCR, the dd PCR method resulted in a linear range of 10~1–10~4 copy/l L and was able to detect concentrations as low as 1 copy/l L. Thus, for detecting ZIKV from clinical samples, RT-qPCR is a better choice for high-concentration samples(above 10~1 copy/l L),while ddPCR has excellent accuracy and sensitivity for low-concentration samples. These results indicate that the ddPCR method should be of considerable use in the early diagnosis, laboratory study, and monitoring of ZIKV.Yuan Hui Zhiming Wu Zhiran Qin Li Zhu Junhe Liang Xujuan Li Hanmin Fu Shiyu Feng Jianhai Yu Xiaoen He Weizhi Lu Weiwei Xiao Qinghua Wu Bao Zhang Wei Zhao 2018Virologica Sinica2018,33,3:6
6CO2 corrosion behaviors of 13Cr steel in the high-temperature steam environment显示文摘The study aims to explore the corrosion behaviors of 13Cr steel in the high-temperature steam environment.The corrosion behaviors of 13Cr steel were tested in CO2 auxiliary steam drive environment simulated with the HTHP autoclave.The corrosion morphology and product composition were explored by SEM,EDS,XRD and XPS.The exploration results showed the corrosion rate of 13Cr steel in the high-temperature steam environment was less than 0.04 mm/a.The corrosion behaviors of 13Cr steel were mainly affected by temperature and chloride ion concentration.Temperature inhibited steam condensation and the compactness of Cr-rich layer.With the increase in temperature,more droplets were adsorbed on the surface of 13Cr steel and the compactness of the Crrich layer is worse.Chloride ions affects the activity of Fe atoms in the metal matrix.When chloride concentration increased,Fe^2+concentration in the solution and FeCO3 content in the rich-Cr layer were increased and the rich-Cr layer became looser.Guoqing Xiao SiZhou Tan Zhiming Yu Baojun Dong Yonggang Yi Gang Tian Huiyong Yu Shanzhi Shi 2020Petroleum2020,6,1:5
7Evolution of surface microstructure of Cu-50Cr alloy treated by high current pulsed electron beam显示文摘A Cu-50Cr alloy was treated by the high current pulsed electron beam(HCPEB)at 20 and 30 ke V with pulse numbers ranging from 1 to 100.Surface morphologies and microstructures of specimens before and after the treatments were investigated by employing scanning electron microscopy and X-ray diffraction.Results show that the HCPEB technique is able to induce remarkable surface modifications for the Cu-50Cr alloy.Cracks in Cr phases appear even after one-pulse treatment and their density always increases with the pulse number.Formation reason for these cracks is attributed to quasi-static thermal stresses accumulated along the specimen surface.Craters with typical morphologies are formed due to the dynamic thermal field induced by the HCPEB and they are found to prefer the sites near cracks or boundaries between neighboring Cr phases.Another microstructural characteristic produced by the HCPEB is the fine Cr spheroids,which are determined to be due to occurrence of liquid phase separation in the Cu-50Cr alloy.Finally,a general microstructural evolution profile that incorporates various HCPEB-induced surface features is tentatively outlined.CHAI LinJiang ZHOU ZhiMing XIAO ZhiPei TU Jian WANG YaPing HUANG WeiJiu 2015Science China(Technological Sciences)2015,58,3:5
8Mapping rice cropping systems using Landsat-derived Renormalized Index of Normalized Difference Vegetation Index (RNDVI) in the Poyang Lake Region, China显示文摘印射在多重收割区域与光形象收割系统的米饭由于云污染和数据可获得性是挑战性的;有一个减少的数据要求的一个基于物候学的算法的开发是必要的。在这研究,规范的差别植被索引(RNDVI ) 的导出 Landsat 的重新使正常化的索引基于 NDVI 单身者并且早在珍视的二个时间的窗口被建议(或迟了) 米饭显示器逆变化,然后适用区别收割系统的米饭。波伊昂·莱克区域(PLR ) ,由收割米饭(SCR,或单个米饭) 和两倍收割米饭(DCR,包括的早米饭和迟了的米饭) 的单身者的一个典型收割系统描绘了,作为一个严峻的区域被选择。结果显示出数据在八点从 Landsat 时间系列导出到十六天俘获的那 NDVI 稻米饭的时间的发展。在 SCR 和 DCR 的 NDVI 价值相反地在变化的重叠生长时期期间有二个关键 phenological 阶段,也就是,早米饭的成熟阶段和象成熟一样的单个米饭的成长阶段近来单个米饭和成长阶段上演米饭。NDVI 在二扇时间的窗户,明确地早的 8 月和早 10 月中源于场面,被用来为区别在 PLR 的新辟的低地区域收割系统的米饭构造 RNDVI,中国。有地面真相数据的比较显示高分类精确性。RNDVI 途径由于在二个时间的窗口之间的米饭生长的差别加亮 NDVI 值的反的变化。当它仅仅需要区分候选人米饭类型是否在生长的时期,这使收割系统的米饭的辨别直接(RNDVI < 0 ) 或老朽(RNDVI > 0 ) 。Peng LI Luguang JIANG Zhiming FENG Sage SHELDON Xiangming XIAO 2016Frontiers of Earth Science2016,10,2:4
9Basic Features of the Crustal Structure in the Lower Yangtze and Its Neighboring Area in the Chinese Mainland: Review of Deep Seismic Sounding Research显示文摘The Deep Seismic Sounding( DSS) projects carried out from the 1970 s in the lower Yangtze region and its neighboring area were reviewed in this paper,then the basic wave group features of those wide angle reflection / refraction record sections,and of the crustal structure are summarized. It shows that there were in total five clear wave groups on the record sections,which include the first arrival Pg,the reflection P1 from the bottom interface of the upper crust,the reflection P3 from the bottom interface of the middle crust,the strong reflection Pm from the Moho boundary,and the refraction Pn from uppermost mantle. In general,these phases are easily consistently traced and compared,despite some first arrivals being delayed or arriving earlier than normal due to the shallow sedimentary cover or bedrocks. In particular,in the Dabie Mountain region the seismic events of a few gathered shots always have weak reflection energy,are twisted,or exhibit disorganized waveforms, which could be attributed to the disruption variations of reflection depth,the broken Moho,and the discontinuity of the reflection boundary within crust. The regional crustal structures are composed of the upper,middle and lower crust,of which the middle and lower layers can be divided into two weak reflection ones. The crustal thickness of the North China and Yangtze platform are 30km- 36 km,and the Moho exhibits a flat geometry despite some local uplifts. The average pressure velocity in lower crust beneath this two tectonic area is 6. 7 ± 0. 3km / s. Nevertheless,beneath the Dabieshan area the crustal thickness is 32km- 41 km,the Moho bends down sharply andtakes an abrupt 4km- 7km dislocation in the vertical direction. The average pressure velocity in the lower crust beneath the Dabieshan area is 6. 8 ± 0. 2km / s.Bai Zhiming Wu Qingju Xu Tao Wang Xiao 2016Earthquake Research in China2016,30,3:3
10Optimized statistical analysis of software trustworthiness attributes显示文摘Software trustworthiness has become one of the key restrictions for software service quality and the development of the software industry.However,trustworthiness attributes interlace structured and dynamical coupling relations,which causes great barriers for trustworthiness measurements of large-scale software.According to the dynamical evolutionary characteristics of software trustworthiness attributes,this paper proposes a new approach for optimizing the trustworthiness measurement in terms the kernel trustworthiness attributes,and improves a downsize-optimized statistical analysis method for software trustworthiness attributes based on their nonlinear relations.The improved method considerably simplifies the trustworthiness assessment of largescale software.Using theoretical analysis and numerical simulations,the feasibility of this method is verified using two typical examples that illustrate the realization of the trustworthiness measurement.ZHANG Xiao LI Wei ZHENG ZhiMing GUO BingHui 2012Science China(Information Sciences)2012,55,11:3
11Effect of Interlayers on Microstructure and Properties of 2205/Q235B Duplex Stainless Steel Clad Plate显示文摘In this research,2205/Q235 B clad plates were prepared by a vacuum hot rolling composite process.The effects of adding Fe,Ni,and Nb interlayers on the bonding interface structures and the shear strengths of the clad steel plates were studied.The results showed that 2205 duplex stainless steel and the three interlayers produced a large amount of plastic deformation and low-angle boundaries,and the main structures were the recrystallized and deformed grains.There were many recrystallized grains in the microstructure of the Q235 B low-carbon steel due to the low deformation in the rolling process.The Fe interlayer had better wettability with the two kinds of steel,but the lower strength led to the reduction of shear strength by about14 MPa compared with the original clad steel plate.The C element in the Q235 B low-carbon steel easily diffused into the Fe interlayer,and the clad steel plate attained a poor corrosion resistance because a large decarburization area was formed.The Nb interlayer reacted with the Mo element in the 2205 duplex stainless steel to form an Nb-Mo binary alloy,which generated long-banded ferrite.The decarburization area was also produced because the Nb reacted with the C element in the Q235 B to form hard and brittle NbCx.As a result,the shear strength was significantly reduced by about 282 MPa,and the corrosion resistance of the bonding surface was deteriorated.The Ni interlayer did not react with the alloy elements in both sides,and therefore effectively prevented element diffusion and improved the corrosion resistance of the bonding surface.Due to the low strength of the Ni interlayer and the increased number of bonding surfaces of the clad steel plates,the shear strength was reduced to some extent(about 40 MPa),but it still met the engineering application standards.Fengqiang Xiao Dongpo Wang Wenbin Hu Lei Cui Zhiming Gao Lanju Zhou 2020Acta Metallurgica Sinica(English Letters)2020,33,5:2
12Acquisition probability differences in cloud coverage of the available Landsat observations over mainland Southeast Asia from 1986 to 2015显示文摘Landsat data are the longest available records that consistently document global change.However,the extent and degree of cloud coverage typically determine its usability,especially in the tropics.In this study,scene-based metadata from the U.S.Geological Survey Landsat inventories,ten-day,monthly,seasonal,and annual acquisition probabilities(AP)of targeted images at various cloud coverage thresholds(10%to 100%)were statistically analyzed using available Landsat TM,ETM+,and OLI observations over mainland Southeast Asia(MSEA)from 1986 to 2015.Four significant results were found.First,the cumulative average acquisition probability of available Landsat observations over MSEA at the 30%cloud cover(CC)threshold was approximately 41.05%.Second,monthly and ten-day level probability statistics for the 30%CC threshold coincide with the temporal distribution of the dry and rainy seasons.This demonstrates that Landsat images acquired during the dry season satisfy the requirements needed for land cover monitoring.Third,differences in acquisition probabilities at the 30%CC threshold are different between the western and eastern regions of MSEA.Finally,the ability of TM,ETM+,and OLI to acquire high-quality imagery has gradually enhanced over time,especially during the dry season,along with consequently larger probabilities at lower CC thresholds.Peng Li Zhiming Feng Chiwei Xiao 2018International Journal of Digital Earth2018,11,5:2
13Self-supported hierarchical porous Li_(4)Ti_(5)O_(12)/carbon arrays for boosted lithium ion storage显示文摘The development of fast rechargeable lithium ion batteries(LIBs)is highly dependent on the innovation of advanced high-power electrode materials.In this work,for the first time,we report a sacrificial NiO arrays template method for controllable synthesis of self-supported hierarchical porous Li_(4)Ti_(5)O_(12)/C(LTO/C)nanoflakes arrays,for use as fast rechargeable anodes for LIBs.The ultrathin(2-3 nm)carbon layer was uniformly coated on the LTO forming arrays architecture.The hierarchical porous LTO/C nanoflakes consisted of primary cross-linked nanoparticles of 50-100 nm and showed large porosity.Because of the enhanced electrical conductivity and accelerated ion transfer channels,the well-designed binderfree porous LTO/C nanoflakes arrays exhibited notable high-rate lithium ion storage performance with smaller polarization,better electrochemical reactivity,higher specific capacity(157 mAh g^(-1) at the current density of 20C)and improved long-term cycling life(96.2% after 6000 cycles at 20C),superior to the unmodified porous LTO arrays counterpart(126 mAh g^(-1) at 20C and 88.0%after 6000 cycles at 20C).Our work provides a new template for the construction of high-performance high-rate electrodes for electrochemical energy storage.Jun Liu Aixiang Wei Guoxiang Pan Shenghui Shen Zhiming Xiao Yu Zhao Xinhui Xia 2021Journal of Energy Chemistry2021,30,3:2
14Effects of supports and combined process on hydrogen purification over nickel supported catalysts显示文摘Hydrogen purification must be done to meet the different purposes of hydrogen utilization.In the present work,it is confirmed that the catalyst Ni/CeO2 has the highest activity for total methanation(Total MET) of CO and CO2,and is thus most suitable for hydrogen purification for ammonia synthesis.While,the catalyst Ni/ZrO2 appears the best one for selective methanation of CO(CO-SMET) in the H2-rich gas to produce clean fuel for proton exchange membrane fuel cell(PEMFC).In spite of this,the catalyst Ni/ZrO2 without adding chlorine ions as promoter is not yet capable of removing the CO in the reformate gas to below 10 ppm in a wide reaction temperature range by the way of CO-SMET.Adding chlorine ions as promoter is indeed not favorable for practical application due to its gradual loss in the catalytic reaction as proved in our previous work.Therefore,a step to decrease CO2 concentration(called as de-CO2 step) is suggested to be set prior to the CO-SMET step in this work.It is proved that such combination of de-CO2 step and CO-SMET step is efficient to achieve a deep removal of CO to below 10 ppm with a high selectivity more than 50% in a wide reaction temperature range of 220-280℃over the catalyst Ni/ZrO2 without adding chlorine ions as promoter.The combined process has potential for practical application,at least in the large-scale power plant of PEMFC.Menglan Xiao Lu Zhang Yanyan Sang Zhiming Gao 2020Journal of Rare Earths2020,38,1:2
15Activation of the bitter taste sensor TRPM5 prevents high saltinduced cardiovascular dysfunction显示文摘High salt intake is a known risk factor of cardiovascular diseases. Our recent study demonstrated that long-term high salt intake impairs transient receptor potential channel M5(TRPM5)-mediated aversion to high salt concentrations, consequently promoting high salt intake and hypertension;however, it remains unknown whether TRPM5 activation ameliorates cardiovascular dysfunction. Herein we found that bitter melon extract(BME) and cucurbitacin E(CuE), a major compound in BME, lowered high salt-induced hypertension. Long-term BME intake significantly enhanced the aversion to high salt concentrations by upregulating TRPM5 expression and function, eventually decreasing excessive salt consumption in mice. Moreover, dietary BME ameliorated high salt-induced cardiovascular dysfunction and angiotensin II-induced hypertension in vivo. The mechanistic evidence demonstrated that dietary BME inhibited high salt-induced RhoA/Rho kinase pathway overactivation, leading to reduced phosphorylation levels of myosin light chain kinase and myosin phosphatase targeting subunit 1. Furthermore, CuE inhibited vasoconstriction by attenuating L-type Ca^(2+) channel-induced Ca^(2+) influx in vascular smooth muscle cells. To summarize, our findings indicate that dietary BME has a beneficial role in antagonizing excessive salt consumption and thus appears promising for the prevention of high salt-induced cardiovascular dysfunction.Hao Wu Yuanting Cui Chengkang He Peng Gao Qiang Li Hexuan Zhang Yanli Jiang Yingru Hu Xiao Wei Zongshi Lu Tianyi Ma Daoyan Liu Zhiming Zhu 2020Science China(Life Sciences)2020,63,11:2
16“Extreme utilization”development of deep shale gas in southern Sichuan Basin,SW China显示文摘To efficiently develop deep shale gas in southern Sichuan Basin,under the guidance of“extreme utilization”theory,a basic idea and solutions for deep shale gas development are put forward and applied in practice.In view of multiple influencing factors of shale gas development,low single-well production and marginal profit of wells in this region,the basic idea is to establish“transparent geological body”of the block in concern,evaluate the factors affecting shale gas development through integrated geological-engineering research and optimize the shale gas development of wells in their whole life cycle to balance the relationship between production objectives and development costs.The solutions are as follows:(1)calculate the gold target index and pinpoint the location of horizontal well drilling target,and shale reservoirs are depicted accurately by geophysical and other means to build underground transparent geological body;(2)optimize the drilling and completion process,improve the adaptability of key tools by cooling,reducing density and optimizing the performance of drilling fluid,the“man-made gas reservoir”is built by comprehensively considering the characteristics of in-situ stress and fractures after the development well is drilled;(3)through efficient management,establishment of learning curve and optimization of drainage and production regime,the development quality and efficiency of the well are improved across its whole life cycle,to fulfil“extreme utilization”development of shale gas.The practice shows that the estimated ultimate recovery of single wells in southern Sichuan Basin increase by 10%-20%than last year.MA Xinhua WANG Hongyan ZHAO Qun LIU Yong ZHOU Shangwen HU Zhiming XIAO Yufeng 2022Petroleum Exploration and Development2022,49,6:2
17An efficient, high-order perturbation approach for flow in random porous media via Karhunen- Loeve and polynomial expansions显示文摘ZHANG Dong- xiao LU Zhiming 2004Journal of Computational Physics2004,194,:1
18Preparation and thermophysical properties of CeO 2 doped La 2 Zr 2 O 7 ceramic for thermal barrier coatings显示文摘Hongming Zhou Danqing Yi Zhiming Yu Lairong Xiao 2006Journal of Alloys and Compounds2006,,1:1
19Single-Cell Exome Sequencing Reveals Single-Nucleotide Mutation Characteristics of a Kidney Tumor显示文摘Xun Xu Yong Hou Xuyang Yin Li Bao Aifa Tang Luting Song Fuqiang Li Shirley Tsang Kui Wu Hanjie Wu Weiming He Liang Zeng Manjie Xing Renhua Wu Hui Jiang Xiao Liu Dandan Cao Guangwu Guo Xueda Hu Yaoting Gui Zesong Li Wenyue Xie Xiaojuan Sun Min Shi Zhiming 2012Cell2012,,5:1
20Boosting High-Voltage and Ultralong-Cycling Performance of Single-Crystal LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) Cathode Materials via Three-in-One Modification显示文摘LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) is extensively researched as one of the most widely used commercially materials for Li-ion batteries at present.However,the poor high-voltage performance(≥4.3 V)with low reversible capacity limits its replacement for LiCoO_(2) in high-end digital field.Herein,three-in-one modification,Na-doping and Al_(2)O_(3)@Li_(3)BO_(3) dual-coating simultaneously,is explored for single-crystalline LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2)(N-NCM@AB),which exhibits excellent high-voltage performance.N-NCM@AB displays a discharge-specific capacity of 201.8 mAh g^(−1) at 0.2 C with a high upper voltage of 4.6 V and maintains 158.9 mAh g^(−1) discharge capacity at 1 C over 200 cycles with the corresponding capacity retention of 87.8%.Remarkably,the N-NCM@AB||graphite pouch-type full cell retains 81.2% of its initial capacity with high working voltage of 4.4 V over 1600 cycles.More importantly,the fundamental understandings of three-in-one modification on surface morphology,crystal structure,and phase transformation of N-NCM@AB are clearly revealed.The Na+doped into the Li–O slab can enhance the bond energy,stabilize the crystal structure,and facilitate Li+transport.Additionally,the interior surface layer of Li^(+)-ions conductor Li_(3)BO_(3) relieves the charge transfer resistance with surface coating,whereas the outer surface Al_(2)O_(3) coating layer is beneficial for reducing the active materials loss and alleviating the electrode/electrolyte parasite reaction.This three-in-one strategy provides a reference for the further research on the performance attenuation mechanism of NCM,paving a new avenue to boost the high-voltage performance of NCM cathode in Li-ion batteries.Bao Zhang Jixue Shen Qi Wang Changqing Hu Bi Luo Yun Liu Zhiming Xiao Xing Ou 2023Energy & Environmental Materials2023,6,1:1
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